The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane and KCl in DMF. Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry . In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene .

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Answer 1

Question

Chapter 7, Problem 47P

(a)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane and KCl in DMF.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(b)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KI in DMF.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(c)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KCl in CH₃NO₂.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(d)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with NH₃ in CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(e)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with NaOCH₂CH₃ in CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(f)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(g)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KOC(CH₃)₃ in (CH₃)₃COH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(h)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with (CH₃)₃P.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(i)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with CH₃COOH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

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Br Brz CH3 CH3 H3C CH2CI2 H3C Br Electrophilic addition of bromine, Br2; to alkenes yields a 1,2-dibromoalkane. The reaction proceeds through a cyclic intermediate known as a bromonium ion. The reaction occurs in an anhydrous solvent such as CH,Cl). In the second step of the reaction, bromide is the nucleophile and attacks at one of the carbons of the bromonium ion to yield the product. Due to steric clashes, the bromide ion always attacks the carbon from the opposite face of the bromonium ion so that a product with anti stereochemistry is formed. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions Br: :Br: .CH3 H3C H3C CH3 Br:

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Provide the curved-arrow mechanism to account for the following nucleophilic addition reaction. H20 EN NaOH NH2

Answer 2

Question

Chapter 7, Problem 47P

(a)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane and KCl in DMF.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(b)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KI in DMF.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(c)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KCl in CH₃NO₂.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(d)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with NH₃ in CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(e)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with NaOCH₂CH₃ in CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(f)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(g)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KOC(CH₃)₃ in (CH₃)₃COH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(h)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with (CH₃)₃P.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(i)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with CH₃COOH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

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Answer 3

Question

Chapter 7, Problem 47P

(a)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane and KCl in DMF.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(b)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KI in DMF.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(c)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KCl in CH₃NO₂.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(d)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with NH₃ in CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(e)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with NaOCH₂CH₃ in CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(f)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(g)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KOC(CH₃)₃ in (CH₃)₃COH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(h)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with (CH₃)₃P.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(i)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with CH₃COOH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

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Answer 4

Question

Chapter 7, Problem 47P

(a)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane and KCl in DMF.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(b)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KI in DMF.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(c)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KCl in CH₃NO₂.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(d)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with NH₃ in CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(e)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with NaOCH₂CH₃ in CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(f)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(g)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KOC(CH₃)₃ in (CH₃)₃COH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(h)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with (CH₃)₃P.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(i)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with CH₃COOH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

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Answer 5

Chapter 7, Problem 47P

(a)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane and KCl in DMF.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(b)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KI in DMF.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(c)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KCl in CH₃NO₂.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(d)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with NH₃ in CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(e)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with NaOCH₂CH₃ in CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(f)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(g)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KOC(CH₃)₃ in (CH₃)₃COH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(h)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with (CH₃)₃P.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(i)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with CH₃COOH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 6

Chapter 7, Problem 47P

(a)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane and KCl in DMF.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 7

Chapter 7, Problem 47P

(a)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane and KCl in DMF.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 8

(b)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KI in DMF.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 9

(b)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KI in DMF.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 10

(c)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KCl in CH₃NO₂.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 11

(c)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KCl in CH₃NO₂.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 12

(d)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with NH₃ in CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 13

(d)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with NH₃ in CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 14

(e)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with NaOCH₂CH₃ in CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 15

(e)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with NaOCH₂CH₃ in CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 16

(f)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 17

(f)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with CH₃CH₂OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 18

(g)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KOC(CH₃)₃ in (CH₃)₃COH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 19

(g)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KOC(CH₃)₃ in (CH₃)₃COH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 20

(h)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with (CH₃)₃P.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 21

(h)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with (CH₃)₃P.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 22

(i)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with CH₃COOH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 23

(i)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with CH₃COOH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 24

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Answer 25

Expert Solution & Answer

Answer 26

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Answer 27

Ch. 7.1 - Prob. 7.1E Ch. 7.2 - Prob. 7.2E Ch. 7.3 - Prob. 7.3E Ch. 7.3 - Prob. 7.5TIY Ch. 7.4 - Prob. 7.7TIY Ch. 7.5 - Prob. 7.9TIY Ch. 7.6 - Prob. 7.10E Ch. 7.7 - Prob. 7.11E Ch. 7.7 - Prob. 7.12E Ch. 7.7 - Prob. 7.13E

Solution Summary: The author explains the nucleophillic substitution and elimination reactions in the reaction between 2-bromo-2methylpropane and KCl in DMF.

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