Organic Chemistry: Structure and Function
Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 8, Problem 27P

(a)

Interpretation Introduction

Interpretation:

The following order of water solubility should be explained.

Ethanol > chloroethane > ethane

Concept Introduction:

The property which refers to the ability of a substance usually known as solute to dissolves in a particular amount of solvent is known as solubility.

(b)

Interpretation Introduction

Interpretation:

The following order of water solubility should be explained.

Methanol > ethanol > 1-propanol

Concept Introduction:

The property which refers to the ability of a substance usually known as solute to dissolves in a particular amount of solvent is known as solubility.

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(a) Give a seperate chemical test to distinguish between the following pairs of compounds:(i) Ethanol and Phenol (ii) 2-Pentanol and 3-Pentanol(b) Explain Kolbe’s reaction with the help of suitable example.
(i) increasing solubility in water. (CH3),CHCH,OH CH;CH,CH,CH,OH CH;CH,CH,Br CH;CH,OCH3 (a) (b) (c) (d) least soluble most soluble (ii) increasing stability. CH -CH3 H3C -CH3 H3C -CH3 H3C. -CH3 (а) (b) (c) (d) least stable stable (iii) increasing stability. CH,CH3 CH3 CH,CH3 CH,CH3 CH,CH3 CH3 -CH3 `CH3 (CH3),CH´ (CH3),CH' `CH3 (CH3),CH´ `CH `CH3 (CH3),CH´ CH3 (d) (a) (b) (c) least stable most stable (iv) increasing boiling point. (CH3),COH (CH3),CHCH,NH, (CH3),CHCH,OH (CH3),NCH,CH3 (a) (b) (c) (d) lowest bp highest bp
Rank the following compounds according to increasing solubility in gasoline. (1) C6H5CH3; (II) C6H5CI; (III) C6H5OH; (IV) C6H5SH (A) III < IV < I| < | (B) I < || < IV < III (C) I < || < III < IV (D) IV < III < I < ||
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