Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 7, Problem 70P
Interpretation Introduction
Interpretation:The reaction intermediate that is involved in the following reaction should be determined:
Concept introduction:The type of
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4. What are the products from the following reaction?
H3O+
کا
Questão 10A certain hydrocarbon had the molecular formula C16H26 and contained two triple bonds. Ozonolysis resulted in CH3(CH2)4CO2H and HO2CCH2CH2CO2H as the only products. What is the reasonable structure for this hydrocarbon?
Hexadec-6,10-dino
undec-1,5-dino
Hept-1,5-dino
hex-1,5-dino
nah
The following reaction is an example
of a
reaction.
H H
нн
Heat or light
H-C-C- H + Cl–CI
H-C-C-cı: + H-Ci:
нн
нн
ethane
chloroethane
Substitution
O Elimination
O Hydrogenation
Chlorination
Chapter 7 Solutions
Organic Chemistry: Structure and Function
Ch. 7.1 - Prob. 7.1ECh. 7.2 - Prob. 7.2ECh. 7.3 - Prob. 7.3ECh. 7.3 - Prob. 7.5TIYCh. 7.4 - Prob. 7.7TIYCh. 7.5 - Prob. 7.9TIYCh. 7.6 - Prob. 7.10ECh. 7.7 - Prob. 7.11ECh. 7.7 - Prob. 7.12ECh. 7.7 - Prob. 7.13E
Ch. 7.7 - Prob. 7.15TIYCh. 7.8 - Prob. 7.16ECh. 7.8 - Prob. 7.17ECh. 7.9 - Prob. 7.18ECh. 7.9 - Prob. 7.19ECh. 7.9 - Prob. 7.20ECh. 7.9 - Prob. 7.21ECh. 7.9 - Prob. 7.22ECh. 7 - Prob. 25PCh. 7 - Prob. 26PCh. 7 - Prob. 27PCh. 7 - Prob. 28PCh. 7 - Prob. 29PCh. 7 - Prob. 30PCh. 7 - Prob. 31PCh. 7 - Prob. 32PCh. 7 - Prob. 33PCh. 7 - Prob. 34PCh. 7 - Prob. 35PCh. 7 - Prob. 36PCh. 7 - Prob. 37PCh. 7 - Prob. 38PCh. 7 - Prob. 39PCh. 7 - Prob. 40PCh. 7 - Prob. 41PCh. 7 - Prob. 42PCh. 7 - Prob. 43PCh. 7 - Prob. 44PCh. 7 - Prob. 45PCh. 7 - Prob. 46PCh. 7 - Prob. 47PCh. 7 - Prob. 48PCh. 7 - Prob. 49PCh. 7 - Prob. 50PCh. 7 - Prob. 51PCh. 7 - Prob. 52PCh. 7 - Prob. 53PCh. 7 - Prob. 54PCh. 7 - Prob. 55PCh. 7 - Prob. 56PCh. 7 - Prob. 57PCh. 7 - Prob. 58PCh. 7 - Prob. 59PCh. 7 - Prob. 60PCh. 7 - Prob. 61PCh. 7 - Prob. 62PCh. 7 - Prob. 63PCh. 7 - Prob. 64PCh. 7 - Prob. 65PCh. 7 - Prob. 66PCh. 7 - Prob. 67PCh. 7 - Prob. 68PCh. 7 - Prob. 69PCh. 7 - Prob. 70P
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- What is the major product for | the following reaction? * ÇH3 CH;C-CH=CH, + HCI major product , 3-chloro-2,2-dimethylpentane 2-chloro-2,3-dimethylbutane 3-chloro-2,2-dimethylpropane 3-chloro-2,2-dimethylbutane 3-chloro-2,3-dimethylpentane 2-chloro-2,3-dimethylpentane 2-chloro-3,4-dimethylbutane 2-chloro-2,2-dimethylbutanearrow_forwardWhat is the organic product formed in the following reaction? C6H5-CH=CH-C-C6H5 ÷ (CH3CH2)2NH O C6H-CH-CH-C-C6H5 (CH3CH2)2N || III CH-CH, CH- (CH3CH2)2N -CH OH IV O-N(CH2CH3)2 C6H3-CH=CH-C-CH¸ CH-CH=CH-C-CHS (CH3CH₁₂N Select one: A. IV B. II OC. III D. I F1 10: - F2 80 F3 000 000 FAarrow_forwardAlcohols undergo an oxidation reaction to yield carbonyl compounds on treatment with CrO3. For example, 2-tert-butylcyclohexanol gives 2-tert-butylcyclohexanone. If axial OH groups are generally more reactive than their equatorial isomers, which do you think reacts faster, the cis isomer of 2-tert-butylcyclohexanol or the trans isomer? Explain.arrow_forward
- Draw structural formulas for all possible carbocations formed by the reaction of each alkene with HC1. Label each carbocation as primary, secondary, or tertiary. ch3 I ch3ch,c=chch3 ch3ch2ch=chch3arrow_forwardDraw the alkene reactant of the following reaction. n 6 H3o+ H3C OH H20arrow_forwardDraw structures for the alkene (or alkenes) that gives the following reaction product. H3C ? H₂/Pd H3C CH₂CH3 CH3arrow_forward
- This reaction is an example of: H H OOOOO H Halogenation Reduction Substitution Addition Oxidation H H₂SO4 concentrated heat H H SO3H H H H + H₂Oarrow_forward4. A student was asked to prepare an alkene X in high yield using any alcohol as starting material CH3 CH,-C -CH=CH, CH3 X He chose 3, 3-dimethylbutan-2-ol (XI) and carried out a dehydration reaction. He was however horrified to note that the only alkene obtained was XII. CH3 OH CH3 CH;-C=C-CH3 conc. H,SO4 CH-CH3 heat CH3 CH3 XI XII i) Explain what went wrong here, and why X could not be formed from 3, 3-dimethylbutan-2-ol. Use structures to help support your answer. ii) Give an equation to show a much better method for preparing X in high yield. 5. Analyze the following structure and write one combination for Grignard reagent and a carbonyl that would give rise to it. CH,-CH,-OHarrow_forwardIn the reaction given below, what type of reaction is used? n-Pentane → Isopentane нннн H ITH Н—С—с—С—с —О —Н Н—с—с— с-с—н ||| | H нн H Addition Elimination Substitution Rearrangementarrow_forward
- convert 1,2-dimethylcyclohexane to trans-1,2-dimethyl-1,2-dihydroxycyclohexane?list reagents in order usedarrow_forwardWhat reagent/reagents is/are necessary to transform the starting molecule into the desired product? CH3 CH2BRarrow_forwardThe reaction of 3-methylene-1-cyclohexene and HBr yields the four products shown in the attachment. Which two are formed at high temperatures and which two are formed at low temperatures? Why? Why is 1-bromo-3-methylenecyclohexane not formed?arrow_forward
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