Organic Chemistry: Structure and Function
Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 1, Problem 45P

(a)

Interpretation Introduction

Interpretation: The condensed formula should be converted to hashed and wedged form.

  Organic Chemistry: Structure and Function, Chapter 1, Problem 45P , additional homework tip  1

Concept introduction:There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

  Organic Chemistry: Structure and Function, Chapter 1, Problem 45P , additional homework tip  2

(b)

Interpretation Introduction

Interpretation: The condensed formula of CHCl3 should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

  Organic Chemistry: Structure and Function, Chapter 1, Problem 45P , additional homework tip  3

(c)

Interpretation Introduction

Interpretation: The condensed formula of ( CH3)2NH should be converted to hashed and wedged form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

  Organic Chemistry: Structure and Function, Chapter 1, Problem 45P , additional homework tip  4

(d)

Interpretation Introduction

Interpretation: The condensed formula should be converted to hashed and wedged form.

  Organic Chemistry: Structure and Function, Chapter 1, Problem 45P , additional homework tip  5

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

  Organic Chemistry: Structure and Function, Chapter 1, Problem 45P , additional homework tip  6

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I have given you a condensed structure. You need to convert it to an accurate bond-line structure. CH3 CH3-CH-CH2-CH-CH₂-C-H 12-CH-CH2₂-C-1 CI Draw (as bond-line structures) isomers of this compound where you only move the chlorine atom. Draw four isomers of the original compound that would have a five carbon chain as the longest chain. [Note: there would be many isomers that will satisfy this. Find any four.] Using the original molecule (and looking at the carbon next to the aldehyde carbonyl) what would be the charge on that carbon if I removed an H atom and left behind the pair of electrons? Circle the best answer Positive Negative Neutral In the space below, draw that structure (from the sentence above) as a bond-line structure. Then, draw a resonance structure for this ion and be sure to add curved arrows to show the movement of electrons.
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