Chemical Principles: The Quest for Insight
Chemical Principles: The Quest for Insight
7th Edition
ISBN: 9781464183959
Author: Peter Atkins, Loretta Jones, Leroy Laverman
Publisher: W. H. Freeman
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Chapter 3, Problem 3E.1BST
Interpretation Introduction

Interpretation:

Pressure in tank that has volume of 100 L with 20 mol CO2 at 20 °C has to be determined.

Concept Introduction:

Real gases consist of atoms or molecules that have intermolecular attractions as well as repulsions. These gases deviate from ideal gases in terms of intermolecular forces. Such gases obey van der Waals equation. Van der Waals equation is as follows:

  (P+an2V2)(Vnb)=nRT

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The pressure P of a sample of oxygen gas that is compressed at a constant temperature is related to the volume V of gas by a reciprocal function of the form  P =  k V . (a) A sample of oxygen gas that occupies 0.674 m3 exerts a pressure of 39 kPa at a temperature of 293 K (absolute temperature measured on the Kelvin scale). Find the value of k (in kPa · m3) in the given model.
The van der Waals equation, nRT = [P + (n/V)2a)](v-nb) incorporates corrections to the ideal gas law in order to account for the properties of real gases. One of the corrections accounts for     the quantum behavior of molecules.     that average kinetic energy is inversely proportional to temperature.     the finite volume of molecules.     the possibility of chemical reaction between molecules.
(5) Using the data in Table 1C.3 (from the textbook), calculate the pressure that 2.500 moles of carbon dioxide confined in a volume of 1.000 L at 450 K exerts. Compare the pressure with that calculated assuming ideal-gas behavior.

Chapter 3 Solutions

Chemical Principles: The Quest for Insight

Ch. 3 - Prob. 3A.5ECh. 3 - Prob. 3A.6ECh. 3 - Prob. 3A.7ECh. 3 - Prob. 3A.8ECh. 3 - Prob. 3A.9ECh. 3 - Prob. 3A.10ECh. 3 - Prob. 3B.1ASTCh. 3 - Prob. 3B.1BSTCh. 3 - Prob. 3B.2ASTCh. 3 - Prob. 3B.2BSTCh. 3 - Prob. 3B.3ASTCh. 3 - Prob. 3B.3BSTCh. 3 - Prob. 3B.4ASTCh. 3 - Prob. 3B.4BSTCh. 3 - Prob. 3B.5ASTCh. 3 - Prob. 3B.5BSTCh. 3 - Prob. 3B.6ASTCh. 3 - Prob. 3B.6BSTCh. 3 - Prob. 3B.7ASTCh. 3 - Prob. 3B.7BSTCh. 3 - Prob. 3B.8ASTCh. 3 - Prob. 3B.8BSTCh. 3 - Prob. 3B.1ECh. 3 - Prob. 3B.2ECh. 3 - Prob. 3B.5ECh. 3 - Prob. 3B.6ECh. 3 - Prob. 3B.9ECh. 3 - Prob. 3B.10ECh. 3 - Prob. 3B.11ECh. 3 - Prob. 3B.12ECh. 3 - Prob. 3B.13ECh. 3 - Prob. 3B.14ECh. 3 - Prob. 3B.15ECh. 3 - Prob. 3B.16ECh. 3 - Prob. 3B.17ECh. 3 - Prob. 3B.18ECh. 3 - Prob. 3B.19ECh. 3 - Prob. 3B.20ECh. 3 - Prob. 3B.21ECh. 3 - Prob. 3B.22ECh. 3 - Prob. 3B.23ECh. 3 - Prob. 3B.24ECh. 3 - Prob. 3B.25ECh. 3 - Prob. 3B.26ECh. 3 - Prob. 3B.27ECh. 3 - Prob. 3B.28ECh. 3 - Prob. 3B.29ECh. 3 - Prob. 3B.30ECh. 3 - Prob. 3B.31ECh. 3 - Prob. 3B.32ECh. 3 - Prob. 3B.33ECh. 3 - Prob. 3B.34ECh. 3 - Prob. 3B.35ECh. 3 - Prob. 3B.36ECh. 3 - Prob. 3B.37ECh. 3 - Prob. 3B.38ECh. 3 - Prob. 3B.39ECh. 3 - Prob. 3B.40ECh. 3 - Prob. 3B.41ECh. 3 - Prob. 3B.42ECh. 3 - Prob. 3C.1ASTCh. 3 - Prob. 3C.1BSTCh. 3 - Prob. 3C.2ASTCh. 3 - Prob. 3C.2BSTCh. 3 - Prob. 3C.3ASTCh. 3 - Prob. 3C.3BSTCh. 3 - Prob. 3C.1ECh. 3 - Prob. 3C.2ECh. 3 - Prob. 3C.3ECh. 3 - Prob. 3C.4ECh. 3 - Prob. 3C.5ECh. 3 - Prob. 3C.6ECh. 3 - Prob. 3C.7ECh. 3 - Prob. 3C.8ECh. 3 - Prob. 3C.9ECh. 3 - Prob. 3C.10ECh. 3 - Prob. 3C.11ECh. 3 - Prob. 3C.12ECh. 3 - Prob. 3C.13ECh. 3 - Prob. 3C.14ECh. 3 - Prob. 3C.15ECh. 3 - Prob. 3C.16ECh. 3 - Prob. 3D.1ASTCh. 3 - Prob. 3D.1BSTCh. 3 - Prob. 3D.2ASTCh. 3 - Prob. 3D.2BSTCh. 3 - Prob. 3D.1ECh. 3 - Prob. 3D.2ECh. 3 - Prob. 3D.3ECh. 3 - Prob. 3D.4ECh. 3 - Prob. 3D.5ECh. 3 - Prob. 3D.6ECh. 3 - Prob. 3D.7ECh. 3 - Prob. 3D.8ECh. 3 - Prob. 3D.9ECh. 3 - Prob. 3D.10ECh. 3 - Prob. 3D.11ECh. 3 - Prob. 3D.12ECh. 3 - Prob. 3D.13ECh. 3 - Prob. 3D.14ECh. 3 - Prob. 3D.15ECh. 3 - Prob. 3D.16ECh. 3 - Prob. 3D.17ECh. 3 - Prob. 3D.18ECh. 3 - Prob. 3E.1ASTCh. 3 - Prob. 3E.1BSTCh. 3 - Prob. 3E.1ECh. 3 - Prob. 3E.2ECh. 3 - Prob. 3E.3ECh. 3 - Prob. 3E.4ECh. 3 - Prob. 3E.5ECh. 3 - Prob. 3E.6ECh. 3 - Prob. 3E.7ECh. 3 - Prob. 3E.8ECh. 3 - Prob. 3E.9ECh. 3 - Prob. 3E.10ECh. 3 - Prob. 3E.13ECh. 3 - Prob. 3E.14ECh. 3 - Prob. 3F.1ASTCh. 3 - Prob. 3F.1BSTCh. 3 - Prob. 3F.2ASTCh. 3 - Prob. 3F.2BSTCh. 3 - Prob. 3F.3ASTCh. 3 - Prob. 3F.3BSTCh. 3 - Prob. 3F.1ECh. 3 - Prob. 3F.2ECh. 3 - Prob. 3F.3ECh. 3 - Prob. 3F.4ECh. 3 - Prob. 3F.5ECh. 3 - Prob. 3F.6ECh. 3 - Prob. 3F.7ECh. 3 - Prob. 3F.8ECh. 3 - Prob. 3F.9ECh. 3 - Prob. 3F.10ECh. 3 - Prob. 3F.11ECh. 3 - Prob. 3F.12ECh. 3 - Prob. 3F.13ECh. 3 - Prob. 3F.14ECh. 3 - Prob. 3F.15ECh. 3 - Prob. 3F.16ECh. 3 - Prob. 3F.17ECh. 3 - Prob. 3F.18ECh. 3 - Prob. 3F.19ECh. 3 - Prob. 3F.20ECh. 3 - Prob. 3F.21ECh. 3 - Prob. 3F.22ECh. 3 - Prob. 3G.1ECh. 3 - Prob. 3G.2ECh. 3 - Prob. 3G.3ECh. 3 - Prob. 3G.4ECh. 3 - Prob. 3G.5ECh. 3 - Prob. 3G.6ECh. 3 - Prob. 3G.7ECh. 3 - Prob. 3G.8ECh. 3 - Prob. 3G.9ECh. 3 - Prob. 3G.10ECh. 3 - Prob. 3G.11ECh. 3 - Prob. 3G.12ECh. 3 - Prob. 3G.13ECh. 3 - Prob. 3G.14ECh. 3 - Prob. 3G.15ECh. 3 - Prob. 3G.16ECh. 3 - Prob. 3G.17ECh. 3 - Prob. 3G.18ECh. 3 - Prob. 3H.1ASTCh. 3 - Prob. 3H.1BSTCh. 3 - Prob. 3H.2ASTCh. 3 - Prob. 3H.2BSTCh. 3 - Prob. 3H.3ASTCh. 3 - Prob. 3H.3BSTCh. 3 - Prob. 3H.4ASTCh. 3 - Prob. 3H.4BSTCh. 3 - Prob. 3H.5ASTCh. 3 - Prob. 3H.5BSTCh. 3 - Prob. 3H.1ECh. 3 - Prob. 3H.2ECh. 3 - Prob. 3H.3ECh. 3 - Prob. 3H.4ECh. 3 - Prob. 3H.5ECh. 3 - Prob. 3H.6ECh. 3 - Prob. 3H.7ECh. 3 - Prob. 3H.8ECh. 3 - Prob. 3H.9ECh. 3 - Prob. 3H.10ECh. 3 - Prob. 3H.11ECh. 3 - Prob. 3H.12ECh. 3 - Prob. 3H.13ECh. 3 - Prob. 3H.14ECh. 3 - Prob. 3H.15ECh. 3 - Prob. 3H.16ECh. 3 - Prob. 3H.17ECh. 3 - Prob. 3H.19ECh. 3 - Prob. 3H.20ECh. 3 - Prob. 3H.23ECh. 3 - Prob. 3H.24ECh. 3 - Prob. 3H.25ECh. 3 - Prob. 3H.26ECh. 3 - Prob. 3H.27ECh. 3 - Prob. 3H.28ECh. 3 - Prob. 3H.29ECh. 3 - Prob. 3H.30ECh. 3 - Prob. 3H.31ECh. 3 - Prob. 3H.32ECh. 3 - Prob. 3H.33ECh. 3 - Prob. 3H.34ECh. 3 - Prob. 3H.35ECh. 3 - Prob. 3H.36ECh. 3 - Prob. 3I.1ASTCh. 3 - Prob. 3I.1BSTCh. 3 - Prob. 3I.2ASTCh. 3 - Prob. 3I.2BSTCh. 3 - Prob. 3I.3ASTCh. 3 - Prob. 3I.3BSTCh. 3 - Prob. 3I.4ASTCh. 3 - Prob. 3I.4BSTCh. 3 - Prob. 3I.1ECh. 3 - Prob. 3I.2ECh. 3 - Prob. 3I.3ECh. 3 - Prob. 3I.4ECh. 3 - Prob. 3I.5ECh. 3 - Prob. 3I.6ECh. 3 - Prob. 3I.7ECh. 3 - Prob. 3I.8ECh. 3 - Prob. 3I.11ECh. 3 - Prob. 3I.12ECh. 3 - Prob. 3I.13ECh. 3 - Prob. 3I.14ECh. 3 - Prob. 3I.15ECh. 3 - Prob. 3I.16ECh. 3 - Prob. 3J.1ASTCh. 3 - Prob. 3J.1BSTCh. 3 - Prob. 3J.2ASTCh. 3 - Prob. 3J.2BSTCh. 3 - Prob. 3J.3ASTCh. 3 - Prob. 3J.3BSTCh. 3 - Prob. 3J.1ECh. 3 - Prob. 3J.2ECh. 3 - Prob. 3J.3ECh. 3 - Prob. 3J.4ECh. 3 - Prob. 3J.5ECh. 3 - Prob. 3J.6ECh. 3 - Prob. 3J.7ECh. 3 - Prob. 3J.8ECh. 3 - Prob. 3J.9ECh. 3 - Prob. 3J.10ECh. 3 - Prob. 3J.11ECh. 3 - Prob. 3J.12ECh. 3 - Prob. 3J.13ECh. 3 - Prob. 3J.14ECh. 3 - Prob. 3J.15ECh. 3 - Prob. 3J.16ECh. 3 - Prob. 3.1ECh. 3 - Prob. 3.2ECh. 3 - Prob. 3.3ECh. 3 - Prob. 3.4ECh. 3 - Prob. 3.5ECh. 3 - Prob. 3.6ECh. 3 - Prob. 3.7ECh. 3 - Prob. 3.8ECh. 3 - Prob. 3.9ECh. 3 - Prob. 3.10ECh. 3 - Prob. 3.11ECh. 3 - Prob. 3.12ECh. 3 - Prob. 3.13ECh. 3 - Prob. 3.15ECh. 3 - Prob. 3.18ECh. 3 - Prob. 3.19ECh. 3 - Prob. 3.23ECh. 3 - Prob. 3.24ECh. 3 - Prob. 3.25ECh. 3 - Prob. 3.26ECh. 3 - Prob. 3.27ECh. 3 - Prob. 3.29ECh. 3 - Prob. 3.31ECh. 3 - Prob. 3.32ECh. 3 - Prob. 3.35ECh. 3 - Prob. 3.36ECh. 3 - Prob. 3.37ECh. 3 - Prob. 3.38ECh. 3 - Prob. 3.40ECh. 3 - Prob. 3.41ECh. 3 - Prob. 3.42ECh. 3 - Prob. 3.45ECh. 3 - Prob. 3.47ECh. 3 - Prob. 3.49ECh. 3 - Prob. 3.50ECh. 3 - Prob. 3.51ECh. 3 - Prob. 3.53ECh. 3 - Prob. 3.54ECh. 3 - Prob. 3.55ECh. 3 - Prob. 3.56ECh. 3 - Prob. 3.57ECh. 3 - Prob. 3.58ECh. 3 - Prob. 3.59ECh. 3 - Prob. 3.60ECh. 3 - Prob. 3.61ECh. 3 - Prob. 3.62ECh. 3 - Prob. 3.63ECh. 3 - Prob. 3.64ECh. 3 - Prob. 3.65ECh. 3 - Prob. 3.66ECh. 3 - Prob. 3.67ECh. 3 - Prob. 3.68E
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