Organic Chemistry: Structure and Function
Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 1, Problem 47P

(a)

Interpretation Introduction

Interpretation:Condensed formula that shows multiple bonds, lone pairs should be drawn for the pair HCCCH3 and H2CCCH3 .

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

  Organic Chemistry: Structure and Function, Chapter 1, Problem 47P , additional homework tip  1

(b)

Interpretation Introduction

Interpretation: Condensed formula that shows multiple bonds, lone pairs should be drawn for the pair CH3CN and CH3NC .

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

  Organic Chemistry: Structure and Function, Chapter 1, Problem 47P , additional homework tip  2

(c)

Interpretation Introduction

Interpretation: Condensed formula that shows multiple bonds, lone pairs should be drawn for the pair H3CCHO and H2CCHOH .

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance the propane is written in this notation as follows:

  Organic Chemistry: Structure and Function, Chapter 1, Problem 47P , additional homework tip  3

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Provide a reasonable Lewis structure below each molecular formula. Please note that you must indicate the proper number of lone pairs CH3CH2OCH3   (CH3)3NH Na OCH(CH3)2           AlCl3 H3CCH(OH)CH2CO2H       H3CCNO
1. For each of the following compounds and ions, draw the complete Lewis structure. All formal charges should be on the atoms that possess that formal charge. CH4 H3CBr CH3CH₂OH H₂S H₂SO4 (sulfuric acid) H³0+ CH3* 2. Convert the following condensed formulas into bond-line structures, making sure to draw in zig-zag formation. CH3CH₂CH₂CH₂CH₂CH₂CH₂CH3 FCH₂CH₂I H₂C=CHCH₂OH (CH3)2CHCOOH
Draw the Lewis structures for the following three molecules. Rank the molecules in terms of C-N bond length, from shortest (1) to longest (3) C-N bond length. CH3NH2 CH3CN CH2NCH3
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