Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 1.3, Problem 1.2E
Interpretation Introduction
Interpretation:The electron-dot pictures for ionic compound LiBr, Na2O, BeF2, AlCl3 and MgS should be drawn.
Concept introduction:The formation of ion takes place either by lose of electron(s) to make cations or by addition of electron(s) to make anions. Generally, the addition or loss of electron(s) takes place in an atom to have eight electrons in their valence shell said to be octet rule.
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4. The common oxidation number for an alkaline earth metal is +2.
(a) Using the Born-Mayer equation (for determining the lattice enthalpy) and a Born-Haber
cycle (draw it), show that CaCl is an exothermic compound (negative AHf). Make a
reasonable prediction to estimate the ionic radius of Ca (explain your reasoning). The
sublimation (atomization) enthalpy for Ca(s) is 178 kJ/mol.
(b) Show that an explanation for the non-existence of CaCl can be found in the enthalpy
change for the reaction below. The AHf for CaCl2(s) is -190.2 kcal/mol.
2 CaCl(s) → Ca(s) + CaCl2(s)
AL, TI, SR
1. Identify which element (from above) will have the largest atomic radius
2. Identify which element (from above) will have the highest electronegativity (hardest to remove an electron).
Write the chemical formula for manganese(V) hydrogen carbonate
Chapter 1 Solutions
Organic Chemistry: Structure and Function
Ch. 1.3 - Prob. 1.1ECh. 1.3 - Prob. 1.2ECh. 1.3 - Prob. 1.3ECh. 1.3 - Prob. 1.4ECh. 1.3 - Prob. 1.5ECh. 1.4 - Prob. 1.6ECh. 1.4 - Prob. 1.8TIYCh. 1.5 - Prob. 1.9ECh. 1.5 - Prob. 1.11TIYCh. 1.6 - Prob. 1.12E
Ch. 1.6 - Prob. 1.13ECh. 1.7 - Prob. 1.15TIYCh. 1.8 - Prob. 1.16ECh. 1.8 - Prob. 1.18TIYCh. 1.9 - Prob. 1.19ECh. 1.9 - Prob. 1.20ECh. 1.9 - Prob. 1.21ECh. 1.9 - Prob. 1.22ECh. 1 - Prob. 25PCh. 1 - Prob. 26PCh. 1 - Prob. 27PCh. 1 - Prob. 28PCh. 1 - Prob. 29PCh. 1 - Prob. 30PCh. 1 - Prob. 31PCh. 1 - Prob. 32PCh. 1 - Prob. 33PCh. 1 - Prob. 34PCh. 1 - Prob. 35PCh. 1 - Prob. 36PCh. 1 - Prob. 37PCh. 1 - Prob. 38PCh. 1 - Prob. 39PCh. 1 - Prob. 40PCh. 1 - Prob. 41PCh. 1 - Prob. 42PCh. 1 - Prob. 43PCh. 1 - Prob. 44PCh. 1 - Prob. 45PCh. 1 - Prob. 46PCh. 1 - Prob. 47PCh. 1 - Prob. 48PCh. 1 - Prob. 49PCh. 1 - Prob. 50PCh. 1 - Prob. 51PCh. 1 - Prob. 52PCh. 1 - Prob. 53PCh. 1 - Prob. 54PCh. 1 - Prob. 55PCh. 1 - Prob. 56PCh. 1 - Prob. 57PCh. 1 - Prob. 58P
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