Concept explainers
(a)
Interpretation:The better nucleophile out of
Concept introduction:Nucleophile is an electron rich, negative ion or a molecule with an electronegative atom & lone pairs of electrons.
(b)
Interpretation: The better nucleophile out of
Concept introduction: Nucleophile is an electron rich, negative ion or a molecule with an electronegative atom & lone pairs of electrons.
(c)
Interpretation: The better nucleophile out of
Concept introduction: Nucleophile is an electron rich, negative ion or a molecule with an electronegative atom & lone pairs of electrons.
(d)
Interpretation: The better nucleophile out of
Concept introduction: Nucleophile is an electron rich, negative ion or a molecule with an electronegative atom & lone pairs of electrons.
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Organic Chemistry: Structure and Function
- Aircraft de-icing agents, such as propylene glycol [1,2-propanediol; CH₃CH(OH)CH₂OH; d=1.036 g/mL], are used toremove ice and snow prior to winter flights, but their presence inrunoff depletes O₂ in natural waters. (a) Write a balanced equa-tion for the complete oxidation of propylene glycol by O₂.(b) What is the “theoretical oxygen demand,” in grams of O₂ required per gram of propylene glycol oxidized? (c) What is thetheoretical oxygen demand, in grams of O₂ required per liter ofsolution, of 90.0% by volume aqueous propylene glycol?arrow_forward(b) NABH, CH3 COCH,CH3 CH3CH2OH (c)arrow_forwardWrite an equation to show the proton transfer between each alkene or cycloalkene and HCl. Where two carbocations are possible, show each. (a) CH,CH,CH=CHCH, (b) 2-Pentene Cyclohexenearrow_forward
- Write the equilibrium-constant expressions and obtain numerical values for each constant in (a) the basic dissociation of aniline, C6H5NH2. (b) the acidic dissociation of hypochlorous acid, HClO. (c) the acidic dissociation of methyl ammonium hydrochloride, CH3NH3Cl. (d) the basic dissociation of NaNO2. (e) the dissociation of H3AsO3 to H3O+ and AsO33- just answer the letters C, D and E.arrow_forward(a) What is the K(b) of the benzoate ion, C₆H₅COO?(b) What is the Kₐ of the 2-hydroxyethylammonium ion,HOCH₂CH₂NH₃⁺(pK(b) of HOCH₂CH₂NH₂=4.49)?arrow_forwarda) If the pH value of an aqueous solution of trimethylamine [(CH3) 3N] is 10.75, what should be the molarity of this solution? (CH3) 3N + H2O ↔ (CH3) 3NH + + OH-, Kb = 6.3 × 10-5 b) What will be the pH of the solution prepared by dissolving 8.35 g of aniline hydrochloride (C6H5NH3 + Cl-) in 750 mL of 0.215 M aniline (C6H5NH2)? Is this solution an effective buffer? Explain (Kb = 7.4 × 10-10 for aniline, C: 12.0 g / mol, H: 1.0 g / mol, N: 14.0 g / mol, Cl: 35.4 g / mol) .arrow_forward
- (a) (b) HO N N-H Catalytic H+ (-H₂O) ? (c) NH2 HO N (d)arrow_forwardDraw the structure of the predominant form of CF3CH2OH (pK a = 12.4) at pH = 6.arrow_forwarda) If the pH value of an aqueous solution of trimethylamine [(CH3)3N] is 10.75, what should be the molarity of this solution? (CH3)3N + H2O ↔ (CH3)3NH+ + OH-, Kb = 6,3 × 10-5 b) What will be the pH of the solution prepared by dissolving 8.35 g of aniline hydrochloride (C6H5NH3+Cl-) in 750 mL of 0.215 M aniline (C6H5NH2)? Is this solution an effective buffer? Explain (Kb = 7,4 × 10-10 for aniline, C: 12.0 g / mol, H: 1.0 g / mol, N: 14.0 g / mol, Cl: 35.4 g / mol) .arrow_forward
- Identify which of the statements is/are correct. (i) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O. (j) The molecular formula of the smallest carboxylic acid is C2H4O2.arrow_forwardDraw the product formed when (CH3CH2)3N:, a Lewis base, reacts with each Lewis acid: (a) B(CH3)3; (b) (CH3)3C+; (c) AlCl3.arrow_forwardChemical Equilibrium Write the equilibrium-constant expressions and obtain numerical values for each constant in (a) the basic dissociation of aniline, C6H5NH2. (b) the acidic dissociation of hypochlorous acid, HClO. (c) the acidic dissociation of methyl ammonium hydrochloride, CH3NH3Cl. (d) the basic dissociation of NaNO2. (e) the dissociation of H3AsO3 to H3O+ and AsO33- Using step-by-step processarrow_forward
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