Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 5.4, Problem 5.13E
Interpretation Introduction
Interpretation: The Fisher projection of the molecules needs to be drawn.
Concept Introduction:The Fisher projection is the diagram of the molecule in two dimensions. It is the arrangements of the substituent of the molecule at the stereocenteric carbon atom. Here, the horizontal lines are towards the observer and vertical lines are away from the observer.
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Chapter 5 Solutions
Organic Chemistry: Structure and Function
Ch. 5.1 - Prob. 5.3ECh. 5.1 - Prob. 5.4ECh. 5.1 - Prob. 5.5ECh. 5.2 - Prob. 5.6ECh. 5.2 - Prob. 5.8TIYCh. 5.3 - Prob. 5.9ECh. 5.3 - Prob. 5.11TIYCh. 5.3 - Prob. 5.12ECh. 5.4 - Prob. 5.13ECh. 5.4 - Prob. 5.14E
Ch. 5.4 - Prob. 5.16TIYCh. 5.4 - Prob. 5.17ECh. 5.5 - Prob. 5.18ECh. 5.5 - Prob. 5.19ECh. 5.5 - Prob. 5.20ECh. 5.6 - Prob. 5.21ECh. 5.6 - Prob. 5.22ECh. 5.6 - Prob. 5.23ECh. 5.7 - Prob. 5.24ECh. 5.7 - Prob. 5.26TIYCh. 5.7 - Prob. 5.27ECh. 5 - Prob. 5.1ECh. 5 - Prob. 5.2ECh. 5 - Prob. 30PCh. 5 - Prob. 31PCh. 5 - Prob. 32PCh. 5 - Prob. 33PCh. 5 - Prob. 34PCh. 5 - Prob. 35PCh. 5 - Prob. 36PCh. 5 - Prob. 37PCh. 5 - Prob. 38PCh. 5 - Prob. 39PCh. 5 - Prob. 40PCh. 5 - Prob. 41PCh. 5 - Prob. 42PCh. 5 - Prob. 43PCh. 5 - Prob. 44PCh. 5 - Prob. 45PCh. 5 - Prob. 46PCh. 5 - Prob. 47PCh. 5 - Prob. 48PCh. 5 - Prob. 49PCh. 5 - Prob. 50PCh. 5 - Prob. 51PCh. 5 - Prob. 52PCh. 5 - Prob. 53PCh. 5 - Prob. 54PCh. 5 - Prob. 55PCh. 5 - Prob. 56PCh. 5 - Prob. 57PCh. 5 - Prob. 58PCh. 5 - Prob. 59PCh. 5 - Prob. 60PCh. 5 - Prob. 61PCh. 5 - Prob. 62PCh. 5 - Prob. 63PCh. 5 - Prob. 64PCh. 5 - Prob. 65PCh. 5 - Prob. 66PCh. 5 - Prob. 67PCh. 5 - Prob. 68PCh. 5 - Prob. 69PCh. 5 - Prob. 70PCh. 5 - Prob. 71P
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- ors) Consider this compound with a chiral carbon, shown as a Fischer projection. Assign priorities to each group (1 through 4) by writing the appropriate number next to it, and assign the whole compound as R or S. CI 1927 CI Br ts 13 B Al Ga 14 C N 12.011 14.07 * SI P 32 Ge As * O 15 50 S Se F 21 22 2 He Ne Ar Br Krarrow_forwardComplete the Fischer projection that matches the following dash-wedge structure by dragging the correct group to the correct location. Br CN H OH OHarrow_forwardOrganic chem: Need some help naming Fischer projectionsarrow_forward
- 1. Identify all stereogenic centers (chiral C) with an* in the following molecules. a) OH nă Br b) o C-CH3arrow_forwardWhich sawhorse drawing below has the identical conformation as the following Fischer projection?arrow_forwardIn Fischer projections, the horizontal bonds represent groups projecting forward (on wedges) and the vertical bonds represent groups projecting backwards (on dashes). True or False True Falsearrow_forward
- Complete the following sentences regarding the partial Fischer projection show in the image below. H Match the words in the left column to the appropriate blanks in the sentences on the right. Make certain each sentence is complete before submitting your answer. NH₂ OH 1. Position "1" will be occupied by 2. Position "2" will be occupied by 3. Position "3" will be occupied by OH 4. Position "4" will be occupied by NH₂ Reset Help 3 CH3 Ph -2 -4arrow_forwardThe Fischer projection of glucose is shown. How man chiral centers does glucose have? How many stereoisomers of glucose can exist (including glucose, itself)? Define the absolute configurations (R or S) for carbons 2 and 3. H-C-OH HO-C-H H C-OH H-C-OH CH,OH owank o -n) wolad me glucosearrow_forward7B Compound A shown below is given. OH A Complete the Fischer projection below to represent compound A CH₂CH3 CH₂CH₂CH3arrow_forward
- Tasks Demonstrate the usefulness of Fischer projections by showing how it is easy to determine isomeric relationship between two structures. 1. Convert both isomers in Figure 8 to Fischer projections. 2. Identify the stereoisomeric relationship between the isomers. Briefly explain the process. ОН CI Br „Br "CI HO, isomer A isomer B Figure 8: Isomersarrow_forward8. The Fischer projection formula for D-mannose, a hexose sugar, is shown below. How many chiral centers are in D-mannose, please circle each Chiral C? HO- HO- H H CHO -H H -OH -OH CH₂OH Number of Chiral Centers and circle each in the structure: Study Guide Practice Questions 9. Draw the structure for 2-chloro-4-methylhexanal 10. What is the IUPAC name of the compound shown below? CH3 CH₂-C CH₂CH₂CH₂CHCH₂arrow_forwardAldosterone, a steroid involved in regulating blood pressure, is shown without dash-wedge notation. How many chiral centers does aldosterone have? OH HO, Aldosteronearrow_forward
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