Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 6, Problem 65P
Interpretation Introduction
Interpretation: The type of substrates best suited for
Concept introduction: Bimolecular substitution or
A general
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7. What is the major organic product obtained from the following reaction?
a. 1
b. 2
c. 3
d. 4
CH3
1. BH3
2. H₂O2. NaOH
CH3
CH3
H3C
OH
HO
CH3
OH
"OH
OH
3
What product(s) will form:
2-Pentene + H₂O →
O a.
2-Pentanol
O b. Isopropyl alcohol
O c. 3-Pentanol
O d. a 50/50 mixture of 2-Pentanol and 3-Pentanol
Oe. no reaction will occur
12. What is the product of the following sequence of
reactions?
A. I
B. II
C. III
D. IV
I
NaOH
NaNH,
III
IV
NH₂
1
Chapter 6 Solutions
Organic Chemistry: Structure and Function
Ch. 6.2 - Prob. 6.1ECh. 6.2 - Prob. 6.3TIYCh. 6.3 - Prob. 6.4ECh. 6.3 - Prob. 6.5ECh. 6.3 - Prob. 6.6ECh. 6.3 - Prob. 6.7ECh. 6.3 - Prob. 6.8ECh. 6.4 - Prob. 6.10TIYCh. 6.4 - Prob. 6.11ECh. 6.5 - Prob. 6.12E
Ch. 6.5 - Prob. 6.13ECh. 6.6 - Prob. 6.14ECh. 6.6 - Prob. 6.16TIYCh. 6.6 - Prob. 6.17ECh. 6.7 - Prob. 6.18ECh. 6.7 - Prob. 6.19ECh. 6.7 - Prob. 6.20ECh. 6.8 - Prob. 6.21ECh. 6.8 - Prob. 6.22ECh. 6.8 - Prob. 6.23ECh. 6.8 - Prob. 6.24ECh. 6.9 - Prob. 6.26TIYCh. 6.10 - Prob. 6.27ECh. 6.10 - Prob. 6.28ECh. 6 - Prob. 31PCh. 6 - Prob. 32PCh. 6 - Prob. 33PCh. 6 - Prob. 34PCh. 6 - Prob. 35PCh. 6 - Prob. 36PCh. 6 - Prob. 37PCh. 6 - Prob. 38PCh. 6 - Prob. 39PCh. 6 - Prob. 40PCh. 6 - Prob. 41PCh. 6 - Prob. 42PCh. 6 - Prob. 43PCh. 6 - Prob. 44PCh. 6 - Prob. 45PCh. 6 - Prob. 46PCh. 6 - Prob. 47PCh. 6 - Prob. 48PCh. 6 - Prob. 49PCh. 6 - Prob. 50PCh. 6 - Prob. 51PCh. 6 - Prob. 52PCh. 6 - Prob. 53PCh. 6 - Prob. 54PCh. 6 - Prob. 55PCh. 6 - Prob. 56PCh. 6 - Prob. 57PCh. 6 - Prob. 58PCh. 6 - Prob. 59PCh. 6 - Prob. 60PCh. 6 - Prob. 61PCh. 6 - Prob. 62PCh. 6 - Prob. 63PCh. 6 - Prob. 64PCh. 6 - Prob. 65PCh. 6 - Prob. 66PCh. 6 - Prob. 67PCh. 6 - Prob. 68P
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- compound c compound f Reagents compound e a. HBr m. 2 equivalents of NaNH2 b. HBr, H2O2, hv H2, Lindlar's catalyst Na / NH3 H2SO4, H9SO4 (sia)2BH then H2O2, NaOH n. m c. H2O, H2SO4 d. Br2 e. Cl2 f. H2, Pd g. Br2, H20 h. Cl2, H2O i. O. d. compound b compound d p. q. 1 equivalent of NANH2 r. S. NBS, hv compound a Br2, hy Cl2, hy t. Os04 then NaHSO3 j. Hg(OAc)2, H2O then NaBH4 k. BH3 then H2O2, NaOH I. u. V. HCI w. (CH3)3CO'K* Og then (CH3)2S The above synthesis was designed using the Organic Chemistry Roadmaps in the appendix of your textbook. In this synthesis, reagents from the table are used to carry out the indicated steps (shown in blue). In the box below, draw the structure of compound c.arrow_forward105. Determine the one or two steps it takes to get from the starting material to the product using the reactions found in this chapter. a. b. H₂C-C OH *-* OH H₂C-C H₂C H₂C U=O CH₂ CH₂-OH CH3-CH-CH₂-CH-CH3 I CH₂ - CH3 CH3–CH2–C-CH, CH3 O CH₂ || CH3-CH-CH₂-C-CH3 CH₂CH3 Br CH3 CH₂-C-CH3 CH3arrow_forwardWhat is the major product of the following reaction? a. d. HBr, heat -Br & EX C. Br g. NR Br ? b. afad Br f. Br Brarrow_forward
- 3. Predict the product(s) that forms and explain why it forms. a. b. HN MeO OH 1. NaOH 2. MeBr محمد 1. NaNH,arrow_forwardReaction Product/s a. C,H1, + O2 b. Butane+ CI, c. Propanearrow_forward22. Write the structure(s) of the product(s) for each of the reactions below. a. b. C. 1. NBS, CC14 2. KOC(CH3)3, HOC(CH3)3 H₂O H₂SO4 HBr etherarrow_forward
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- Reagents m. 2 equivalents of NaNH2 H2, Lindlar's catalyst Na / NH3 p. H2SO4, HgSO4 q. (sia)2BH then H2O2, NaOH 1 equivalent of NaNH2 a. HCI b. HBr n. c. H20, H2SO4 d. Br2 0. n Cl2 е. H2, Pd g. Br2, H20 h. Cl2, H2O f. r. compound a Os04 then NaHSO3 j. Hg(OAc)2, H20 then NABH4 k. BH3 then H2O2, NaOH Oz then (CH3)2S i. compound b I. The above synthesis was designed using the Organic Chemistry Roadmaps in the appendix of your textbook. In this synthesis, reagents from the table (shown in blue) are used to carry out the indicated reactions. In the box below, draw the structure of compound b. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • Consider E/Z stereochemistry of alkenes. • If more than one structure fits the description, draw them all. • If a compound is formed more than once, add another sketcher and draw it again. • If the reaction produces a racemic mixture, draw both stereoisomers. Separate structures with + signs from the drop-down menu.arrow_forward1. Complete the following reactions by writing missing reactant(s), reagent(s), or product(s). a. b. C. OH SOCI₂ (CH3CH₂)2CuLi ola OCH3 i. 2 PhMgCl ii. H₂O OHarrow_forwardWrite the reaction between ammonia, NH3, and hydrosulfuric acid, H2S. NH3 + + In this reaction completes the reactant side while and complete the products side. а. NH3 b. NH4+1 с. HS-1 d. H2S е. Н20 f. H30+1 9. ОН-1arrow_forward
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