(a) Interpretation: The disulfide formed on oxidizing the following thiol should be determined: Concept Introduction: Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon. Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

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Answer 1

Question

Chapter 14, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Interpretation Introduction

(b)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

CH3(CH2)4SH

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

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An acid catalyst in nucleophilic addition of aldehydes and ketones is used for: Select one: a. Protonation of carbonyl carbon b. Making the aldehyde and ketone more susceptible to nucleophiles c. Increasing the nucleophilicity of the nucleophile d. To provide a medium for the reaction.

50. If this molecule was heated, which carboxyl group will be readily lost as carbon dioxid. C HO2C CO2H CO2H HO2C B a. b. B C. C d.

What is produced when most aldehydes undergo Grignard reaction? O A. primary alcohol B. secondary alcohol O C. tertiary alcohol O D. no reaction 2.

Answer 2

Question

Chapter 14, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Interpretation Introduction

(b)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

CH3(CH2)4SH

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

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Answer 3

Question

Chapter 14, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Interpretation Introduction

(b)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

CH3(CH2)4SH

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

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Answer 4

Question

Chapter 14, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Interpretation Introduction

(b)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

CH3(CH2)4SH

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

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Answer 5

Chapter 14, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Interpretation Introduction

(b)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

CH3(CH2)4SH

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Answer 6

Chapter 14, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Answer 7

Chapter 14, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

CH3(CH2)4SH

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

CH3(CH2)4SH

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 14.1 - Prob. 14.1P Ch. 14.2 - Prob. 14.1PP Ch. 14.2 - Classify each hydroxyl group in sorbitol as 1°,...Ch. 14.2 - Prob. 14.3P Ch. 14.2 - Prob. 14.4P Ch. 14.3 - Prob. 14.2PP Ch. 14.3 - Give the structure corresponding to each name a....Ch. 14.5 - Draw the products formed when each alcohol is...Ch. 14.5 - Prob. 14.6P Ch. 14.5 - Prob. 14.7P

Solution Summary: The author explains that thiols are considered as sulfur analogs of alcohols since S is placed directly below to the oxygen in the periodic table.

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