Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
expand_more
expand_more
format_list_bulleted
Question
Chapter 3.1, Problem 3.2TIY
Interpretation Introduction
Interpretation:The reason behind the decreased bond strength in the series
Concept introduction:There are several factors that contribute to the strength of a bond and they are as follows:
The orbitals of bonds if matched betterin size and energy then lead to effective overlap and thus it is difficult to cleave such strong bonds.If the polarity between the atoms that overlap is greater then greater extent of columbic attraction that reinforces the bond.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Draw the complete Lewis structure of (CH3)2CHCH(NH2)CO2H and identify all H-bond donors and all H-bond acceptors.
1: In the sweetening MEROX process for kerosene the mercaptans are converted into
(a) Sulpher (b) Disulphide (c) Hydrogen sulphide (d) None of these
2: Which of the following products contain maximum sulphur?
(a) Diesel fuel (b) Fuel oil (c) Jet fuel (d) LPG
3: Which of the following petroleum product has a maximum C/H ratio (by weight)?
(a) Light diesel oil (b) Fuel oil (c) Naphtha (d) Heating oil
4: Which of the following hydrocarbon are most desirable in gasoline?
(a) Paraffins (b) Isoparaffins (c) Naphthenes (d) Aromatic
5: Octane no. of paraffins:
(a) Remain constant with change in the number of carbon atoms
(b) Increases with increase in the number of carbon atoms
(c)Decreases with increase in the number of carbon atoms
(d)None of the above
6: Which of the following hydrocarbons has a maximum octane number?
(a) Benzene (b) Cyclohexane (c) Hexane (d) Iso-hexane
7: Which of the following petroleum products has a minimum flashpoint?
(a)Gasoline (b) Kerosene (c) Fuel oil (d) Heating…
Select the bonds in the 3D representation of methyl urethane below that are multiple bonds.
(Hint: Consider the number of bonds attached to an atom in the image compared to the normal valence of that atom. In a valid structure, the number of bonds to an atom will equal the valence of that atom.)
• Gray = C: white = H; red = 0; blue = N; dark green = Cl; brown = Br; light green = F; purple = 1; yellow = S: orange = P.
• Double click to select bonds.
You can zoom in and out using the mouse scroll wheel (or pinch to zoom on touch screens).
●
Chapter 3 Solutions
Organic Chemistry: Structure and Function
Ch. 3.1 - Prob. 3.2TIYCh. 3.1 - Prob. 3.3ECh. 3.4 - Prob. 3.5TIYCh. 3.5 - Prob. 3.6ECh. 3.7 - Prob. 3.7ECh. 3.7 - Prob. 3.9TIYCh. 3.9 - Prob. 3.11TIYCh. 3.11 - Prob. 3.12ECh. 3 - Prob. 15PCh. 3 - Prob. 16P
Ch. 3 - Prob. 17PCh. 3 - Prob. 18PCh. 3 - Prob. 19PCh. 3 - Prob. 20PCh. 3 - Prob. 21PCh. 3 - Prob. 22PCh. 3 - Prob. 23PCh. 3 - Prob. 24PCh. 3 - Prob. 25PCh. 3 - Prob. 26PCh. 3 - Prob. 27PCh. 3 - Prob. 28PCh. 3 - Prob. 29PCh. 3 - Prob. 30PCh. 3 - Prob. 31PCh. 3 - Prob. 32PCh. 3 - Prob. 33PCh. 3 - Prob. 34PCh. 3 - Prob. 35PCh. 3 - Prob. 36PCh. 3 - Prob. 37PCh. 3 - Prob. 38PCh. 3 - Prob. 39PCh. 3 - Prob. 40PCh. 3 - Prob. 41PCh. 3 - Prob. 42PCh. 3 - Prob. 43PCh. 3 - Prob. 44PCh. 3 - Prob. 45PCh. 3 - Prob. 46PCh. 3 - Prob. 47PCh. 3 - Prob. 48PCh. 3 - Prob. 49PCh. 3 - Prob. 50PCh. 3 - Prob. 51P
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 2. Calculate AH for the reaction; C₂H₂ (s) → 2 C (s) + H₂ (g), from the following Data; 1) CO2 (g) → C (s) +O2 (g) 2) 2 H₂O (1)→ → 2 2 H2 H2 (g) + O2 (g) 3) 2 C2H2 (s) + 5 O2 (g) → 4 CO2 (g) + 2 H₂O (1) ΔΗ = +394 kJ ΔΗ = +572 kJ AH = -2600 kJarrow_forwardCompare the polarity of the C-Cl bond in (CH3)3C-Cl with the polarity of the Si-Cl bond in (CH3)3Si-Cl.arrow_forward(a) How does the structure of diborane (B2H6) differ fromthat of ethane (C2H6)? (b) Explain why diborane adoptsthe geometry that it does. (c) What is the significance ofthe statement that the hydrogen atoms in diborane aredescribed as “hydridic”?arrow_forward
- Two useful organic compounds that contain Cl atoms are vinyl chloride (CH2 = CHCI) and chloroethane (CH;CH;CI). Vinyl chloride is the starting material used to prepare poly (vinyl chloride), a plastic used in insulation, pipes, and bottles. Chloroethane (ethyl chloride) is a local anesthetic. Why is the C – Cl bond of | vinyl chloride stronger than the C – Cl bond in chloroethane.arrow_forwardWhich compound in each of the following pairs would have the higher .boiling point? Explain your answers (1) or HO, (a) (b) (2) HO. OH or (a) (Б) (3) -OH or (a) (Ь)arrow_forwardOne of the steps in fat metabolism is the hydration of crotonate to yield 3-hydroxybutyrate. This reaction occurs by addition of —OH to the Si face at C3, followed by protonation at C2, also from the Si face. Draw the product of the reaction, showing the stereochemistry of each step.arrow_forward
- Your chemistry professor draws a number of molecules on the board: (1) CH4 ; (2) H2C=CH2 ; (3) H2C=C=CH2 ; and (4) H2C=C=C=CH2. You muse about all the molecules that chemists draw on a two-dimensional board and wonder which ones are actually planar, existing basically as they appear on the board, and which ones are not plane but rather three-dimensional. Answer ALL of the following questions. What are the specific orbital overlaps (i.e., sp3-sp3) that are in each of the molecules? What are the bond angles for each central atom in each molecule? Which molecules are planar and which are non-planar?arrow_forwardc) 1) OsO4 2) H2S NaOMe Ph MeOH OTsarrow_forwardDraw Lewis structures and condensed structural formulas for the four alcohols with the molecular formula C4H10O. Classify each alcohol as primary, secondary, or tertiary. (Hint: First consider the connectivity of the four carbon atoms; they can be bonded either four in a chain or three in a chain with the fourth carbon as a branch on the middle carbon. Then consider the points at which the iOH group can be bonded to each carbon chain.)arrow_forward
- Your chemistry professor draws a number of molecules on the board: (1) CH4 ; (2) H2C=CH2 ; (3) H2C=C=CH2 ; and (4) H2C=C=C=CH2. You muse about all the molecules that chemists draw on a two-dimensional board and wonder which ones are actually planar, existing basically as they appear on the board, and which ones are not plane but rather three-dimensional. Answer the following questions. What is the geometry and hybridization of the carbon in CH4? What is the geometry and hybridization of each central carbon atom in the remaining molecules? Draw each molecule showing the bonds and identify each bond in all the molecules as s or p. What are the specific orbital overlaps (i.e., sp3-sp3) that are in each of the molecules? What are the bond angles for each central atom in each molecule? Which molecules are planar and which are non-planar?arrow_forward-C≡C-C6H5 what is this mass of this?arrow_forwardIn this chapter, we did not discuss the interaction that is primarily responsible for the attraction that exists between an anion like CH30¯ and a nonpolar molecule like Br2. (a) What name would be ascribed to the strongest interaction that exists between those two species? (b) For which pair of species would you expect that type of attractive interaction to be stronger: between CH30¯ and Br2 or between CH30¯ and I2? Why?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Group Theory - Learn like Expert with 3D animation | Introduction for Beginners | ONE Chemistry; Author: One Chemistry;https://www.youtube.com/watch?v=Lz2ih8fkgDs;License: Standard YouTube License, CC-BY