Organic Chemistry: Structure and Function
Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 4.2, Problem 4.6TIY
Interpretation Introduction

Interpretation: The heat of reaction of compound ‘A’ where the reaction is with hydrogen to give cyclohexane is to be determined. The strain energy is given as 50.7 kcal mol-1.

Concept introduction: The heat of reaction is calculated using the equation of enthalpy for a reaction and can be written as:

  ΔH°=(strengths of bonds broken)- (strengths of bond made)       =DH°reactantDH°product

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(a) Calculate the standard enthalpy change for the combustion of 1 mol of benzene, C6H61l2, to CO21g2 and H2O1l2.(b) Compare the quantity of heat produced by combustion of 1.00 g propane with that produced by 1.00 g benzene.
Calculate the enthalpy of benzene from its enthalpy of combustion and the enthalpy of combustion of cyclohexane
Alcohols A, B, and C all have the composition C4H10O. Molecules of alcohol A contain a branched carbon chain and can be oxidized to an aldehyde; molecules of alcohol B contain a linear carbon chain and can be oxidizedto a ketone; and molecules of alcohol C can be oxidized to neither an aldehyde nor a ketone. Write the Lewis structures of these molecules.
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