(a)
Interpretation: The isomeric products obtained after monobromination of propane should be drawn.
Concept introduction: The monobromination performed with ultraviolet light proceeds via radical chain mechanism.
Tertiary
The phenomenon of hyperconjugation refers to donation of
(b)
Interpretation: The approximate ratio of products obtained, major product of monobromination and whether the selectivity exhibited by bromine is sufficient enough for formation of isomeric products in good yields should be drawn.
Concept introduction: The monobromination performed with ultraviolet light proceeds via radical chain mechanism.
Tertiary
The phenomenon of hyperconjugation refers to donation of
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Organic Chemistry: Structure and Function
- (a) (i) 3-Methyl-2-butanol will react with sulphuric acid to give two isomeric alkenes in 3:1 proportions.(i) Write down the structures for these alkenes and assign appropriate systematic names to them. (ii) Name the most abundant isomer. (iii) Write down detailed mechanism for the formation of a minor product.arrow_forward(b) Compare combustion of Anthracene and Xylene in sufficient supply of air. Which one will produce more carbon rich sooty flame and why?arrow_forwardAnswer both Questions below: Describe giving reagents and reaction conditions, how B may be converted into the compound below The enthalpies of formation of B and C are -52KJ/mol and -156KJ/mol respectively. Calculate the enthalpy of hydrogenation of B, giving your reasoning.arrow_forward
- Carbon–carbon bond dissociation enthalpies have been measured for many alkanes. Identify the alkane in each of the following pairs that has the lower carbon–carbon bond-dissociation enthalpy, and explain the reason for your choice. (a) Ethane or propane (b) Propane or 2-methylpropane (c) 2-Methylpropane or 2,2-dimethylpropane (d) Cyclobutane or cyclopentanearrow_forwardDisiamylborane adds only once to alkynes by virtue of its two bulky secondary isoamylgroups. Disiamylborane is prepared by the reaction of BH3 # THF with an alkene.(a) Draw the structural formulas of the reagents and the products in the preparation ofdisiamylboranearrow_forward(d) When butane, CH3CH2CH2CH3 and bromine gas, Br2 is exposed to sunlight, monobrominated product are produced. The reaction equation is given below: uv CH;CH,CH,CH3 + Br2 A + B (i) State the type of reaction. (ii) What is the function of the sunlight in the reaction? (iii) Draw the structure of monosubstituted products, A and B. Label the major product. (iv) Draw the propagation steps in the mechanism for the formation of the major product.arrow_forward
- (b) Fill in the blanks for the following from (1) until (11). The answer can be either reagent and condition (s) or product. You are required to draw the structural formula if the answer is a product. Strong reducing agent ÇONH, Alkylation of benzene at meta соон ÇOONA position only Strong oxidation agent 10 11 -1arrow_forward(b) (1-chloromethyl)cyclopentane, CeH11CI reacts with aqueous sodium hydroxide, NaOH to produce a primary alcohol AA. When CeH11Cl is added with magnesium, Mg in ether, an organometallic compound BB is formed. When compound BB reacts with ethanal, CH3CHO, a secondary alcohol cCis formed. The molecular structure of CeH11Cl is given below. (1-klorometil)siklopentana, CoH1,CI bertindak balas dengan akues natrium hidroksida, NaOH bagi menghasilkan satu alkohol primer AA. Apabila CeH11CI ditambah dengan magnesium, Mg dalam eter, sebatian organologam BB terbentuk. Apabila sebatian BB bertindak balas dengan etanal, CH;CHO, satu alkohol sekunder CC dihasilkan. Struktur molekul bagi CsH11CI diberikan di bawah. .CI (1-chloromethyl)cyclopentane (i) Draw the structural formula for compound AA through Cc. Lukiskan formula struktur bagi sebatian AA sehingga C. (ii) What is the type of reaction to produce compound AA? Apakah jenis tindak balas untuk menghasilkan sebatian AA?arrow_forwardArrange the following compounds in increasing order of their property as indicated :(i) CH3COCH3, C6H5COCH3, CH3CHO(reactivity towards nucleophilic addition reaction)(ii) Cl—CH2—COOH, F—CH2—COOH, CH3—COOH (acidic character)arrow_forward
- The name of the parent six-membered sulfur-containing heterocycle is thiane. It is numbered beginning at sulfur. Multiple incorporation of sulfur in the ring is indicated by the prefixes di-, tri-, and so on. (a) How many methyl-substituted thianes are there? Which ones are chiral? (b) Write structural formulas for 1,4-dithiane and 1,3,5-trithiane. (c) Which dithiane isomer (1,2-, 1,3-, or 1,4-) is a disulfide?(d) Draw the two most stable conformations of the sulfoxide derived from thiane.arrow_forwardWrite the equilibrium-constant expressions and obtain numerical values for each constant in (a) the basic dissociation of aniline, C6H5NH2. (b) the acidic dissociation of hypochlorous acid, HClO. (c) the acidic dissociation of methyl ammonium hydrochloride, CH3NH3Cl. (d) the basic dissociation of NaNO2. (e) the dissociation of H3AsO3 to H3O+ and AsO33- just answer the letters C, D and E.arrow_forward2. (a) The heat of combustion of liquid benzaldehyde (C6H5CHO) is -3393 kJ/mole, and that of liquid 2,4,6-cycloheptatrien-1-one (C₂H6O) is -3470 kJ/mole. Assume that both combustions result in products, CO2 and H₂O, that are entirely in the gas phase. Using the standard chemical equation for the combustion of a hydrocarbon, find the heats of formation (in kJ/mol) for both benzaldehyde and 2,4,6-cycloheptatrien-1-one in the liquid phase. (b) Consider the isomerization from 2,4,6-cycloheptatrien-1-one to benzaldehyde. What is the enthalpy change (in kJ/mol) for this reaction? Is it endothermic or exothermic? (c) If ArxnS = -18 J/mol-K for the isomerization reaction, find ArxnG at 350 K (in kJ/mol) and determine if it is spontaneous in the liquid phase at this temperature. For this calculation, you may assume that ArxnH and ArxnS are constant between 300 and 350 K.arrow_forward
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