Organic Chemistry: Structure and Function
Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 4, Problem 44P

(a)

Interpretation Introduction

Interpretation:The more stable form from the two needs to be determined.

Concept Introduction:Checking the hydroxyl groups for equatorial positions (no diaxial interaction).

(b)

Interpretation Introduction

Interpretation:The free energy difference corresponding to the given equilibrium ratio needs to be determined.

Concept Introduction:The free energy difference corresponding to the given equilibrium ratio(K) is calculated using the formula:

  ΔG0=1.36log(K) .

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