Living by Chemistry
Living by Chemistry
2nd Edition
ISBN: 9781464142314
Author: Angelica M. Stacy
Publisher: W. H. Freeman
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Chapter U2.37, Problem 6E
Interpretation Introduction

Interpretation: The three molecules which have bent shape needs to be listed.

Concept Introduction: The Lewis structure of an organic compound represents the bonding of atoms with lone pairs (if any). It indicates the bonds with atoms and also arrangement of atoms in molecule.

Hybridization of any atom indicates the molecular geometry of molecule. The formula to check the hybridization can be written as:

Hybridization = Number of sigma bonds + Number of lone pair

The molecular geometry of molecules with lone pair on central atom is given by VSEPR theory.

Expert Solution & Answer
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Answer to Problem 6E

Living by Chemistry, Chapter U2.37, Problem 6E , additional homework tip  1Living by Chemistry, Chapter U2.37, Problem 6E , additional homework tip  2Living by Chemistry, Chapter U2.37, Problem 6E , additional homework tip  3

Explanation of Solution

For Lewis structure of H2S molecule, calculate total number of valence electrons:

H2S molecule = 6 electrons in S + 1 x 2 valence electrons in H = 8 electrons

Living by Chemistry, Chapter U2.37, Problem 6E , additional homework tip  4

Hybridization = Number of sigma bonds + Number of lone pair

Hybridization of S atom = 2 + 2 = 4 = sp3

For Lewis structure of H2O molecule, calculate total number of valence electrons:

H2O molecule = 6 electrons in O+ 1 x 2 valence electrons in H = 8 electrons

Living by Chemistry, Chapter U2.37, Problem 6E , additional homework tip  5

Hybridization = Number of sigma bonds + Number of lone pair

Hybridization of O atom = 2 + 2 = 4 = sp3

For Lewis structure of H2Se molecule, calculate total number of valence electrons:

H2Se molecule = 6 electrons in O+ 1 x 2 valence electrons in H = 8 electrons

Living by Chemistry, Chapter U2.37, Problem 6E , additional homework tip  6

Hybridization = Number of sigma bonds + Number of lone pair

Hybridization of Se atom = 2 + 2 = 4 = sp3

Thus, with sp3 hybridization, the molecular shape must be tetrahedral but due to presence of two lone pair on central atom, the geometry must be bent shape with bond angle less than 109°.

Conclusion

The presence of lone pairs on central atom changes the molecular geometry of molecules.

Chapter U2 Solutions

Living by Chemistry

Ch. U2.29 - Prob. 3ECh. U2.29 - Prob. 4ECh. U2.29 - Prob. 5ECh. U2.29 - Prob. 6ECh. U2.29 - Prob. 7ECh. U2.30 - Prob. 1TAICh. U2.30 - Prob. 1ECh. U2.30 - Prob. 2ECh. U2.30 - Prob. 3ECh. U2.30 - Prob. 4ECh. U2.30 - Prob. 5ECh. U2.31 - Prob. 1TAICh. U2.31 - Prob. 1ECh. U2.31 - Prob. 2ECh. U2.31 - Prob. 3ECh. U2.31 - Prob. 4ECh. U2.31 - Prob. 5ECh. U2.31 - Prob. 6ECh. U2.31 - Prob. 7ECh. U2.31 - Prob. 8ECh. U2.32 - Prob. 1TAICh. U2.32 - Prob. 1ECh. U2.32 - Prob. 2ECh. U2.32 - Prob. 3ECh. U2.32 - Prob. 4ECh. U2.32 - Prob. 5ECh. U2.32 - Prob. 6ECh. U2.32 - Prob. 7ECh. U2.32 - Prob. 8ECh. U2.32 - Prob. 9ECh. U2.33 - Prob. 1TAICh. U2.33 - Prob. 1ECh. U2.33 - Prob. 2ECh. U2.33 - Prob. 3ECh. U2.33 - Prob. 4ECh. U2.33 - Prob. 5ECh. U2.33 - Prob. 6ECh. U2.33 - Prob. 7ECh. U2.33 - Prob. 8ECh. U2.33 - Prob. 9ECh. U2.33 - Prob. 10ECh. U2.33 - Prob. 11ECh. U2.34 - Prob. 1TAICh. U2.34 - Prob. 1ECh. U2.34 - Prob. 2ECh. U2.34 - Prob. 3ECh. U2.34 - Prob. 4ECh. U2.34 - Prob. 5ECh. U2.35 - Prob. 1TAICh. U2.35 - Prob. 1ECh. U2.35 - Prob. 2ECh. U2.35 - Prob. 3ECh. U2.35 - Prob. 4ECh. U2.35 - Prob. 5ECh. U2.35 - Prob. 6ECh. U2.36 - Prob. 1TAICh. U2.36 - Prob. 1ECh. U2.36 - Prob. 2ECh. U2.36 - Prob. 3ECh. U2.36 - Prob. 4ECh. U2.36 - Prob. 5ECh. U2.36 - Prob. 6ECh. U2.36 - Prob. 7ECh. U2.37 - Prob. 1TAICh. U2.37 - Prob. 1ECh. U2.37 - Prob. 2ECh. U2.37 - Prob. 3ECh. U2.37 - Prob. 4ECh. U2.37 - Prob. 5ECh. U2.37 - Prob. 6ECh. U2.37 - Prob. 7ECh. U2.37 - Prob. 8ECh. U2.37 - Prob. 9ECh. U2.38 - Prob. 1TAICh. U2.38 - Prob. 1ECh. U2.38 - Prob. 2ECh. U2.38 - Prob. 3ECh. U2.38 - Prob. 4ECh. U2.38 - Prob. 5ECh. U2.38 - Prob. 6ECh. U2.38 - Prob. 7ECh. U2.39 - Prob. 1TAICh. U2.39 - Prob. 1ECh. U2.39 - Prob. 2ECh. U2.39 - Prob. 3ECh. U2.39 - Prob. 4ECh. U2.39 - Prob. 5ECh. U2.39 - Prob. 6ECh. U2.39 - Prob. 7ECh. U2.40 - Prob. 1TAICh. U2.40 - Prob. 1ECh. U2.40 - Prob. 2ECh. U2.40 - Prob. 3ECh. U2.40 - Prob. 4ECh. U2.40 - Prob. 5ECh. U2.41 - Prob. 1TAICh. U2.41 - Prob. 1ECh. U2.41 - Prob. 2ECh. U2.41 - Prob. 3ECh. U2.41 - Prob. 4ECh. U2.41 - Prob. 5ECh. U2.41 - Prob. 6ECh. U2.41 - Prob. 7ECh. U2.41 - Prob. 8ECh. U2.42 - Prob. 1TAICh. U2.42 - Prob. 1ECh. U2.42 - Prob. 2ECh. U2.42 - Prob. 4ECh. U2.42 - Prob. 5ECh. U2.42 - Prob. 6ECh. U2.43 - Prob. 1TAICh. U2.43 - Prob. 1ECh. U2.43 - Prob. 2ECh. U2.43 - Prob. 3ECh. U2.43 - Prob. 4ECh. U2.43 - Prob. 6ECh. U2.43 - Prob. 7ECh. U2.44 - Prob. 1TAICh. U2.44 - Prob. 1ECh. U2.44 - Prob. 2ECh. U2.44 - Prob. 3ECh. U2.44 - Prob. 4ECh. U2.44 - Prob. 5ECh. U2.44 - Prob. 6ECh. U2.44 - Prob. 7ECh. U2.44 - Prob. 8ECh. U2.44 - Prob. 9ECh. U2.45 - Prob. 1TAICh. U2.45 - Prob. 1ECh. U2.45 - Prob. 2ECh. U2.45 - Prob. 3ECh. U2.45 - Prob. 4ECh. U2.45 - Prob. 5ECh. U2.45 - Prob. 6ECh. U2.45 - Prob. 7ECh. U2.46 - Prob. 1TAICh. U2.46 - Prob. 1ECh. U2.46 - Prob. 2ECh. U2.46 - Prob. 3ECh. U2.46 - Prob. 4ECh. U2.46 - Prob. 5ECh. U2.46 - Prob. 6ECh. U2.46 - Prob. 7ECh. U2.46 - Prob. 8ECh. U2.46 - Prob. 9ECh. U2.47 - Prob. 1TAICh. U2.47 - Prob. 1ECh. U2.47 - Prob. 2ECh. U2.47 - Prob. 3ECh. U2.47 - Prob. 4ECh. U2.47 - Prob. 5ECh. U2.47 - Prob. 6ECh. U2.47 - Prob. 7ECh. U2.47 - Prob. 8ECh. U2.47 - Prob. 9ECh. U2.48 - Prob. 1TAICh. U2.48 - Prob. 1ECh. U2.48 - Prob. 2ECh. U2.48 - Prob. 3ECh. U2.48 - Prob. 4ECh. U2.48 - Prob. 6ECh. U2 - Prob. C6.1RECh. U2 - Prob. C6.2RECh. U2 - Prob. C6.3RECh. U2 - Prob. C6.4RECh. U2 - Prob. C6.5RECh. U2 - Prob. C7.1RECh. U2 - Prob. C7.2RECh. U2 - Prob. C7.3RECh. U2 - Prob. C7.4RECh. U2 - Prob. C7.5RECh. U2 - Prob. C8.1RECh. U2 - Prob. C8.2RECh. U2 - Prob. C8.3RECh. U2 - Prob. C8.4RECh. U2 - Prob. C8.5RECh. U2 - Prob. C8.6RECh. U2 - Prob. C9.1ECh. U2 - Prob. C9.2ECh. U2 - Prob. C9.3ECh. U2 - Prob. C9.4ECh. U2 - Prob. C9.5ECh. U2 - Prob. 1RECh. U2 - Prob. 2RECh. U2 - Prob. 3RECh. U2 - Prob. 4RECh. U2 - Prob. 5RECh. U2 - Prob. 6RECh. U2 - Prob. 7RECh. U2 - Prob. 8RECh. U2 - Prob. 1STPCh. U2 - Prob. 2STPCh. U2 - Prob. 3STPCh. U2 - Prob. 4STPCh. U2 - Prob. 5STPCh. U2 - Prob. 6STPCh. U2 - Prob. 7STPCh. U2 - Prob. 8STPCh. U2 - Prob. 9STPCh. U2 - Prob. 10STPCh. U2 - Prob. 11STPCh. U2 - Prob. 12STPCh. U2 - Prob. 13STPCh. U2 - Prob. 14STPCh. U2 - Prob. 15STPCh. U2 - Prob. 16STPCh. U2 - Prob. 17STPCh. U2 - Prob. 18STPCh. U2 - Prob. 19STPCh. U2 - Prob. 20STP
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