Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 12, Problem 12.35UKC
Consider the following ball-and-stick model of an alcohol.
- a. Locate the chirality center.
- b. Classify the alcohol as 1°, 2°, or 3°.
- c. Name the alcohol.
- d. Draw the structure of the product formed when the alcohol is oxidized.
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1. Classify the molecule shown according to the location of its carbonyl group and the
number of carbon atoms.
CH₂OH
C=O
PIL
a. Aldotriose
b. Aldotetrose
Aldopentose
d., Ketotriose
Ketotetrose
HO-C-H
L
CH₂OH
1.
Which compounds contain chiral centers? Show your solution for each
ww ww w w
item.
a. 2-Chloropentane
b. 3-Chloro-1-pentene
c. 3-Chloropentane
d. 1,2-Dichloropropane
1. Assign a name to each of the following monosaccharides. Use D and L designations.
H
I
CH 2OH
C=O
C=O
a.
b.
a.
HO-C-H
H-C-OH
H-C-OH
CH₂OH
d. True or False:
b.
HỌCH
CH ₂OH
C. Circle all chiral centers for the monosaccharides shown.
The molecules shown can rotate plane polarized light?
Chapter 12 Solutions
Principles of General, Organic, Biological Chemistry
Ch. 12.1 - a. Label the hydroxyl groups, thiols, halogens,...Ch. 12.1 - Draw out each compound to clearly show what groups...Ch. 12.2 - Classify each alcohol as 1, 2, or 3.Ch. 12.2 - Classify each hydroxyl group in sorbitol as 1, 2,...Ch. 12.2 - Which compound in each pair has the higher boiling...Ch. 12.2 - Label each compound as water soluble or water...Ch. 12.2 - Give the IUPAC name for each compound.Ch. 12.2 - Give the structure corresponding to each name. a....Ch. 12.3 - Name each ether. a. CH3OCH2CH2CH2CH3 b....Ch. 12.3 - Prob. 12.10P
Ch. 12.3 - Which compound in each pair has the higher boiling...Ch. 12.5 - Prob. 12.12PCh. 12.5 - Prob. 12.13PCh. 12.6 - Prob. 12.14PCh. 12.6 - Prob. 12.15PCh. 12.6 - Give the structure corresponding to each name. a....Ch. 12.7 - Prob. 12.17PCh. 12.8 - Give the IUPAC name for each aldehyde. a....Ch. 12.8 - Prob. 12.19PCh. 12.8 - Give the IUPAC name for each aldehyde depicted in...Ch. 12.8 - Prob. 12.21PCh. 12.8 - Prob. 12.22PCh. 12.8 - Acetone and progesterone are two ketones that...Ch. 12.9 - Prob. 12.24PCh. 12.10 - Prob. 12.25PCh. 12.11 - Prob. 12.26PCh. 12.11 - Prob. 12.27PCh. 12.11 - Prob. 12.28PCh. 12.11 - Prob. 12.29PCh. 12.11 - Prob. 12.30PCh. 12.11 - Prob. 12.31PCh. 12.11 - Prob. 12.32PCh. 12 - Prob. 12.33UKCCh. 12 - Prob. 12.34UKCCh. 12 - Consider the following ball-and-stick model of an...Ch. 12 - Consider the following ball-and-stick model. a....Ch. 12 - Name each compound. a. CH3CH2OCH2CH2CH2CH3Ch. 12 - Name each compound. a. CH3OCH2CH2CH3 b....Ch. 12 - Answer the following questions about alcohol A. a....Ch. 12 - Answer the following questions about alcohol B. a....Ch. 12 - Prob. 12.41UKCCh. 12 - Prob. 12.42UKCCh. 12 - Prob. 12.43UKCCh. 12 - Prob. 12.44UKCCh. 12 - Prob. 12.45APCh. 12 - Prob. 12.46APCh. 12 - Prob. 12.47APCh. 12 - Prob. 12.48APCh. 12 - Prob. 12.49APCh. 12 - Prob. 12.50APCh. 12 - Prob. 12.51APCh. 12 - Prob. 12.52APCh. 12 - Prob. 12.53APCh. 12 - Give the structure corresponding to each name. a....Ch. 12 - Prob. 12.55APCh. 12 - Draw structures for the four constitutional...Ch. 12 - Prob. 12.57APCh. 12 - Rank the following compounds in order of...Ch. 12 - Explain why two four-carbon organic molecules have...Ch. 12 - Explain why the boiling point of CH3CH2CH2CH2OH...Ch. 12 - Which compound in each pair has the higher boiling...Ch. 12 - Which compound in each pair is more water soluble?...Ch. 12 - Prob. 12.63APCh. 12 - Prob. 12.64APCh. 12 - Prob. 12.65APCh. 12 - Prob. 12.66APCh. 12 - Prob. 12.67APCh. 12 - Xylitol is a nontoxic compound as sweet as table...Ch. 12 - Prob. 12.69APCh. 12 - Prob. 12.70APCh. 12 - Prob. 12.71APCh. 12 - Prob. 12.72APCh. 12 - Prob. 12.73APCh. 12 - Prob. 12.74APCh. 12 - Prob. 12.75APCh. 12 - Prob. 12.76APCh. 12 - Prob. 12.77APCh. 12 - Draw the structure corresponding to each name. a....Ch. 12 - Prob. 12.79APCh. 12 - Prob. 12.80APCh. 12 - What product is formed when each compound is...Ch. 12 - Prob. 12.82APCh. 12 - Prob. 12.83APCh. 12 - Prob. 12.84APCh. 12 - Prob. 12.85APCh. 12 - Prob. 12.86APCh. 12 - Prob. 12.87APCh. 12 - Label each of the following objects as chiral or...Ch. 12 - Prob. 12.89APCh. 12 - Prob. 12.90APCh. 12 - Prob. 12.91APCh. 12 - Prob. 12.92APCh. 12 - Prob. 12.93APCh. 12 - Prob. 12.94APCh. 12 - Prob. 12.95APCh. 12 - Prob. 12.96APCh. 12 - Prob. 12.97APCh. 12 - How are the compounds in each pair related? Are...Ch. 12 - Prob. 12.99APCh. 12 - Prob. 12.100APCh. 12 - Prob. 12.101APCh. 12 - Prob. 12.102APCh. 12 - Prob. 12.103APCh. 12 - Lactic acid [CH3CH(OH)CO2H] gives sour milk its...Ch. 12 - Prob. 12.105APCh. 12 - Prob. 12.106APCh. 12 - Prob. 12.107CPCh. 12 - Prob. 12.108CPCh. 12 - Prob. 12.109BTCCh. 12 - Prob. 12.110BTC
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- 28. A structural feature with in a molecule which is responsible for chirality is called c. chirality d. Chiral C e. Chiral center d. all 29. Optically active compounds have isomer a Two C. four b. Three d. five 30. Propanone and propenol are a. structural isomers C. tautomer b. metamers d position isomerarrow_forward58. Which of the following statements incorrectly describes alcohols? A. The solubility of an alcohol is affected by the length of its carbon chain. B. The boiling point of an alcohol is affected by the length of its carbon chain. C. The solubility of an alcohol is affected by the shape of the molecule. D. Straight chain isomers will have a higher boiling point than the branched molecule. 59. Why do phenols have a higher boiling point than toluene despite having similar shape? A. The higher boiling point of phenol is attributed to the electronegativity of the oxygen. B. The higher boiling point of phenol is attributed to the hydrogen bonding. C. Both D. Neither 60. Which of the following statements incorrectly describes ethers? A. Ethers react easily with acids. B. Ethers are miscible with water. C. Ether serves as an electron acceptor group. D. None of the above Refer to the reaction to answer items 61 to 63. CH₂ OH KMnO4 H₂C 61. What type of reaction is catalyzed based on the…arrow_forwardIdentify which type of isomerism is described by each statement. A. Isomerism based on a single difference on the location of OH B. Isomerism based on functional group of the monosaccharides C. Isomerism based on configuration of hemiketal or hemiacetal carbon D. Isomerism based on ability to rotate plane of polarized light E. Isomerism based on OH position in the carbon atoms of the linear structure F. Isomerism based on aromatic ring structure derivationarrow_forward
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