EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
6th Edition
ISBN: 9781305687875
Author: Gilbert
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Chapter 7.2, Problem 1E

(a)

Interpretation Introduction

Interpretation: The maximum number of stereoisomers that could exist for 1,2-cyclohexanediol needs to be determined, if the formula is 2n ( n = number of stereocenters).

Concept Introduction: Organic compounds are the compounds which are mainly composed C and H atoms. The branch of chemistry that deals with preparation, reactions, and properties of organic compounds. The compounds with same molecular formula and different structural formula are called as isomers. Isomers can be classified as constitutional isomers and stereoisomers.

Constitutional isomers can be defined as the pair of molecules with the same molecular formula but different structural formula. Stereoisomers have same molecular and structural formula but they have different arrangement of atoms in the three-dimensional space.

Optical isomers are type of stereoisomers which have same molecular and structural formula but they have different arrangement of atoms in the three-dimensional space. The essential condition for a molecule to be optical isomer is the presence of chiral carbon atom.

(b)

Interpretation Introduction

Interpretation: The reason of three stereoisomers of 1, 2-cyclohexanediol rather than calculated value 4 needs to be explained.

Concept Introduction: Organic compounds are the compounds which are mainly composed C and H atoms. The branch of chemistry that deals with preparation, reactions, and properties of organic compounds. The compounds with same molecular formula and different structural formula are called as isomers. Isomers can be classified as constitutional isomers and stereoisomers.

Constitutional isomers can be defined as the pair of molecules with the same molecular formula but different structural formula. Stereoisomers have same molecular and structural formula but they have different arrangement of atoms in the three-dimensional space.

Optical isomers are type of stereoisomers which have same molecular and structural formula but they have different arrangement of atoms in the three-dimensional space. The essential condition for a molecule to be optical isomer is the presence of chiral carbon atom.

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9) There are 3 different cyclopropane molecules with the formula GHĄC12. a. Draw and build the 3 molecules. b. Below each drawing, name each molecule with correct nomenclature. Label a pair that are constitutional isomers. d. Label a pair that are stereoisomers (or configurational isomers). С.
2. Designate the R/S configuration of all the stereocenters in the following molecules COOH HO-H
2. If a molecule has 3 asymmetric carbon centers, how many stereoisomers are there? Show work. ^.
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