Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic . Concept introduction: In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond. Amines are the derivatives of ammonia ( N H 3 ) with one or more of the hydrogens replaced with a substituent such as an alkyl group. Depending on the number of carbon side chain of the amide, different types of amides can form. If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine. If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine. If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine.

Question

Classify each amine as a primary, secondary, or tertiary.

Answer 1

Question

Chapter 23, Problem 23.18P

(a)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine.

(b)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine

(c)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine.

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Classify each amine as a primary, secondary, or tertiary.

TRUE OR FALSE (a) There are three amines with the molecular formula C3H9N. (b) Aldehydes, ketones, carboxylic acids, and esters all contain a carbonyl group. (c) A compound with the molecular formula of C3H6O may be either an aldehyde, a ketone, or a carboxylic acid. (d) Bond angles about the carbonyl carbon of an aldehyde, a ketone, a carboxylic acid, and an ester are all approximately 109.5°. (e) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O. (f) The molecular formula of the smallest carboxylic acid is C2H4O2.

What is the full structure of an amine which is an isomer of ethylamine? What is the isomer called? Is it primary, secondary or tertiary?

Answer 2

Question

Chapter 23, Problem 23.18P

(a)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine.

(b)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine

(c)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine.

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Answer 3

Question

Chapter 23, Problem 23.18P

(a)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine.

(b)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine

(c)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine.

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Answer 4

Question

Chapter 23, Problem 23.18P

(a)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine.

(b)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine

(c)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine.

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Answer 5

Chapter 23, Problem 23.18P

(a)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine.

(b)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine

(c)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine.

Answer 6

Chapter 23, Problem 23.18P

(a)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine.

Answer 7

Chapter 23, Problem 23.18P

(a)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine

Answer 9

(b)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine

Answer 10

(c)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Each of the amine has to be classified as primary, secondary, or tertiary amine and as aliphatic or aromatic.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the amide, different types of amides can form.

If nitrogen atom in amine group is attached only to alkyl groups, then it is an aliphatic amine.

If nitrogen atom in amine group is attached to at least one aryl groups, then it is an aromatic amine.

If nitrogen atom in amine group is a part of an aromatic ring, then it is a heterocyclic aromatic amine.

Answer 12

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Answer 23

Ch. 23.1 - Prob. 23.1P Ch. 23.2 - Prob. 23.2P Ch. 23.2 - Prob. 23.3P Ch. 23.2 - Prob. 23.4P Ch. 23.5 - Prob. 23.5P Ch. 23.5 - Prob. AQ Ch. 23.5 - What is the hybridization of the nitrogen in...Ch. 23.5 - Prob. CQ Ch. 23.5 - The pKas of the conjugate acids of aniline and...Ch. 23.5 - Prob. EQ

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Chapter 23 Solutions