Biochemistry: The Molecular Basis of Life
6th Edition
ISBN: 9780190209896
Author: Trudy McKee, James R. McKee
Publisher: Oxford University Press
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Chapter 7, Problem 27RQ
Summary Introduction
To review:
The classification of the following sugar pairsintoenantiomers, diastereomers, epimers, or aldose-ketose pair:
a. D-erythrose and D-threose
b. D-glucose and D-mannose
c. D-ribose and L-ribose
d. D-allose and D-galactose
e. D-glyceraldehyde and dihydroxyacetone.
Introduction:
Stereoisomers are those compounds thatdiffer only in the arrangement of an atom in their structure. Enantiomers are those type of stereoisomersthat are mirror images of each other. The stereoisomers that are not enantiomers are called diastereomers. Epimers are those diastereomersthatdiffer in the position of a single asymmetric carbon atom.
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Indicate whether the following pairs of monosaccharides are aldoses or ketoses. a. D-altrose & D-xylose
b. D-arabinose & D-glyceraldehyde
c. D-erythrulose & D-psicose
d. D-talose & D-gulose
e. dihydroxyacetone & D-tagatose
f. D-idose & D-threose
Indicate which of the terms monosaccharide, disaccharide, reducing sugar, anomers, enantiomers, and aldohexose applies to both members of each of the following pairs of substances. More than one term may apply to a given pair of substances.
a-D-Glucose and a-D-galactose-
Sucrose and cellobiose-
Glyceraldehyde and dihydroxyacetone-
D-Ribose and L-ribose-
Draw the Fischer projection formula for each sugar and give the importance/use of each. 1. D- glyceraldehyde 2. D- erythrose 3. D- ribose 4. D- deoxyribose 5. D- glucose 6. D- galactose 7. D- fructose 8. D- ribulose
Chapter 7 Solutions
Biochemistry: The Molecular Basis of Life
Ch. 7 - Prob. 1QCh. 7 - Prob. 2QCh. 7 - Prob. 3QCh. 7 - Prob. 4QCh. 7 - Prob. 5QCh. 7 - Prob. 6QCh. 7 - Prob. 7QCh. 7 - Prob. 1RQCh. 7 - Prob. 2RQCh. 7 - Prob. 3RQ
Ch. 7 - Prob. 4RQCh. 7 - Prob. 5RQCh. 7 - Prob. 6RQCh. 7 - Prob. 7RQCh. 7 - Prob. 8RQCh. 7 - Prob. 9RQCh. 7 - Prob. 10RQCh. 7 - Prob. 11RQCh. 7 - Prob. 12RQCh. 7 - Prob. 13RQCh. 7 - Prob. 14RQCh. 7 - Prob. 15RQCh. 7 - Prob. 16RQCh. 7 - Prob. 17RQCh. 7 - Prob. 18RQCh. 7 - Prob. 19RQCh. 7 - Prob. 20RQCh. 7 - Prob. 21RQCh. 7 - Prob. 22RQCh. 7 - Prob. 23RQCh. 7 - Prob. 24RQCh. 7 - Prob. 25RQCh. 7 - Prob. 26RQCh. 7 - Prob. 27RQCh. 7 - Prob. 28FBCh. 7 - Prob. 29FBCh. 7 - Prob. 30FBCh. 7 - Prob. 31FBCh. 7 - Prob. 32FBCh. 7 - Prob. 33FBCh. 7 - Prob. 34FBCh. 7 - Prob. 35FBCh. 7 - Prob. 36FBCh. 7 - Prob. 37FBCh. 7 - Prob. 38SACh. 7 - Prob. 39SACh. 7 - Prob. 40SACh. 7 - Prob. 41SACh. 7 - Prob. 42SACh. 7 - Prob. 43TQCh. 7 - Prob. 44TQCh. 7 - Prob. 45TQCh. 7 - Prob. 46TQCh. 7 - Prob. 47TQCh. 7 - Prob. 48TQCh. 7 - Prob. 49TQCh. 7 - Prob. 50TQCh. 7 - Prob. 51TQCh. 7 - Prob. 52TQCh. 7 - Prob. 53TQCh. 7 - Prob. 54TQCh. 7 - Prob. 55TQCh. 7 - Prob. 56TQCh. 7 - Prob. 57TQCh. 7 - Prob. 58TQCh. 7 - Prob. 59TQCh. 7 - Prob. 60TQCh. 7 - Prob. 61TQCh. 7 - Prob. 62TQCh. 7 - Prob. 63TQCh. 7 - Prob. 64TQCh. 7 - Prob. 65TQCh. 7 - Prob. 66TQCh. 7 - Prob. 67TQCh. 7 - Prob. 68TQCh. 7 - Prob. 69TQCh. 7 - Prob. 70TQ
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- Draw the respective enantiomer of the following sugar molecules: D-glyceraldehyde D-glucose D-mannose D-fructosearrow_forwardName which, if any, of the following groups are notaldose–ketose pairs: d-ribose and d-ribulose, d-glucose and dfructose, d-glyceraldehyde and dihydroxyacetone.arrow_forwardMatch the following sugars with their corresponding descriptions. A. Esculin J. 1. aldonitol G. rhamnose K cellobiose D. Melibiose E. saccharose C. raffinose H. trehalose F. Glucose B. Lactose Arabinose A. a pentose alcohol. B. a disaccharide consisting of glucose and galactose units linked by 3(1-4) glycosidic bond C. a trisaccharide consisting of galactose, fructose and glucose D. a disaccharide consisting of glucose and galactose units linked by a(1-6) glycosidic bond E. a disaccharide consisting of glucose and fructose linked by a1-32 glycosidic bond F. a monosaccharide under aldohexoses G. deoxymannose H. a disaccharide consisting of 2 glucose units linked by a(1-1) glycosidic bond I. glucoside of esculetin. J. a monosaccharide under aldopentoses K. a disaccharide consisting of 2 glucose units linked by B(1-4) glycosidic bondarrow_forward
- Define the following terms: a. reducing sugar b. alditol c. enediol d. acetal e. ketalarrow_forwardIdentify the type of isomerism exhibited by the following pairs of monosaccharides D-glyceraldehyde & dihydroxyacetone D-glucose & D-mannose α-D-glucose & β-D-glucose d-galactose & l-galactose D-glucose & D-allose A. optical isomers B. Diastereomers C. Epimers D. enantiomers E. Functional Isomersarrow_forwardName which, if any, of the following groups are not aldose– ketose pairs: D-ribose and D-ribulose, d-glucose and D-fructose, d-glyceraldehyde and dihydroxyacetone.arrow_forward
- Refer to the figure below. Determine whether the given descriptions between the relationship of glucose and galactose is correct or incorrect. * сно ÇHO H OH HO-H H- -OH HO-H HO H- H-OH ČH,OH D-Glucose -H -OH H- -он CH,OH D-Galactose CORRECT INCORRECT Glucose and galactose are both Aldohexoses They constitute the structure of the disaccharide maltose They are epimers at carbon 4 They are not mirror images of each other, neither an enantiomeric pairarrow_forwardIdentify whether each monosaccharide is an aldose or a ketose. Н НО Н Н НО- CHO ОН H -ОН ОН CH2OH CH2OH H CH₂OH Н НО Н CHO ОН CHO H -ОН CH₂OH н-с ОН CH2OH Н Н Н Н· CH2OH C=0 ОН CH2OH ... CHO ОН ОН ОН CH2OH Но Н Н Н CH2OH c=0 -Н -ОН CH2OH CH2OH О ОН ОН CH2OHarrow_forwardIdentify which of the following structural polysaccharides (amylopectin, amylose, glycogen, cellulose, and chitin) fits the description given below. A specific description may apply to more than one of the polysaccharides. 1. Contains both a(1→4) and a(1→6) glycosidic linkages 2. Polymer chain is unbranched 3. Glucose derivatives are present in the polymer chain 4. Contains only ß(1→4) glycosidic linkagesarrow_forward
- Referring to the structures in Figures 28.4 and 28.5, classify each pair of compounds as enantiomers, epimers, diastereomers but not epimers, or constitutional isomers of each other. a. D-allose and L-allose d. D-mannose and D-fructose b. D-altrose and D-gulose c. D-galactose and D-talose e. D-fructose and D-sorbose f. L-sorbose and L-tagatosearrow_forwardIndicate whether each of the following monosaccharides would be classified as an aldose, ketose, triose, tetrose, pentose, or hexose (each can be classified into two different categories). Which of these sugars would exist predominantly in the cyclic form?arrow_forwardName the enantiomer of D-glucose.arrow_forward
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