Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 4, Problem 50P
Interpretation Introduction
Interpretation:Hybridization of carbon atom in cyclobutane is to be find out with the C-C-C bond angle and position of the hydrogen atom.
Concept introduction:Hybridization is defined as the mixing of atomic orbitals to form a new set of orbitals having equal energy and identical shape. It is used to explain shape of molecules.
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The bond lengths of ethane, ethene, and ethyne were determined, and a graph of the C-H bond length vs. % s-character of the C hybrid orbital was made.
Comment on the observed trend, additionally. How would this trend change if C-H bond energy vs. % s-character of the C hybrid orbital was graphed? Which hydrocarbon has the strongest carbon-carbon bond?
2,4-dimethy/-2,3-pentadiene has the following line diagram structure (with hydrogens drawn
in). Explain with PICTURES of the sigma and pi bonds and with words why this molecule does not actually have a planar arrangement of methyl groups. Include an electron diagram of the hybridization of the central carbon atom.
Examine the sigma bonding in ethene. What types of orbitals does each C atom use when forming sigma bonds to the H atoms?
s orbial
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What type of orbital does each C atom use to form a sigma bond to the other C atom?
s orbial
p orbitals
hybrid orbitals
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Now examine the pi bonding in ethene. What types of orbitals on the C atoms are used to form the pi bond?
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Chapter 4 Solutions
Organic Chemistry: Structure and Function
Ch. 4.1 - Prob. 4.1ECh. 4.1 - Prob. 4.3TIYCh. 4.2 - Prob. 4.4ECh. 4.2 - Prob. 4.6TIYCh. 4.3 - Prob. 4.7ECh. 4.4 - Prob. 4.8ECh. 4.4 - Prob. 4.10TIYCh. 4.4 - Prob. 4.11ECh. 4.4 - Prob. 4.12ECh. 4.4 - Prob. 4.14TIY
Ch. 4.6 - Prob. 4.15ECh. 4.7 - Prob. 4.16ECh. 4.7 - Prob. 4.17ECh. 4.7 - Prob. 4.18ECh. 4 - Prob. 21PCh. 4 - Prob. 22PCh. 4 - Prob. 23PCh. 4 - Prob. 24PCh. 4 - Prob. 25PCh. 4 - Prob. 26PCh. 4 - Prob. 27PCh. 4 - Prob. 28PCh. 4 - Prob. 29PCh. 4 - Prob. 30PCh. 4 - Prob. 31PCh. 4 - Prob. 32PCh. 4 - Prob. 33PCh. 4 - Prob. 34PCh. 4 - Prob. 35PCh. 4 - Prob. 36PCh. 4 - Prob. 37PCh. 4 - Prob. 38PCh. 4 - Prob. 39PCh. 4 - Prob. 40PCh. 4 - Prob. 41PCh. 4 - Prob. 42PCh. 4 - Prob. 43PCh. 4 - Prob. 44PCh. 4 - Prob. 45PCh. 4 - Prob. 46PCh. 4 - Prob. 47PCh. 4 - Prob. 48PCh. 4 - Prob. 49PCh. 4 - Prob. 50PCh. 4 - Prob. 51PCh. 4 - Prob. 52PCh. 4 - Prob. 53PCh. 4 - Prob. 54PCh. 4 - Prob. 55PCh. 4 - Prob. 56PCh. 4 - Prob. 57PCh. 4 - Prob. 58PCh. 4 - Prob. 59PCh. 4 - Prob. 60P
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