EP ESSENTIAL ORG.CHEM.-MOD.MASTERING3rd EditionBruice Publisher: PEARSON COISBN: 9780133858501
EP ESSENTIAL ORG.CHEM.-MOD.MASTERING
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Chapter 1 - Remembering General Chemistry: Electronic Structure And BondingChapter 1.1 - The Structure Of An AtomChapter 1.2 - How The Electrons In An Atom Are DistributedChapter 1.3 - Ionic And Covalent BondsChapter 1.4 - How The Structure Of A Compound Is RepresentedChapter 1.7 - How Single Bonds Are Formed In Organic CompoundsChapter 1.9 - How A Triple Bond Is Formed: The Bonds In EthyneChapter 1.11 - The Bonds In Ammonia And In The Ammonium IonChapter 1.12 - The Bonds In WaterChapter 1.13 - The Bond In A Hydrogen Halide
Chapter 1.14 - Summary: Hybridization, Bond Lengths, Bond Strengths, And Bond AnglesChapter 1.15 - Dipole Moments Of MoleculesChapter 2 - Acids And Bases: Central To Understanding Organic ChemistryChapter 2.1 - An Introduction To Acids And BasesChapter 2.2 - Pka And PhChapter 2.3 - Organic Acids And BasesChapter 2.4 - How To Predict The Outcome Of An Acid-base ReactionChapter 2.5 - How To Determine The Position Of EquilibriumChapter 2.6 - How The Structure Of An Acid Affects Its Pka ValueChapter 2.7 - How Substituents Affect The Strength Of An AcidChapter 2.8 - An Introduction To Delocalized ElectronsChapter 2.10 - How Ph Affects The Structure Of An Organic CompoundChapter 2.11 - Buffer SolutionsChapter 3 - An Introduction To Organic CompoundsChapter 3.1 - How Alkyl Substituents Are NamedChapter 3.2 - The Nomenclature Of AlkanesChapter 3.3 - The Nomenclature Of Cycloalkanes • Skeletal StructuresChapter 3.4 - The Nomenclature Of Alkyl HalidesChapter 3.5 - The Classification Of Alkyl Halides, Alcohols, And AminesChapter 3.6 - The Structures Of Alkyl Halides, Alcohols, Ethers, And AminesChapter 3.7 - Noncovalent InteractionsChapter 3.8 - Factors That Affect The Solubility Of Organic CompoundsChapter 3.9 - Rotation Occurs About Carbon-carbon Single BondsChapter 3.11 - Conformers Of CyclohexaneChapter 3.12 - Conformers Of Monosubstituted CyclohexanesChapter 3.13 - Conformers Of Disubstituted CyclohexanesChapter 4 - Isomers: The Arrangement Of Atoms In SpaceChapter 4.1 - Cis-trans Isomers Result From Restricted RotationChapter 4.2 - Designating Geometric Isomers Using The E,z SystemChapter 4.3 - A Chiral Object Has A Nonsuperimposable Mirror ImageChapter 4.4 - An Asymmetric Center Is A Cause Of Chirality In A MoleculeChapter 4.5 - Isomers With One Asymmetric CenterChapter 4.6 - How To Draw EnantiomersChapter 4.7 - Naming Enantiomers By The R,s SystemChapter 4.8 - Chiral Compounds Are Optically ActiveChapter 4.9 - How Specific Rotation Is MeasuredChapter 4.10 - Isomers With More Than One Asymmetric CenterChapter 4.11 - Stereoisomers Of Cyclic CompoundsChapter 4.12 - Meso Compounds Have Asymmetric Centers But Are Optically InactiveChapter 5 - AlkenesChapter 5.1 - The Nomenclature Of AlkenesChapter 5.3 - How Alkenes React • Curved Arrows Show The Flow Of ElectronsChapter 5.4 - Thermodynamics: How Much Product Is Formed?Chapter 5.6 - Calculating Δη° Values To Determine The Relative Stabilities Of AlkenesChapter 5.7 - Kinetics: How Fast Is The Product Formed?Chapter 5.9 - A Reaction Coordinate Diagram Describes The Energy Changes That Take Place During A ReactionChapter 5.10 - CatalysisChapter 6 - The Reaction Of Alkenes And AlkynesChapter 6.1 - The Addition Of A Hydrogen Halide To An AlkeneChapter 6.2 - Carbocation Stability Depends On The Number Of Alkyl Groups Attached To The Positively Charged CarbonChapter 6.3 - Electrphilic Addition Reactions Are RegioselectiveChapter 6.5 - The Addition Of Water To An AlkeneChapter 6.6 - The Stereochemistry Of Alkene ReactionsChapter 6.8 - Enantiomers Can Be Distinguished By Biological MoleculesChapter 6.10 - The Nomenclature Of AlkynesChapter 6.11 - The Structure Of AlkynesChapter 6.13 - The Addition Of A Hydrogen Halide To An AlkyneChapter 6.14 - The Addition Of Water To An AlkyneChapter 6.15 - The Addition Of Hydrogen To An AlkyneChapter 7 - Delocalized Electrons: Their Effect On Stability, Pka, And The Products Of A Reaction • Aromaticity And Electronic Effects: An Introduction To The Reactions Of BenzeneChapter 7.4 - How To Draw Resonance ContributorsChapter 7.5 - The Predicted Stabilities Of Resonance ContributorsChapter 7.6 - Delocalization Energy Is The Additional Stability Delocalized Electrons Give To A CompoundChapter 7.7 - Delocalized Electrons Increase StabilityChapter 7.8 - Delocalized Electrons Affect Pka ValuesChapter 7.9 - Electronic EffectsChapter 7.11 - Reactions Of DienesChapter 7.12 - The Diels-alder Reaction Is A 1,4-addition ReactionChapter 7.15 - Applying The Criteria For AromaticityChapter 7.17 - The Mechanism For Electrophilic Aromatic Substitution ReactionsChapter 8 - Substitution And Elimination Reactions Of Alkyl HalidesChapter 8.1 - The Mechanism Of An Sn2 ReactionChapter 8.2 - Factors That Affect Sn2 ReactionsChapter 8.3 - The Mechanism Of An Sn1 ReactionChapter 8.4 - Factors That Affect Sn1 ReactionsChapter 8.5 - Comparing Sn2 And Sn1 ReactionsChapter 8.6 - Intermolecular Versus Intramolecular ReactionsChapter 8.9 - Relative Reactivities Of Alkyl Halides ReactionsChapter 8.11 - Competition Between Substitution And EliminationChapter 8.12 - Solvent EffectsChapter 8.13 - Substitution Reactions In SynthesisChapter 9 - Reactions Of Alcohols, Ethers, Epoxides, Amines, And ThiolsChapter 9.1 - The Nomenclatur Of AlcoholsChapter 9.2 - Activating An Alcohol For Nucleophilic Substitution By ProtonationChapter 9.4 - Elimination Reactions Of Alcohols: DehydrationChapter 9.5 - Oxidation Of AlcoholsChapter 9.6 - Nomenclature Of EthersChapter 9.8 - Nucleophilic Substitution Reactions Of EpoxidesChapter 9.9 - Using Carbocation Stability To Determine The Carcinogenicity Of An Arene OxideChapter 9.11 - Thiols, Sulfides, And Sulfonium IonsChapter 10 - Determining The Structure Of Organic CompoundsChapter 10.1 - Mass SpectrometryChapter 10.2 - The Mass Spectrum • FragmentationChapter 10.3 - Using The M/z Value Of The Molecular Ion To Calculate The Molecular FormulaChapter 10.4 - Isotopes In Mass SpectrometryChapter 10.5 - High-resolution Mass Spectrometry Can Reveal Molecular FormulasChapter 10.6 - Fragmentation PatternsChapter 10.8 - Spectroscopy And The Electromagnetic SpectrumChapter 10.12 - The Position Of Absorption BandsChapter 10.13 - The Position And Shape Of An Absorption Band Is Affected By Electron Delocalization, Electron Donation And Withdrawal, And Hydrogen BondingChapter 10.14 - The Absence Of Absorption BandsChapter 10.15 - How To Interpret An Infrared SpectrumChapter 10.17 - The Effect Of Conjugation On ΛmaxChapter 10.18 - The Visible Spectrum And ColorChapter 10.19 - Some Uses Of Uv/vis SpectroscopyChapter 10.22 - The Number Of Signals In 1h Nmr SpectrumChapter 10.23 - The Chemical Shift Tells How Far The Signal Is From The Reference SignalChapter 10.24 - The Relative Positions Of 1h Nmr SignalsChapter 10.25 - The Characteristic Values Of Chemical ShiftsChapter 10.26 - The Integration Of Nmr Signals Reveals The Relative Number Of Protons Causing Each SignalChapter 10.27 - The Splitting Of Signals Is Described By The N+1 RuleChapter 10.28 - More Examples Of 1h Nmr SpectraChapter 10.29 - 13c Nmr SpectroscopyChapter 11 - Reactions Of Carboxylic Acids And Carboxylic Acid DerivativesChapter 11.1 - The Nomenclature Of Carboxylic Acids And Carboxylic Acid DerivativesChapter 11.2 - The Structures Of Carboxylic Acids And Carboxylic Acid DerivativesChapter 11.4 - How Carboxylic Acids And Carboxylic Acid Derivatives ReactChapter 11.5 - The Relative Reactivities Of Carboxylic Acids And Carboxylic Acid DerivativesChapter 11.6 - The Reactions Of Acyl ChloridesChapter 11.7 - The Reactions Of EstersChapter 11.8 - Acid-catalyzed Ester Hydrolysis And TransesterificationChapter 11.9 - Hydroxide-ion-promoted Ester HydrolysisChapter 11.10 - Reactions Of Carboxylic AcidsChapter 11.11 - Reactions Of AmidesChapter 11.12 - NitrilesChapter 11.13 - Acid AnhydridesChapter 11.14 - How Chemists Activate Carboxylic AcidsChapter 11.15 - How Cells Activate Carboxylic AcidsChapter 12 - Reactions Of Aldehydes And Ketones • More Reactions Of Carboxylic Acid DerivativesChapter 12.1 - The Nomenclature Of Aldehydes And KetonesChapter 12.2 - The Relative Reactivities Of Carbonyl CompoundsChapter 12.4 - Organometallic CompoundsChapter 12.5 - The Reactions Of Carbonyl Compounds With Grignard ReagentsChapter 12.6 - The Reactions Of Aldehydes And Ketones With Cyanide IonChapter 12.7 - The Reactions Of Carbonyl Compounds With Hydride IonsChapter 12.8 - The Reactions Of Aldehydes And Ketones With AminesChapter 12.9 - The Reactions Of Aldehydes And Ketones With AlcoholsChapter 12.10 - Nucleophilic Addition To Α,β-unsaturated Aldehydes And KetonesChapter 12.11 - Nucleophilic Addition To Α,β-unsaturated Carboxylic Acid DerivativesChapter 13 - Reactions At The Α-carbon Of Carbonyl CompoundsChapter 13.1 - The Aciidity Of An Α-hydrogenChapter 13.2 - Keto-enol TautomersChapter 13.3 - Keto-enol InterconversionChapter 13.4 - Alkylation Of Enolate IonsChapter 13.5 - An Aldol Addition Forms A Β-hydroxyaldehyde Or A Β-hydroxyketoneChapter 13.6 - The Dehydration Of Aldol Addition Products Forms Α,β-unsaturated Aldehydes And KetonesChapter 13.7 - A Crossed Aldol AdditionChapter 13.8 - A Claisen Condensation Forms A Β-keto EsterChapter 13.9 - Co2 Can Be Removed From A Carboxylic Acid That Has A Carbonyl Group At The 3-positionChapter 13.10 - Reactions At The Α-carbon In CellsChapter 14 - RadicalsChapter 14.2 - The Chlorination And Bromination Of AlkanesChapter 14.4 - The Distribution Of Products Depends On Radical StabilityChapter 14.5 - The Stereochemistry Of Radical Substitution ReactionsChapter 14.6 - Formation Of Explosive PeroxidesChapter 14.7 - Radical Reactions Occur In Biological SystemsChapter 15 - Synthetic PolymersChapter 15.2 - Chain-growth PolymersChapter 15.5 - Polymerization Of Dienes • Natural And Synthetic RubberChapter 15.6 - CopolymersChapter 15.8 - Classes Of Step-growth PolymersChapter 15.10 - Biodegradable PolymersChapter 16 - The Organic Chemistry Of CarbohydratesChapter 16.1 - Classifying CarbohydratesChapter 16.2 - The D And L NotationChapter 16.3 - The Configurations Of AldosesChapter 16.4 - The Configurations Of KetosesChapter 16.5 - The Reactions Of Monosaccharides In Basic SolutionsChapter 16.6 - Monosaccharides Form Cyclic HemiacetalsChapter 16.8 - Formation Of GlycosidesChapter 16.9 - DisaccharidesChapter 16.10 - PolysaccharidesChapter 16.11 - Carbohydrates On Cell SurfacesChapter 17 - The Organic Chemistry Of Amino Acids, Peptides, And ProteinsChapter 17.1 - The Nomenclature Of Amino AcidsChapter 17.2 - The Configuration Of Amino AcidsChapter 17.3 - The Acid-base Properties Of Amino AcidsChapter 17.4 - The Isoelectric PointChapter 17.5 - Separating Amino AcidsChapter 17.6 - The Synthesis Of Amino AcidsChapter 17.7 - The Resolution Of Racemic Mixtures Of Amino AcidsChapter 17.8 - Peptide Bonds And Disulfide BondsChapter 17.10 - How To Determine The Primary Structure Of A Polypeptide Or A ProteinChapter 17.12 - Tertiary StructureChapter 17.13 - Quaternary StructureChapter 18 - How Enzymes Catalyze Reactions • The Organic Chemistry Of The VitaminsChapter 18.1 - Enzyme-catalyzed ReactionsChapter 18.2 - An Enzyme-catalyzed Reactions That Involved Two Sequential Sn2 ReactionsChapter 18.3 - An Enzyme-catalyzed Reaction That Is Reminiscent Of Acid-catalyzed Amide And Ester HydrolysisChapter 18.4 - An Enzyme-catalyzed Reaction That Is Reminiscent Of The Base-catalyzed Enediol RearrangementChapter 18.5 - Another Enzyme-catalyzed Reaction That Is Reminiscent Of A Retro-aldol AdditionChapter 18.7 - Niacin: The Vitamin Needed For Many Redox ReactionsChapter 18.8 - Riboflavin: Another Vitamin Used In Redox ReactionsChapter 18.9 - Vitamin B1: The Vitamin Needed For Acyl Group TransferChapter 18.10 - Vitamin H: The Vitamin Needed For Caboxylation Of An Α-carbonChapter 18.11 - Vitamin B6: The Vitamin Needed For Amino Acid TransformationsChapter 18.12 - Vitamin B12: The Vitamin Needed For Certain IsomerizationsChapter 18.13 - Folic Acid: The Vitamin Needed For One-carbon TransferChapter 19 - The Organic Chemistry Of The Metabolic PathwaysChapter 19.4 - The Catabolism Of FatsChapter 19.5 - The Catabolism Of CarbohydratesChapter 19.6 - The Fats Of PyruvateChapter 19.7 - The Catabolism Of ProteinsChapter 19.8 - The Citric Acid CycleChapter 19.9 - Oxidative PhosphorylationChapter 19.10 - AnabolismChapter 19.13 - Amino Acid BiosynthesisChapter 20 - The Organic Chemistry Of LipidsChapter 20.1 - Fatty Acids Are Long-chain Carboxylic AcidsChapter 20.2 - Fats And Oils Are TriglyveridesChapter 20.4 - Phosphoglycerides And SphingolipidsChapter 20.6 - Terpenes Contain Carbon Atoms In Multiples Of FiveChapter 20.7 - How Terpenes Are BiosynthesizedChapter 20.8 - How Nature Synthesizes CholesterolChapter 20.9 - Synthetic SteroidsChapter 21 - The Chemistry Of The Nucleic AcidsChapter 21.1 - Nucleosides And NucleotidesChapter 21.3 - The Secondary Structure Of Dna-the Double HelixChapter 21.4 - Why Dna Does Not Have A 2'-oh GroupChapter 21.5 - The Biosynthesis Of Dna Is Called ReplicationChapter 21.7 - The Biosynthesis Of Rna Is Called TranscriptionChapter 21.9 - The Biosynthesis Of Proteins Is Called TranslationChapter 21.10 - Why Dna Contains Thymine Instead Of UracilChapter 21.12 - How The Base Sequence Of Dna Is Determined
Sample Solutions for this Textbook
We offer sample solutions for EP ESSENTIAL ORG.CHEM.-MOD.MASTERING homework problems. See examples below:
Chapter 1, Problem 37PChapter 2, Problem 38PChapter 3, Problem 1PChapter 4, Problem 1PChapter 5, Problem 21PAnalyzing the given reaction it shows that Cl− serves as nucleophile since it contains lone pair of...Reason for correct options: The above compounds all have delocalized electrons, which undergo...Chapter 8, Problem 1PChapter 9, Problem 27P
Chapter 10, Problem 51PChapter 11, Problem 31PChapter 12, Problem 28PChapter 13, Problem 24P3-methyl hexane undergoes radical bromination and yields the 3-bromo-3-methylhexane according to the...Chapter 15, Problem 22PThe epimer of D-glucose is D-galactose because the configuration of D-galactose is only different at...Chapter 17, Problem 29PIn the below compound, negatively charged oxygen atom is in axial position where it can easily...Adenosine triphosphate (ATP) is an chemical compound which is involved in many purposes. The process...Cholesterol with hydrogen: Cholesterol reacts with hydrogen in presence of palladium-carbon to...Chapter 21, Problem 15P
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