EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
6th Edition
ISBN: 9781305687875
Author: Gilbert
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Chapter 7.4, Problem 6E
Interpretation Introduction
Interpretation : Whether the boiling point of a mixture of enantiomers is expected to be same as that of a single enantiomer or not should be explained.
Concept Introduction :
Enantiomers are chiral molecules which are non-superimposable mirror images of each other. Chiral molecules are molecules which have a central atom attached with different groups.
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7. Dihydrocarveol is another natural product found in spearmint oil, but in minor amounts.
dihydrocarveol
a) Determine the R or S configuration of each chiral center in dihydrocarveol.
b) When separating the components of spearmint oil by column chromatography, in what
order would you expect carvone, limonene, and dihydrocarveol to elute?
c) Which compound would you expect to have the lowest Rf value by TLC: carvone,
limonene, or dihydrocarveol?
If the optical rotation of a pure enantiomer A is +10 and the optical rotation of a mixture of two enantiomers (A+B) is -4 (Negative 6), what is the percentage of A and B in that mixture?
Describe two methods for resolving (separating) a pair of enantiomers.
Chapter 7 Solutions
EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
Ch. 7.2 - Prob. 1ECh. 7.2 - Prob. 2ECh. 7.2 - Prob. 3ECh. 7.2 - Prob. 4ECh. 7.2 - Prob. 5ECh. 7.2 - Prob. 6ECh. 7.2 - Prob. 7ECh. 7.2 - Prob. 8ECh. 7.2 - Prob. 9ECh. 7.2 - Prob. 10E
Ch. 7.3 - Prob. 1ECh. 7.3 - Prob. 2ECh. 7.3 - Prob. 3ECh. 7.3 - Prob. 4ECh. 7.3 - Prob. 5ECh. 7.3 - Prob. 6ECh. 7.3 - Prob. 7ECh. 7.3 - Prob. 8ECh. 7.4 - Prob. 1ECh. 7.4 - Prob. 2ECh. 7.4 - Prob. 3ECh. 7.4 - Prob. 4ECh. 7.4 - Prob. 5ECh. 7.4 - Prob. 6ECh. 7.4 - Prob. 7ECh. 7.4 - Prob. 8ECh. 7.4 - Prob. 9ECh. 7.4 - Prob. 10ECh. 7.4 - Prob. 11ECh. 7.4 - Prob. 12ECh. 7.4 - Prob. 13ECh. 7.6 - Prob. 1ECh. 7.6 - Prob. 2ECh. 7.6 - Prob. 3ECh. 7.6 - Prob. 4ECh. 7.6 - Prob. 5ECh. 7.6 - Prob. 6ECh. 7.6 - Prob. 7ECh. 7.6 - Prob. 8ECh. 7.6 - Prob. 9ECh. 7.6 - Prob. 10E
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