Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 4.4, Problem 4.14TIY
Interpretation Introduction
Interpretation:The trans-1,2-dimethylcyclohexane exists in diequatorial form and as it is an isomer of cis-1,3-dimethylcyclohexane it is expected to have sameΔG° value. Butthe measured smallerΔG° value needs to be explained.
Concept introduction:The energy difference is caused due to the difference in their conformation and interaction between different groups.
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For each of the following pairs or reactions, which is correctly labeled as having the larger equilibrium constant. There may be more than one
correct answer.
CHон рКа %3D15.5
CHCH2OH pKa =15.9
NH, pKa =9.4
CH;NH pKa =10.7
CH CH OH + NH3
CH OH + NH3
CH;CH20 + NH,"
CHO + NH, larger Kea
CH:CH,OH + CH NH2 CH,CHO + CHNH, larger Keg
CH3CH2OH + NH3 CH3CH 0 + NH
Туре: MС
QUESTION 9
CH-CH3
Name the compound. HC-CH-CH-CH-CH
CH CH2CH3
O 2-ethyl-3-propylpentane
4-ethyl-3-methylheptane
O 2,3-diethylhexane
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Determine the Kc of the following reaction:
AB4(g) + B2C(g) ⇌ AC2(g) + B2(g) Kp = 21/62500
Consider The Following Reaction: CaCO3(S) + 2HCl(Aq) = CaCl2(Aq) + H2O(L) + CO2(G)
Write down the quation of the equilibrium constant kc for this reaction
Chapter 4 Solutions
Organic Chemistry: Structure and Function
Ch. 4.1 - Prob. 4.1ECh. 4.1 - Prob. 4.3TIYCh. 4.2 - Prob. 4.4ECh. 4.2 - Prob. 4.6TIYCh. 4.3 - Prob. 4.7ECh. 4.4 - Prob. 4.8ECh. 4.4 - Prob. 4.10TIYCh. 4.4 - Prob. 4.11ECh. 4.4 - Prob. 4.12ECh. 4.4 - Prob. 4.14TIY
Ch. 4.6 - Prob. 4.15ECh. 4.7 - Prob. 4.16ECh. 4.7 - Prob. 4.17ECh. 4.7 - Prob. 4.18ECh. 4 - Prob. 21PCh. 4 - Prob. 22PCh. 4 - Prob. 23PCh. 4 - Prob. 24PCh. 4 - Prob. 25PCh. 4 - Prob. 26PCh. 4 - Prob. 27PCh. 4 - Prob. 28PCh. 4 - Prob. 29PCh. 4 - Prob. 30PCh. 4 - Prob. 31PCh. 4 - Prob. 32PCh. 4 - Prob. 33PCh. 4 - Prob. 34PCh. 4 - Prob. 35PCh. 4 - Prob. 36PCh. 4 - Prob. 37PCh. 4 - Prob. 38PCh. 4 - Prob. 39PCh. 4 - Prob. 40PCh. 4 - Prob. 41PCh. 4 - Prob. 42PCh. 4 - Prob. 43PCh. 4 - Prob. 44PCh. 4 - Prob. 45PCh. 4 - Prob. 46PCh. 4 - Prob. 47PCh. 4 - Prob. 48PCh. 4 - Prob. 49PCh. 4 - Prob. 50PCh. 4 - Prob. 51PCh. 4 - Prob. 52PCh. 4 - Prob. 53PCh. 4 - Prob. 54PCh. 4 - Prob. 55PCh. 4 - Prob. 56PCh. 4 - Prob. 57PCh. 4 - Prob. 58PCh. 4 - Prob. 59PCh. 4 - Prob. 60P
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- Which of the following statements is false? When K >> 1, the forward reaction is favored and essentially goes to completion. When K > 1 implies that the reaction is very fast at producing products. None of the above.arrow_forward(i) What would be the general form of the rate equation for the reaction: CH4+202-CO₂+2H20 (ii) Write the Equilibrium Constant expression for the following reaction at equilibrium: N₂(g) + 3H2(g) ≤ >2NH, (g) If 8.00g glucose (molar mass, 180.00g) are dissolved in water to make-uparrow_forwardH-C- OH Does the equilibrium lie to the left or to the right in the following reaction: Н-С—ОН + CH,-Ö:- ċ-0 + CH,-ö-H ??arrow_forward
- Consider the following equilibrium reaction: 2 CH3OH + CH2O ⇌CH2(OCH3)2+ H2O ΔH = + 46 indicate the direction that the equilibrium will shift when the following changes are made.(No states are provided because the solvent for the reaction is not water, so aq for aqueous would not be appropriate.) (a)Concentration of CH3OH increases (b)H2O is removed from the reaction (c)Reaction is heatedarrow_forwardUse the following equilibria2CH4(g) <----> C2H6(g) + H2(g) Kc1 = 9.5 × 10-13CH4(g) + H2O(g) CH3OH(g) + H2(g) Kc2 = 2.8 × 10-21to calculate the value of Kc' for the following reaction:2CH3OH(g) + H2(g) <---> C2H6(g) + 2H2O(g) Enter your response in scientific notation, e.g. enter 2E3 for 2000arrow_forwardConsider the following equilibrium reaction: 2 CH3OH + CH2O ⇌CH2(OCH3)2+ H2O ΔH = + 46 cal Indicate the direction that the equilibrium will shift when the following changes are made.(No states are provided because the solvent for the reaction is not water, so aq for aqueous would not be appropriate.) (d)How does the equilibrium constant (Keq) change when temperature is decreased?arrow_forward
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