Organic Chemistry: Structure and Function
Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
Question
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Chapter 2, Problem 40P

(a)

Interpretation Introduction

Interpretation: Atom in the bromoethane that is most is likely to react with oxygen of OH should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(b)

Interpretation Introduction

Interpretation: Atom in propanal that is most is likely to react with the nitrogen of ammonia should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(c)

Interpretation Introduction

Interpretation: Atom in the methoxyethane that is most is likely to react with H+ should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(d)

Interpretation Introduction

Interpretation: Atom in 3-hexanone that is most is likely to react with CH3 should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(e)

Interpretation Introduction

Interpretation: Atom in the acetonitrile that is most likely to react with CH3+ should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(f)

Interpretation Introduction

Interpretation: Atom in the butane that is most is likely to react with OH should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

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Chlorination of 2-butanone yields two isomeric products, each having the molecular formula C4H7ClO. (a) What are these two compounds? (b) Write structural formulas for the enol intermediates that lead to each of these compounds. (c) Using curved arrows, show the flow of electrons in the reaction of each of the enols with Cl2.
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