General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 14, Problem 28P
Draw the structure of a molecule that fits each description:
a. a 2° alcohol of molecular formula
b. a cyclic ether with molecular formula
c. a 1°
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Which is an example of an ether?A. CH3OH
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1. The functional groups present in the following molecules are:
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b. an ether, a ketone and a carboxylic acid
c. an ester, a alcohol and a ketone
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c. nonc of the above
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Rank the compounds in each group in order of increasing boiling point. a. CH 3CH 2CH 2I, CH 3CH 2CH 2Cl, CH 3CH 2CH 2F b. CH 3(CH 2) 4CH 3, CH 3(CH 2) 5Br, CH 3(CH 2) 5Cl
Chapter 14 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 14.1 - Prob. 14.1PCh. 14.2 - Prob. 14.1PPCh. 14.2 - Classify each hydroxyl group in sorbitol as 1°,...Ch. 14.2 - Prob. 14.3PCh. 14.2 - Prob. 14.4PCh. 14.3 - Prob. 14.2PPCh. 14.3 - Give the structure corresponding to each name a....Ch. 14.5 - Draw the products formed when each alcohol is...Ch. 14.5 - Prob. 14.6PCh. 14.5 - Prob. 14.7P
Ch. 14.5 - Prob. 14.4PPCh. 14.6 - Prob. 14.8PCh. 14.7 - Prob. 14.9PCh. 14.7 - Prob. 14.5PPCh. 14.7 - Prob. 14.10PCh. 14.7 - Name each ether. CH3OCH2CH2CH2CH3Ch. 14.7 - Prob. 14.11PCh. 14.8 - (a) Translate the hall and stick model of...Ch. 14.8 - Prob. 14.13PCh. 14.9 - Prob. 14.14PCh. 14.9 - Prob. 14.15PCh. 14.9 - Prob. 14.16PCh. 14.9 - Prob. 14.17PCh. 14.9 - Prob. 14.18PCh. 14.9 - Prob. 14.19PCh. 14.9 - Prob. 14.20PCh. 14.10 - Give the IUPAC name for each thiol.Ch. 14.10 - Prob. 14.21PCh. 14.10 - Prob. 14.22PCh. 14 - Classify each alcohol as 1°, 2°, or 3o a....Ch. 14 - Prob. 24PCh. 14 - Prob. 25PCh. 14 - Classify each halide hi A as 1°, 2°, or 3°. A is a...Ch. 14 - Prob. 27PCh. 14 - Draw the structure of a molecule that fits each...Ch. 14 - Draw the structure of the six constitutional...Ch. 14 - Draw the structure of the four constitutional...Ch. 14 - Draw the structure of l-propanethiol, a compound...Ch. 14 - Prob. 32PCh. 14 - Prob. 33PCh. 14 - Prob. 34PCh. 14 - Prob. 35PCh. 14 - Answer each question about alcohol B. Draw a...Ch. 14 - Prob. 37PCh. 14 - Give the IUAPC name for each alcohol.Ch. 14 - Prob. 39PCh. 14 - Prob. 40PCh. 14 - Prob. 41PCh. 14 - Prob. 42PCh. 14 - Draw the structures and give the IUPAC names for...Ch. 14 - Prob. 44PCh. 14 - Prob. 45PCh. 14 - Prob. 46PCh. 14 - Give the structure corresponding to each IUPAC...Ch. 14 - Give the structure corresponding to each IUPAC...Ch. 14 - Which compound in each pair has the higher boiling...Ch. 14 - Rank the compounds in order of increasing melting...Ch. 14 - Rank the following compounds in order of...Ch. 14 - Rank the following compounds in order of...Ch. 14 - Prob. 53PCh. 14 - Prob. 54PCh. 14 - Prob. 55PCh. 14 - Prob. 56PCh. 14 - Prob. 57PCh. 14 - Prob. 58PCh. 14 - Prob. 59PCh. 14 - Prob. 60PCh. 14 - Prob. 61PCh. 14 - Prob. 62PCh. 14 - Prob. 63PCh. 14 - Prob. 64PCh. 14 - Prob. 65PCh. 14 - Prob. 66PCh. 14 - Prob. 67PCh. 14 - Prob. 68PCh. 14 - Prob. 69PCh. 14 - Prob. 70PCh. 14 - Prob. 71PCh. 14 - Prob. 72PCh. 14 - Prob. 73PCh. 14 - Prob. 74PCh. 14 - Prob. 75PCh. 14 - Prob. 76PCh. 14 - Prob. 77PCh. 14 - Prob. 78PCh. 14 - Prob. 79PCh. 14 - Prob. 80PCh. 14 - With reference to the halogenated organic...Ch. 14 - Prob. 82PCh. 14 - Prob. 83PCh. 14 - Prob. 84PCh. 14 - Write out the chemical reaction that occurs when a...Ch. 14 - Prob. 86PCh. 14 - Prob. 87PCh. 14 - Lactic acid [CH3CH(OH)CO2H] gives sour milk its...Ch. 14 - Prob. 89PCh. 14 - Prob. 90PCh. 14 - Prob. 91PCh. 14 - Prob. 92PCh. 14 - Prob. 93PCh. 14 - Answer the following questions about alcohol B....Ch. 14 - Prob. 95CPCh. 14 - Dehydration of alcohol C forms two products of...
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- Draw the structure of a molecule that fi ts each description: a. a 2 ° alcohol of molecular formula C 6H 12O b. a cyclic ether with molecular formula C 5H 10O c. a 1 ° alkyl halide with molecular formula C 5H 11Clarrow_forward1. Carboxylic acid reacts with an alcohol to form: A. Ester and Water B. Ester C. Water D. No reaction 2. The general formula for Carboxylic acids: A. RCOOH B. RCOOR C. RCOR D. RCOH 3. General formula of phenols: * A. ROH B. Ar-OH C. R-SH D. RCOHarrow_forward1. What does the ff compound belong to: a. ketone b. alcohol c. aldehyde d. alkane 2. What group does the ff organic compound belong? a. ketone b. carboxylic acid c. aldehyde d. alkyl halide 3. What group does the ff organic compound belong? a. alkene b. ketone c. alcohol d. aldehydearrow_forward
- 10. How many H-bonds can a secondary alcohol form? A. 3 B. 1 C. 2 D. 0arrow_forwardDraw the skeletal structure of the following compound: a. carboxylic acid with the molecular formula C4H8O2 b. an ester with molecular formula C4H802 c. a ketone with the molecular formula C4H8O2 d. an aldehyde with the molecular formula C4H8Oarrow_forward24 Which of the following contains a hydroxyl group? A. Alcohol B. Ether C. Thiol D. More than one answer is correct 25 Tetrahydrocannabinol molecule has four functional groups. Which one is not included? A. An alkane B. an ether C. a phenolic -OH D. benzene ring E. a carbon-carbon double bond H H3C CH3 H3C H OH CH3arrow_forward
- The major compounds used in Fragrance are: a. Ethers. O b. Alcohols. O c. Carboxylic acid. O d. Anhydrides. Which of the following statement is CORRECT? O a. Ethanol and Propenol. O b. Methanol and Ethanol. c. Ethanol and Propanol. O d. Cyclomethanol and Cycloethanol. The first two members of the homologous series of alcohols are: a. Ethanol and Propenol. b. Methanol and Ethanol. O c. Ethanol and Propanol. O d. Cyclomethanol and Cycloethanol.arrow_forwardWhat functional group distinguishes each of the following hydrocarbon derivatives? a. halohydrocarbons b. alcohols c. ethers d. aldehydes e. ketones f. carboxylic acids g. esters h. amines Give examples of each functional group. What prefix or suffix is used to name each functional group? What are the bond angles in each? Describe the bonding in each functional group. What is the difference between a primary, secondary, and tertiary alcohol? For the functional groups in ah, when is a number required to indicate the position of the functional group? Carboxylic acids are often written as RCOOH. What does COOH indicate and what does R indicate? Aldehydes are sometimes written as RCHO. What does CHO indicate?arrow_forward53. Which statement below is incorrect? а. the smallest aldehyde has the formula HCOH b. a carbonyl carbon consists of a carbon-oxygen double bond in an aldehyde, the carbonyl carbon is always bonded to a hydrogen atom с. d. Ketones are more soluble in water than alcohols with the equiva lent number of carbonsarrow_forward
- 14. PART 3: Draw the structure for compound A.arrow_forwardWrite the complete chemical reaction and correct chemical formula and structure of the following: 1. Autooxidation of benzaldehyde 2. reaction between acetic acid and ethanol 3. reaction between aspirin and sodium hydroxide 4. reaction of acetone with methanolarrow_forward2. Name and classify the degree of the following alcohols: OH 우 b. a. -OHarrow_forward
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