General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 14, Problem 50P
Rank the compounds in order of increasing melting point:
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Essential oils are concentrated liquid containing metabolites extracted from plant sources and are widely used in the production of
perfumes. The structures of some of these compounds present in essential oils, along with acetone, are presented below.
CH3
H2C
CH
H2
H3CO,
CH2
CH
H2C
H2C
CH
FCH2
HO
H3C
CH2
Compound A
MM: 164.2 g/mol
Boiling Point: 254 C
Compound B
MM: 162.19 g/mol
Boiling Point: 232 C
Compound C
MM: 136.24 g/mol
Boiling Point: 176 C
Determine the most possible boiling point of each of the compounds. Refer to the possible boiling points listed above.
An equal volume of COMPOUNDS A, B and C were stored in separate beakers which were left uncovered at room temperature.
1.
2.
If the three liquids were allowed to stand for about 10 minutes, which of the following will have the least amount of
liquid
b. What physical property is the basis of the answer?
Among the three liquids, what is the most recommended ingredient of a perfume that will have the most lasting scent?
а.…
Which of the following compounds has the lowest boiling point?
Не
Li Be
F
Ne
11
12
13
14
15
16
17
18
Na Mg
Al Si
cI Ar
19
20
21
22
23
24
25
26
27
2
21
33
34
25
36
К Са
Sc Ti
V
Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
37
42
43
44
47
53
54
Rb Sr
Y
Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te
Хе
COME
ST-
72
24
83
85
Cs Ba
Lu Hf Ta W Re Os
Ir
Pt Au Hg TI Pb Bi Po At Rn
87
102
163
104
106
108
110
111
112
114
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Uun Uuu Uub
Uuq
*Lanthanide series
La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb
**Actinide series
95
100
101
102
Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No
Select one:
Oa.
(CH);COH
Ob.
CH;CH;CH;CH;F
CH;CH;CH;CH;OH
Od. C(CH3)4
CH;CH2CH;CH2CH3
Choose the substance with the highest boiling point and explain why you choose it
-NaCl
-H2O
-O3
-CH4
Chapter 14 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 14.1 - Prob. 14.1PCh. 14.2 - Prob. 14.1PPCh. 14.2 - Classify each hydroxyl group in sorbitol as 1°,...Ch. 14.2 - Prob. 14.3PCh. 14.2 - Prob. 14.4PCh. 14.3 - Prob. 14.2PPCh. 14.3 - Give the structure corresponding to each name a....Ch. 14.5 - Draw the products formed when each alcohol is...Ch. 14.5 - Prob. 14.6PCh. 14.5 - Prob. 14.7P
Ch. 14.5 - Prob. 14.4PPCh. 14.6 - Prob. 14.8PCh. 14.7 - Prob. 14.9PCh. 14.7 - Prob. 14.5PPCh. 14.7 - Prob. 14.10PCh. 14.7 - Name each ether. CH3OCH2CH2CH2CH3Ch. 14.7 - Prob. 14.11PCh. 14.8 - (a) Translate the hall and stick model of...Ch. 14.8 - Prob. 14.13PCh. 14.9 - Prob. 14.14PCh. 14.9 - Prob. 14.15PCh. 14.9 - Prob. 14.16PCh. 14.9 - Prob. 14.17PCh. 14.9 - Prob. 14.18PCh. 14.9 - Prob. 14.19PCh. 14.9 - Prob. 14.20PCh. 14.10 - Give the IUPAC name for each thiol.Ch. 14.10 - Prob. 14.21PCh. 14.10 - Prob. 14.22PCh. 14 - Classify each alcohol as 1°, 2°, or 3o a....Ch. 14 - Prob. 24PCh. 14 - Prob. 25PCh. 14 - Classify each halide hi A as 1°, 2°, or 3°. A is a...Ch. 14 - Prob. 27PCh. 14 - Draw the structure of a molecule that fits each...Ch. 14 - Draw the structure of the six constitutional...Ch. 14 - Draw the structure of the four constitutional...Ch. 14 - Draw the structure of l-propanethiol, a compound...Ch. 14 - Prob. 32PCh. 14 - Prob. 33PCh. 14 - Prob. 34PCh. 14 - Prob. 35PCh. 14 - Answer each question about alcohol B. Draw a...Ch. 14 - Prob. 37PCh. 14 - Give the IUAPC name for each alcohol.Ch. 14 - Prob. 39PCh. 14 - Prob. 40PCh. 14 - Prob. 41PCh. 14 - Prob. 42PCh. 14 - Draw the structures and give the IUPAC names for...Ch. 14 - Prob. 44PCh. 14 - Prob. 45PCh. 14 - Prob. 46PCh. 14 - Give the structure corresponding to each IUPAC...Ch. 14 - Give the structure corresponding to each IUPAC...Ch. 14 - Which compound in each pair has the higher boiling...Ch. 14 - Rank the compounds in order of increasing melting...Ch. 14 - Rank the following compounds in order of...Ch. 14 - Rank the following compounds in order of...Ch. 14 - Prob. 53PCh. 14 - Prob. 54PCh. 14 - Prob. 55PCh. 14 - Prob. 56PCh. 14 - Prob. 57PCh. 14 - Prob. 58PCh. 14 - Prob. 59PCh. 14 - Prob. 60PCh. 14 - Prob. 61PCh. 14 - Prob. 62PCh. 14 - Prob. 63PCh. 14 - Prob. 64PCh. 14 - Prob. 65PCh. 14 - Prob. 66PCh. 14 - Prob. 67PCh. 14 - Prob. 68PCh. 14 - Prob. 69PCh. 14 - Prob. 70PCh. 14 - Prob. 71PCh. 14 - Prob. 72PCh. 14 - Prob. 73PCh. 14 - Prob. 74PCh. 14 - Prob. 75PCh. 14 - Prob. 76PCh. 14 - Prob. 77PCh. 14 - Prob. 78PCh. 14 - Prob. 79PCh. 14 - Prob. 80PCh. 14 - With reference to the halogenated organic...Ch. 14 - Prob. 82PCh. 14 - Prob. 83PCh. 14 - Prob. 84PCh. 14 - Write out the chemical reaction that occurs when a...Ch. 14 - Prob. 86PCh. 14 - Prob. 87PCh. 14 - Lactic acid [CH3CH(OH)CO2H] gives sour milk its...Ch. 14 - Prob. 89PCh. 14 - Prob. 90PCh. 14 - Prob. 91PCh. 14 - Prob. 92PCh. 14 - Prob. 93PCh. 14 - Answer the following questions about alcohol B....Ch. 14 - Prob. 95CPCh. 14 - Dehydration of alcohol C forms two products of...
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