Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 5, Problem 23CTQ
Interpretation Introduction

Interpretation: Whether pKa of molecules mentioned below match with the stability of anions or not should be determined.

  Organic Chemistry: A Guided Inquiry, Chapter 5, Problem 23CTQ

Concept introduction: The dissociation constant of acid represents strength of acid in solution. It is denoted by Ka . The expression of pKa is as follows:

  pKa=logKa

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hydrogens on a carbon adjacent to a carbonyl group are far more acidic than those not adjacent to a carbonyl group. The anion derived from acetone, for example, is more stable than is the anion derived from ethane. Account for the greater stability of the anion from acetone. CH,ČCH, H CH,CH, H Acetone Ethane pK, 20.2 pK, 51
What does a value of K eq greater than 1 mean?A. More reactants than products exist at equilibrium.B. More products than reactants exist at equilibrium.C. The rate of the forward reaction is high atequilibrium.D. The rate of the reverse reaction is high atequilibrium.
6. Which of the following compounds has the lowest pKa ? A OH NH B XOH OH C X D NH₂

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Organic Chemistry: A Guided Inquiry

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