Organic Chemistry: Structure and Function
Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 3, Problem 36P
Interpretation Introduction

Interpretation: The mechanism of chlorination of methane with SO2Cl2 as initiator should be written.

Concept introduction: The monochlorination performed with ultraviolet light proceeds via radical chain mechanism. Chlorine transforms CH4 into chloromethane as the major halogenated product with variety of side products due to various possibilities of chain termination.

The fundamental radical chain mechanism is summarized in the illustration below:

  Organic Chemistry: Structure and Function, Chapter 3, Problem 36P

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