From a given pair of compound, which one is higher boiling point has to be determined. Concept introduction: Boiling point of aldehyde, ketone, alcohol and hydrocarbons: Carbonyl compounds such as aldehydes and ketones are more polar nature; therefore, they have more stronger intermolecular forces than hydrocarbons. However, when compare to alcohol this aldehyde and ketones are having weaker intermolecular forces. Finally, the alcohols have more boiling point than hydrocarbons, at the same time; the aldehydes and ketones have less boiling point than alcohols.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.8, Problem 12.22P

a.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Boiling point of aldehyde, ketone, alcohol and hydrocarbons:

Carbonyl compounds such as aldehydes and ketones are more polar nature; therefore, they have more stronger intermolecular forces than hydrocarbons. However, when compare to alcohol this aldehyde and ketones are having weaker intermolecular forces. Finally, the alcohols have more boiling point than hydrocarbons, at the same time; the aldehydes and ketones have less boiling point than alcohols.

b.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

c.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

d.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

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Draw the products formed when CH3CH2C ≡ C−Na+reacts with each compound. a. CH3CH2CH2Brb. (CH3)2CHCH2CH2Clc. (CH3CH2)3CCld. BrCH2CH2CH2CH2OHe. ethylene oxide followed by H2Of. propene oxide followed by H2O

Name each compound

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.8, Problem 12.22P

a.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Boiling point of aldehyde, ketone, alcohol and hydrocarbons:

Carbonyl compounds such as aldehydes and ketones are more polar nature; therefore, they have more stronger intermolecular forces than hydrocarbons. However, when compare to alcohol this aldehyde and ketones are having weaker intermolecular forces. Finally, the alcohols have more boiling point than hydrocarbons, at the same time; the aldehydes and ketones have less boiling point than alcohols.

b.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

c.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

d.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

Expert Solution & Answer

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.8, Problem 12.22P

a.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Boiling point of aldehyde, ketone, alcohol and hydrocarbons:

Carbonyl compounds such as aldehydes and ketones are more polar nature; therefore, they have more stronger intermolecular forces than hydrocarbons. However, when compare to alcohol this aldehyde and ketones are having weaker intermolecular forces. Finally, the alcohols have more boiling point than hydrocarbons, at the same time; the aldehydes and ketones have less boiling point than alcohols.

b.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

c.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

d.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

Expert Solution & Answer

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.8, Problem 12.22P

a.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Boiling point of aldehyde, ketone, alcohol and hydrocarbons:

Carbonyl compounds such as aldehydes and ketones are more polar nature; therefore, they have more stronger intermolecular forces than hydrocarbons. However, when compare to alcohol this aldehyde and ketones are having weaker intermolecular forces. Finally, the alcohols have more boiling point than hydrocarbons, at the same time; the aldehydes and ketones have less boiling point than alcohols.

b.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

c.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

d.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

Expert Solution & Answer

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Answer 5

Chapter 12.8, Problem 12.22P

a.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Boiling point of aldehyde, ketone, alcohol and hydrocarbons:

Carbonyl compounds such as aldehydes and ketones are more polar nature; therefore, they have more stronger intermolecular forces than hydrocarbons. However, when compare to alcohol this aldehyde and ketones are having weaker intermolecular forces. Finally, the alcohols have more boiling point than hydrocarbons, at the same time; the aldehydes and ketones have less boiling point than alcohols.

b.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

c.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

d.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

Answer 6

Chapter 12.8, Problem 12.22P

a.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Boiling point of aldehyde, ketone, alcohol and hydrocarbons:

Carbonyl compounds such as aldehydes and ketones are more polar nature; therefore, they have more stronger intermolecular forces than hydrocarbons. However, when compare to alcohol this aldehyde and ketones are having weaker intermolecular forces. Finally, the alcohols have more boiling point than hydrocarbons, at the same time; the aldehydes and ketones have less boiling point than alcohols.

Answer 7

Chapter 12.8, Problem 12.22P

a.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Boiling point of aldehyde, ketone, alcohol and hydrocarbons:

Carbonyl compounds such as aldehydes and ketones are more polar nature; therefore, they have more stronger intermolecular forces than hydrocarbons. However, when compare to alcohol this aldehyde and ketones are having weaker intermolecular forces. Finally, the alcohols have more boiling point than hydrocarbons, at the same time; the aldehydes and ketones have less boiling point than alcohols.

Answer 8

b.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

Answer 9

b.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

Answer 10

c.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

Answer 11

c.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

Answer 12

d.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

Answer 13

d.

Interpretation Introduction

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 12.1 - a. Label the hydroxyl groups, thiols, halogens,...Ch. 12.1 - Draw out each compound to clearly show what groups...Ch. 12.2 - Classify each alcohol as 1, 2, or 3.Ch. 12.2 - Classify each hydroxyl group in sorbitol as 1, 2,...Ch. 12.2 - Which compound in each pair has the higher boiling...Ch. 12.2 - Label each compound as water soluble or water...Ch. 12.2 - Give the IUPAC name for each compound.Ch. 12.2 - Give the structure corresponding to each name. a....Ch. 12.3 - Name each ether. a. CH3OCH2CH2CH2CH3 b....Ch. 12.3 - Prob. 12.10P

Solution Summary: The author explains that carbonyl compounds such as aldehydes and ketones have stronger intermolecular forces than hydrocarbons.

Concept explainers

Videos

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

Want to see the full answer?

Chapter 12 Solutions

Solution Summary: The author explains that carbonyl compounds such as aldehydes and ketones have stronger intermolecular forces than hydrocarbons.

Concept explainers

Videos

Interpretation: From a given pair of compound, which one is higher boiling point has to be determined. Concept introduction: Refer to part a.

Interpretation: From a given pair of compound, which one is higher boiling point has to be determined. Concept introduction: Refer to part a.

Interpretation: From a given pair of compound, which one is higher boiling point has to be determined. Concept introduction: Refer to part a.

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Chapter 12 Solutions

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.

Interpretation:

From a given pair of compound, which one is higher boiling point has to be determined.

Concept introduction:

Refer to part a.