Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 5, Problem 32P
(a)
Interpretation Introduction
Interpretation: The type of structures needs to be determined.
Concept Introduction:Structural isomers have the same chemical formula, but the atoms arrangements are different in both structures.
(b)
Interpretation Introduction
Interpretation: The type of structures needs to be determined.
Concept Introduction:The identical structures have same groups, but different positions.
(c)
Interpretation Introduction
Interpretation: The type of structures needs to be determined.
Concept Introduction:Structural isomers have same molecular formula, but the arrangements of atoms and groups are different.
(d)
Interpretation Introduction
Interpretation: The type of structures needs to be determined.
Concept Introduction:Conformers have the same formula, but the isomers can be interchanged by rotation at an angle.
(e)
Interpretation Introduction
Interpretation: The type of structures needs to be determined.
Concept Introduction:Structural isomers have same formula but different arrangements of molecules and atoms.
(f)
Interpretation Introduction
Interpretation: The type of structures needs to be determined.
Concept Introduction:Stereoisomer has same molecular formula, but the arrangements of the groups are different in 3-D space.
(f)
Interpretation Introduction
Interpretation: The type of structures needs to be determined.
Concept Introduction:Stereoisomer has same molecular formula, but the arrangements of the groups are different in 3-D space.
(g)
Interpretation Introduction
Interpretation: The type of structures needs to be determined.
Concept Introduction:Conformers have the same formula, but the groups are arranged in a different manner.
(h)
Interpretation Introduction
Interpretation: The type of structures needs to be determined.
Concept Introduction:Stereoisomer has same molecular formula, but the position of the groups is different in 3-D space.
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(b) Classify the following two pairs of structures as conformational or configurational isomers. Explain
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and
HO,
OH
il.
and
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For each of the following pairs, give the relationship between the two compounds. You many ignore conformational isomerism here, and any conformers may be considered to be identical compounds.
It is easy to imagine a cyclohexane as a flat hexagon and a lot of the time we draw it
that way. Looking at 1,3,5-triethylcyclohexane we cannot tell the stability of the
molecule from looking at the flat 2D drawing. Explain why we need to look at the 3D
configuration and what conformation (axial,equatorial) would each of the three ethyl
groups be in for the most stable configuration.
Chapter 5 Solutions
Organic Chemistry: Structure and Function
Ch. 5.1 - Prob. 5.3ECh. 5.1 - Prob. 5.4ECh. 5.1 - Prob. 5.5ECh. 5.2 - Prob. 5.6ECh. 5.2 - Prob. 5.8TIYCh. 5.3 - Prob. 5.9ECh. 5.3 - Prob. 5.11TIYCh. 5.3 - Prob. 5.12ECh. 5.4 - Prob. 5.13ECh. 5.4 - Prob. 5.14E
Ch. 5.4 - Prob. 5.16TIYCh. 5.4 - Prob. 5.17ECh. 5.5 - Prob. 5.18ECh. 5.5 - Prob. 5.19ECh. 5.5 - Prob. 5.20ECh. 5.6 - Prob. 5.21ECh. 5.6 - Prob. 5.22ECh. 5.6 - Prob. 5.23ECh. 5.7 - Prob. 5.24ECh. 5.7 - Prob. 5.26TIYCh. 5.7 - Prob. 5.27ECh. 5 - Prob. 5.1ECh. 5 - Prob. 5.2ECh. 5 - Prob. 30PCh. 5 - Prob. 31PCh. 5 - Prob. 32PCh. 5 - Prob. 33PCh. 5 - Prob. 34PCh. 5 - Prob. 35PCh. 5 - Prob. 36PCh. 5 - Prob. 37PCh. 5 - Prob. 38PCh. 5 - Prob. 39PCh. 5 - Prob. 40PCh. 5 - Prob. 41PCh. 5 - Prob. 42PCh. 5 - Prob. 43PCh. 5 - Prob. 44PCh. 5 - Prob. 45PCh. 5 - Prob. 46PCh. 5 - Prob. 47PCh. 5 - Prob. 48PCh. 5 - Prob. 49PCh. 5 - Prob. 50PCh. 5 - Prob. 51PCh. 5 - Prob. 52PCh. 5 - Prob. 53PCh. 5 - Prob. 54PCh. 5 - Prob. 55PCh. 5 - Prob. 56PCh. 5 - Prob. 57PCh. 5 - Prob. 58PCh. 5 - Prob. 59PCh. 5 - Prob. 60PCh. 5 - Prob. 61PCh. 5 - Prob. 62PCh. 5 - Prob. 63PCh. 5 - Prob. 64PCh. 5 - Prob. 65PCh. 5 - Prob. 66PCh. 5 - Prob. 67PCh. 5 - Prob. 68PCh. 5 - Prob. 69PCh. 5 - Prob. 70PCh. 5 - Prob. 71P
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