Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
expand_more
expand_more
format_list_bulleted
Question
Chapter 8, Problem 27P
(a)
Interpretation Introduction
Interpretation:
The following order of water solubility should be explained.
Ethanol > chloroethane > ethane
Concept Introduction:
The property which refers to the ability of a substance usually known as solute to dissolves in a particular amount of solvent is known as solubility.
(b)
Interpretation Introduction
Interpretation:
The following order of water solubility should be explained.
Methanol > ethanol > 1-propanol
Concept Introduction:
The property which refers to the ability of a substance usually known as solute to dissolves in a particular amount of solvent is known as solubility.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
(a) Give a seperate chemical test to distinguish between the following pairs of compounds:(i) Ethanol and Phenol
(ii) 2-Pentanol and 3-Pentanol(b) Explain Kolbe’s reaction with the help of suitable example.
(i)
increasing solubility in water.
(CH3),CHCH,OH
CH;CH,CH,CH,OH
CH;CH,CH,Br
CH;CH,OCH3
(a)
(b)
(c)
(d)
least soluble
most soluble
(ii)
increasing stability.
CH
-CH3
H3C
-CH3
H3C
-CH3
H3C.
-CH3
(а)
(b)
(c)
(d)
least stable
stable
(iii)
increasing stability.
CH,CH3
CH3
CH,CH3
CH,CH3
CH,CH3
CH3
-CH3
`CH3 (CH3),CH´
(CH3),CH'
`CH3 (CH3),CH´
`CH
`CH3 (CH3),CH´
CH3
(d)
(a)
(b)
(c)
least stable
most stable
(iv)
increasing boiling point.
(CH3),COH
(CH3),CHCH,NH,
(CH3),CHCH,OH
(CH3),NCH,CH3
(a)
(b)
(c)
(d)
lowest bp
highest bp
Rank the following compounds according to increasing solubility in gasoline.
(1) C6H5CH3; (II) C6H5CI;
(III) C6H5OH;
(IV) C6H5SH
(A) III < IV < I| < |
(B) I < || < IV < III
(C) I < || < III < IV
(D) IV < III < I < ||
Chapter 8 Solutions
Organic Chemistry: Structure and Function
Ch. 8.1 - Prob. 8.1ECh. 8.1 - Prob. 8.2ECh. 8.3 - Prob. 8.4TIYCh. 8.3 - Prob. 8.5ECh. 8.3 - Prob. 8.6ECh. 8.4 - Prob. 8.7ECh. 8.5 - Prob. 8.8ECh. 8.5 - Prob. 8.9ECh. 8.5 - Prob. 8.10ECh. 8.5 - Prob. 8.11E
Ch. 8.5 - Prob. 8.12ECh. 8.6 - Prob. 8.14TIYCh. 8.7 - Prob. 8.15ECh. 8.7 - Prob. 8.16ECh. 8.8 - Prob. 8.18TIYCh. 8.8 - Prob. 8.19ECh. 8.8 - Prob. 8.21TIYCh. 8 - Prob. 24PCh. 8 - Prob. 25PCh. 8 - Prob. 26PCh. 8 - Prob. 27PCh. 8 - Prob. 28PCh. 8 - Prob. 29PCh. 8 - Prob. 30PCh. 8 - Prob. 31PCh. 8 - Prob. 32PCh. 8 - Prob. 33PCh. 8 - Prob. 34PCh. 8 - Prob. 35PCh. 8 - Prob. 36PCh. 8 - Prob. 37PCh. 8 - Prob. 38PCh. 8 - Prob. 39PCh. 8 - Prob. 40PCh. 8 - Prob. 41PCh. 8 - Prob. 42PCh. 8 - Prob. 43PCh. 8 - Prob. 44PCh. 8 - Prob. 45PCh. 8 - Prob. 46PCh. 8 - Prob. 47PCh. 8 - Prob. 48PCh. 8 - Prob. 49PCh. 8 - Prob. 50PCh. 8 - Prob. 51PCh. 8 - Prob. 52PCh. 8 - Prob. 53PCh. 8 - Prob. 54PCh. 8 - Prob. 55PCh. 8 - Prob. 56PCh. 8 - Prob. 57PCh. 8 - Prob. 58PCh. 8 - Prob. 59PCh. 8 - Prob. 60PCh. 8 - Prob. 61PCh. 8 - Prob. 62PCh. 8 - Prob. 63PCh. 8 - Prob. 64PCh. 8 - Prob. 65PCh. 8 - Prob. 66P
Knowledge Booster
Similar questions
- (B). Write the chemical reactions of 2-chloro-2-methylbutane with the following two sets of reagents/experimental conditions given below. In each case, denote the type of the chemical reaction: (i). NaOH/H2O/heat: (ii). NaOH/CH3CH2OH/heat:arrow_forwardGive the content and use of the following: (Explain it thoroughly) Ethanol Petroleum ether Dichloromethane KMnO4arrow_forwardRank the following compounds according to increasing solubility in water. (1) CH3CH2CH2OH (1I) CH3CH2CH2CH3 (III) CH3CH2-O-CH2CH3 (IV) CH3CH2OH (A) III < || < I < IV (B) IV < I < || < III (C) I| < III < I < IV (D) I < IV < |I < IIarrow_forward
- (b) (1-chloromethyl)cyclopentane, CeH11CI reacts with aqueous sodium hydroxide, NaOH to produce a primary alcohol AA. When CeH11Cl is added with magnesium, Mg in ether, an organometallic compound BB is formed. When compound BB reacts with ethanal, CH3CHO, a secondary alcohol cCis formed. The molecular structure of CeH11Cl is given below. (1-klorometil)siklopentana, CoH1,CI bertindak balas dengan akues natrium hidroksida, NaOH bagi menghasilkan satu alkohol primer AA. Apabila CeH11CI ditambah dengan magnesium, Mg dalam eter, sebatian organologam BB terbentuk. Apabila sebatian BB bertindak balas dengan etanal, CH;CHO, satu alkohol sekunder CC dihasilkan. Struktur molekul bagi CsH11CI diberikan di bawah. .CI (1-chloromethyl)cyclopentane (i) Draw the structural formula for compound AA through Cc. Lukiskan formula struktur bagi sebatian AA sehingga C. (ii) What is the type of reaction to produce compound AA? Apakah jenis tindak balas untuk menghasilkan sebatian AA?arrow_forwardWhat is(are) the major Organic product(s) in the following reaction? CH; CH; H₂C-C-0-CBr; CBr; CH; H₂C-C-0-CH; CH; CB13 Br3C C 0-CH₂ HBr (SNI) HC CH; H₂C-C-0-H CH, (b) CH; CH; Br CH;Br CH₂OH H;C CH, H₂C C | CH; CH; C CH; (c) H CH + CH₂Br CH; 0—C—CH; -CH:OCH:arrow_forwardDraw the structures for each of the following molecules. (a) 2-fluorotoluene; (b) 4-ethoxytoluene; (c) 2-ethoxyanisole;(d) 1,3-diphenylheptane; (e) 4,4-diphenyl-1-octene; (f) benzylbenzenearrow_forward
- (a) (i) 3-Methyl-2-butanol will react with sulphuric acid to give two isomeric alkenes in 3:1 proportions.(i) Write down the structures for these alkenes and assign appropriate systematic names to them. (ii) Name the most abundant isomer. (iii) Write down detailed mechanism for the formation of a minor product.arrow_forward(a) Answer the following questions based on the reaction scheme below. Jawab soalan berikut berdasarkan rajah tindak balas di bawah. H,SO, 180°C R OH+ Δ U NH, (i) State reagent Q. Nyatakan reagen Q. (ii) Draw the structural formula for compounds R, T, U and W. Lukiskan formula struktur bagi sebatian R, T, U dan W. PCI,arrow_forward2. (i) List all the intermolecular forces presented in the following substances. And list these substances in order of increasing boiling point (lowest first). CH;OCH; CH3CHO C2H6 CH3COOH C2H;OH (ii) State whether each compound is polar or non-polar, explain the order of boiling points in (1). (iii) Which of these two compounds, CH;OCH; and CH;CH2OH, would be more soluble in water and why?arrow_forward
- Which hydrocarbon (heptane, 1-octadecene) is expected to be more soluble in isopropanol? Why?arrow_forwardPropose and draw a structure for a molecule with molecular formula C3H,BrO and the following functional groups: ketone; aromatic ring; alkyl halide.arrow_forward(a) Draw the structure of the following :(i) p-Methylbenzaldehyde (ii) 4-Methylpent-3-en-2-one(b) Give chemical tests to distinguish between the following pairs of compounds :(i) Benzoic acid and Ethyl benzoate, (ii) Benzaldehyde and Acetophenone.(iii) Phenol and Benzoic acid.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY