EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
6th Edition
ISBN: 9781305687875
Author: Gilbert
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Chapter 7.4, Problem 10E
Interpretation Introduction
Interpretation : The phellandrenes are shown to be chiral in nature.
Concept Introduction : Chiral molecule is a molecule that has a mirror image molecule which is non-superimposable. A chiral center can be identified by having an atom with four different groups attached to it.
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(k)
(1)
OH
SOCI₂
1) BH 3 THF
2) H₂O2, NaOH
Rationalize the stereochemical outcomes
for A and B
CH3
A
...OH
B
TSCI
pyridine
LICI
(a)
For each of the following structures A-D, indicate whether it is chiral or not. Explain your answers.
H₂N
OH
A
OH
NH₂
B
PPh₂
PPh ₂
C
Ph.
C=C=C=C
D
Ph
c) An unknown chiral organic compound with molecular formula C7H1402 has a
characteristic IR absorptions at approximately 3000 cm1, 1715 cm1, 2400 -
3400 cm-1 (broad absorption) and 1250 cm1. Propose a possible structure of
this unknown compound.
Chapter 7 Solutions
EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
Ch. 7.2 - Prob. 1ECh. 7.2 - Prob. 2ECh. 7.2 - Prob. 3ECh. 7.2 - Prob. 4ECh. 7.2 - Prob. 5ECh. 7.2 - Prob. 6ECh. 7.2 - Prob. 7ECh. 7.2 - Prob. 8ECh. 7.2 - Prob. 9ECh. 7.2 - Prob. 10E
Ch. 7.3 - Prob. 1ECh. 7.3 - Prob. 2ECh. 7.3 - Prob. 3ECh. 7.3 - Prob. 4ECh. 7.3 - Prob. 5ECh. 7.3 - Prob. 6ECh. 7.3 - Prob. 7ECh. 7.3 - Prob. 8ECh. 7.4 - Prob. 1ECh. 7.4 - Prob. 2ECh. 7.4 - Prob. 3ECh. 7.4 - Prob. 4ECh. 7.4 - Prob. 5ECh. 7.4 - Prob. 6ECh. 7.4 - Prob. 7ECh. 7.4 - Prob. 8ECh. 7.4 - Prob. 9ECh. 7.4 - Prob. 10ECh. 7.4 - Prob. 11ECh. 7.4 - Prob. 12ECh. 7.4 - Prob. 13ECh. 7.6 - Prob. 1ECh. 7.6 - Prob. 2ECh. 7.6 - Prob. 3ECh. 7.6 - Prob. 4ECh. 7.6 - Prob. 5ECh. 7.6 - Prob. 6ECh. 7.6 - Prob. 7ECh. 7.6 - Prob. 8ECh. 7.6 - Prob. 9ECh. 7.6 - Prob. 10E
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