EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
6th Edition
ISBN: 9781305687875
Author: Gilbert
Publisher: CENGAGE LEARNING - CONSIGNMENT
Question
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Chapter 7.6, Problem 1E

(a)

Interpretation Introduction

Interpretation:

Number of stereo centers in (+)-tartaric acid should be identified.

Concept Introduction :

Stereo centers are those carbon atoms which are attached to 4 different groups. They are also known as chiral centers.

(b)

Interpretation Introduction

Interpretation:

All possible stereo isomers of (+)-tartaric acid should be drawn by indicating the optical activity of the each structure while indicating pairs of them as enantiomers, diastereomers or meso compounds.

Concept Introduction :

Stereoisomers are the compounds which have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

(c)

Interpretation Introduction

Interpretation:

Other stereoisomers of (+)-tartaric acid that can be used to resolve racemic 1-phenylethylamine should be identified.

Concept Introduction :

Stereoisomers are the compounds that have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

(d)

Interpretation Introduction

Interpretation:

A possible advantage of using a different stereoisomer of (+)-tartaric acid to resolve racemic 1-phenylethylamine should be identified and the reason should be explained.

Concept Introduction :

Stereoisomers are the compounds that have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

(e)

Interpretation Introduction

Interpretation:

Importance of the optical purity of the resolving compound should be identified and explained.

Concept Introduction :

Stereoisomers are the compounds which have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

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12. Consider the molecule shown below. ОН ОН f. How many stereoisomers are possible? g. Draw each of these stereoisomers. h. Identify pairs of enantiomers and pairs of diastereomers. i. Build a model of the stereoisomer that has both OH groups pointing out. Also, build a model of the mirror image of this molecule. j. Do your two molecules represent enantiomers? Are they chiral?
The [α] of pure quinine, an antimalarial drug, is −165. a.Calculate the ee of a solution with the following [α] values: −50, −83, and −120. b. For each ee, calculate the percent of each enantiomer present. c.What is [α] for the enantiomer of quinine? d. If a solution contains 80% quinine and 20% of its enantiomer, what is the ee of the solution? e. What is [α] for the solution described in part (d)?
5 6 How many stereoisomers of the following molecule are possible in principle? Attachments HO H₂C A. 8 B. 128 C. 64 D. 32 E. 16 CH3 HO What is the relationship between the following two compounds? Attachments HO OH OH moja moja A. They are diastereomers B. They are enantiomers ⒸC. They are mesomers D. None of the above NH₂ OH
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