Organic Chemistry: Structure and Function
Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 1.9, Problem 1.22E

(a)

Interpretation Introduction

Interpretation:Thedashed-wedged line formulas for the isomers of C4H10 needs to be determined.

Concept Introduction:Constitutional isomers are the isomers with same molecular formula but different arrangement of bonded atoms in the molecule. Since they have same molecular formula but different bonding of atoms therefore they exhibit different properties. There are different ways to represent the structural formula such as line formula, wedge formula, condense formula etc.

  Organic Chemistry: Structure and Function, Chapter 1.9, Problem 1.22E

(b)

Interpretation Introduction

Interpretation:Thebond line notation for the structure of benzylpenicillin, cubane and saccharine needs to be drawn.

Concept Introduction: Constitutional isomers are the isomers with same molecular formula but different arrangement of bonded atoms in the molecule. Since they have same molecular formula but different bonding of atoms therefore they exhibit different properties. There are different ways to represent the structural formula such as line formula, wedge formula, condense formula etc.

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a) Draw two different enol tautomers of 2-methylcyclohexanone. (b) Draw two constitutional isomers that are not tautomers, but contain a C = C and an OH group.
(a) Identify the functional groups in salinosporamide A, an anticancer agent isolated from marine sediment. (b) Classify each alcohol, alkyl halide, amide, and amine as 1°, 2°, or 3°.
(a) Identify the functional groups in salinosporamide A, an anticanceragent isolated from marine sediment. (b) Classify each alcohol, alkylhalide, amide, and amine as 1°, 2°, or 3°.
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