Organic Chemistry: Structure and Function
Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 5.5, Problem 5.18E

(a)

Interpretation Introduction

Interpretation: The Fisher projection of the compounds needs to be drawn.

Concept Introduction: The Fisher projection is the two-dimensional presentation of the molecule at the stereocenter atom. It represents by the cross lines.

(b)

Interpretation Introduction

Interpretation: The enantiomers and diastereomers of the Aspartame needs to be determined.

Concept Introduction:The enantiomers are mirror image of each other. They are non-super imposable to each other. Diastereomers are super imposable to each other.

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4. (a) Draw all possible isomers of C4H3CI2. (b) Indicate which pairs of compounds are enantiomers of one another. (c) Indicate which pairs of compounds are diastereomers of one another. (d) Indicate which compounds would have optical rotations of 0°. (e) Assign R and S configurations to all chirality centers of the compounds in part (a).
1) Below you are given the structures of the disaccharides lactose and trehalose. он он но он но но OH но но OH но он но но OH Lactose Trehalose a. Identify clearly the hemiacetal and acetal groups in these disaccharides and determine for each of these identified groups if they have a- or B-configuration.
Please identify the relationship between each pair of structures as: (i) identical, (ii) constitutional, (iii) conformational, (iv) enantiomers, or (v) diastereomers. Choose only one label per pair of structures.
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