Concept explainers
(a)
Interpretation:
Molar volume of an ideal gas at
Concept Introduction:
The mathematical relation between volume and amount at constant pressure as per the
Here,
Or it can also be expressed as follows:
Here,
(b)
Interpretation:
Molar volume of an ideal gas at
Concept Introduction:
The mathematical relation between volume and amount at constant pressure as per the
Here,
Or it can also be expressed as follows:
Here,
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Chemical Principles: The Quest for Insight
- What possible uses exist for the natural gas liquids that are removed from natural gas during its processing?arrow_forwardA student experimentally determines the gas law constant, R, by reacting a small piece of magnesium with excess hydrochloric acid and then collecting the hydrogen gas over water in a eudiometer. Based on experimentally collected data, the student calculates R to equal L'atm 0.0832 mol·K L'atm Ideal gas law constant from literature: 0.08206 mol·K (a) Determine the percent error for the student's R-value. Percent error =|1.389 (b) For the statements below, identify the possible source(s) of error for this student's trial. The student uses the barometric pressure for the lab to calculate R. The student does not equilibrate the water levels within the eudiometer and the beaker at the end of the reaction. The water level in the eudiometer is 1-inch above the water level in the beaker. The student does not clean the zinc metal with sand paper. The student notices a large air bubble in the eudiometer after collecting the hydrogen gas, but does not dislodge it.arrow_forwardThe water pressure of mercury at 25 degrees Celsius is 1.85 mmHg. arrow_forward
- Iodine has an orthorhombic unit cell for which the a, b, and c lattice parameters are 0.479, 0.725, and 0.978 nm, respectively. (a) If the atomic packing factor and atomic radius are 0.547 and 0.177 nm, respectively, determine the number of atoms in each unit cell. (b) The atomic weight of iodine is 126.91 g/mol; compute its theoretical density.arrow_forward(b) A mixture of helium, hydrogen and carbon dioxide gases are at a pressure of 1200 torr in a 4 L closed container. There are a total of 24 moles of gas molecules in the container. If the helium concentration is 2 moles/L and hydrogen concentration is 1.5 moles/L, estimate the partial pressure of carbon dioxide in atm.arrow_forwardA sample of volume 258 cm3has a mass of 2.71 kg.(a) Is the material gaseous or condensed?(b) If the molar mass of the material is 108 g mol-1 , calculate its molar volume.arrow_forward
- The partial pressure of water vapor in saturated air at 34 °C is 5.25×10-2 atm. (a) How many molecules of water are in 1.16 cm3 of saturated air at 34 °C? (b) What volume of saturated air at 34 °C contains 0.563 mol of water?arrow_forward9. The critical temperature of oxygen is 155 K. What does this mean? (a) Oxygen is very cold. (b) The critical pressure must be > 155 bar. (c) It is impossible to produce liquid oxygen by compression alone if its temperature is > 155 K. (d) It is critical to keep oxygen at a temperature of 155 K.arrow_forwardNatural gas is a mixture of hydrocarbons, primarily methane (CH4) and ethane (C2H6). A typical mixture might have mole fraction of methane = 0.915 and mole fraction of ethane = 0.085. (a) What are the partial pressure of the two gases in a 14.10 L container of natural gas at 30 degrees Celcius and 1.34 atm? (b) Assuming complete combustion of both gases in the natural gas sample, what is the total mass of water formed? Hint: Write the balanced combustion chemical equation for each gas separately in the gas mixture to find the mass of water formed.arrow_forward
- A 6.53-g sample of a mixture of magnesium carbonateand calcium carbonate is treated with excesshydrochloric acid. The resulting reaction produces 1.72 Lof carbon dioxide gas at 28 °C and 743 torr pressure.(a) Write balanced chemical equations for the reactionsthat occur between hydrochloric acid and each componentof the mixture. (b) Calculate the total number ofmoles of carbon dioxide that forms from these reactions.(c) Assuming that the reactions are complete, calculatethe percentage by mass of magnesium carbonate in themixture.arrow_forwardThe partial pressure of oxygen in a mixture of oxygen andhydrogen is 0.200 atm, and that of hydrogen is 0.800 atm.(a) How many molecules of oxygen are in a 1.500-L container of this mixture at 40°C?(b) If a spark is introduced into the container, how many grams of water will be produced?arrow_forwardMass of a vacuumed (empty) vessel of volume 5 L is 640.05 g, and mass of the same vessel filled with this hydrocarbon up to the pressure 2.0 atm at 22 oC is 658.23 g. What is the molecular formula of the hydrocarbon?arrow_forward
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