An Introduction to Thermal Physics
1st Edition
ISBN: 9780201380279
Author: Daniel V. Schroeder
Publisher: Addison Wesley
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Chapter 5.3, Problem 37P
To determine
The variation of phase diagram of Calcium Carbonate.
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Recall Problem 1.34, which concerned an ideal diatomic gas taken around a rectangular cycle on a PV diagram. Suppose now that this system is used as a heat engine, to convert the heat added into mechanical work. (a) Evaluate the efficiency of this engine for the case V2 = 3V1 , P2 = 2P1. (b) Calculate the efficiency of an "ideal" engine operating between the same temperature extremes.
Problem 4.1. Recall Problem 1.34, which concerned an ideal diatomic gas taken around a rectangular cycle on a PV diagram. Suppose now that this system is used as a heat engine, to convert the heat added into mechanical work. (a) Evaluate the efficiency of this engine for the case V2 = 3V1, P2 = 2P1. (b) Calculate the efficiency of an "ideal" engine operating between the same temperature extremes.
(b) Consider the following heat system on the real line:
U - U = 0, XER, 1>0
%3D
u(x, 0) = | sin x), rER.
i. Use the fundamental solution of the heat equation to write down a solution u to
the system above as an integral.
ii. Show that the solution u that you have found is bounded by 1.
Chapter 5 Solutions
An Introduction to Thermal Physics
Ch. 5.1 - Prob. 1PCh. 5.1 - Consider the production of ammonia from nitrogen...Ch. 5.1 - Prob. 3PCh. 5.1 - Prob. 4PCh. 5.1 - Consider a fuel cell that uses methane (natural...Ch. 5.1 - Prob. 6PCh. 5.1 - The metabolism of a glucose molecule (see previous...Ch. 5.1 - Derive the thermodynamic identity for G (equation...Ch. 5.1 - Sketch a qualitatively accurate graph of G vs. T...Ch. 5.1 - Suppose you have a mole of water at 25C and...
Ch. 5.1 - Suppose that a hydrogen fuel cell, as described in...Ch. 5.1 - Prob. 12PCh. 5.1 - Prob. 13PCh. 5.1 - Prob. 14PCh. 5.1 - Prob. 15PCh. 5.1 - Prob. 16PCh. 5.1 - Prob. 17PCh. 5.2 - Prob. 18PCh. 5.2 - In the previous section 1 derived the formula...Ch. 5.2 - Prob. 20PCh. 5.2 - Is heat capacity (C) extensive or intensive? What...Ch. 5.2 - Prob. 22PCh. 5.2 - Prob. 23PCh. 5.3 - Go through the arithmetic to verify that diamond...Ch. 5.3 - Prob. 25PCh. 5.3 - How can diamond ever be more stable than graphite,...Ch. 5.3 - Prob. 27PCh. 5.3 - Calcium carbonate, CaCO3, has two common...Ch. 5.3 - Aluminum silicate, Al2SiO5, has three different...Ch. 5.3 - Sketch qualitatively accurate graphs of G vs. T...Ch. 5.3 - Sketch qualitatively accurate graphs of G vs. P...Ch. 5.3 - The density of ice is 917kg/m3. (a) Use the...Ch. 5.3 - An inventor proposes to make a heat engine using...Ch. 5.3 - Below 0.3 K the Slope of the 3He solid–liquid...Ch. 5.3 - Prob. 35PCh. 5.3 - Effect of altitude on boiling water. (a) Use the...Ch. 5.3 - Prob. 37PCh. 5.3 - Prob. 38PCh. 5.3 - Prob. 39PCh. 5.3 - The methods of this section can also be applied to...Ch. 5.3 - Suppose you have a liquid (say, water) in...Ch. 5.3 - Ordinarily, the partial pressure of water vapor in...Ch. 5.3 - Assume that the air you exhale is at 35C, with a...Ch. 5.3 - Prob. 44PCh. 5.3 - Prob. 46PCh. 5.3 - Prob. 47PCh. 5.3 - Prob. 48PCh. 5.3 - Prob. 49PCh. 5.3 - The compression factor of a fluid is defined as...Ch. 5.3 - Prob. 51PCh. 5.3 - Prob. 52PCh. 5.3 - Repeat the preceding problem for T/Tc=0.8.Ch. 5.3 - Prob. 54PCh. 5.3 - Prob. 55PCh. 5.4 - Prove that the entropy of mixing of an ideal...Ch. 5.4 - In this problem you will model the mixing energy...Ch. 5.4 - Suppose you cool a mixture of 50% nitrogen and 50%...Ch. 5.4 - Suppose you start with a liquid mixture of 60%...Ch. 5.4 - Suppose you need a tank of oxygen that is 95%...Ch. 5.4 - Prob. 62PCh. 5.4 - Everything in this section assumes that the total...Ch. 5.4 - Figure 5.32 shows the phase diagram of plagioclase...Ch. 5.4 - Prob. 65PCh. 5.4 - Prob. 66PCh. 5.4 - Prob. 67PCh. 5.4 - Plumbers solder is composed of 67% lead and 33%...Ch. 5.4 - What happens when you spread salt crystals over an...Ch. 5.4 - What happens when you add salt to the ice bath in...Ch. 5.4 - Figure 5.35 (left) shows the free energy curves at...Ch. 5.4 - Repeat the previous problem for the diagram in...Ch. 5.5 - If expression 5.68 is correct, it must be...Ch. 5.5 - Prob. 74PCh. 5.5 - Compare expression 5.68 for the Gibbs free energy...Ch. 5.5 - Seawater has a salinity of 3.5%, meaning that if...Ch. 5.5 - Osmotic pressure measurements can be used to...Ch. 5.5 - Because osmotic pressures can be quite large, you...Ch. 5.5 - Most pasta recipes instruct you to add a teaspoon...Ch. 5.5 - Use the Clausius–Clapeyron relation to derive...Ch. 5.5 - Prob. 81PCh. 5.5 - Use the result of the previous problem to...Ch. 5.6 - Prob. 83PCh. 5.6 - Prob. 84PCh. 5.6 - Prob. 85PCh. 5.6 - Prob. 86PCh. 5.6 - Sulfuric acid, H2SO4, readily dissociates into H+...Ch. 5.6 - Prob. 88PCh. 5.6 - Prob. 89PCh. 5.6 - When solid quartz dissolves in water, it combines...Ch. 5.6 - When carbon dioxide dissolves in water,...Ch. 5.6 - Prob. 92P
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- Show complete solution, please. 3. A sphere of radius 0.500 m, temperature 27.0^oC, and emissivity 0.850 is located in an environment of temperature 77.0^oC. At what rate does the sphere (a) emit and (b) absorb thermal radiation? (c) What is the sphere’s net rate of energy exchange?arrow_forwardProblem 1.14. Calculate the mass of a mole of dry air, which is a mixture of N2 (78% by volume), 02 (21%), and argon (1%). 2. Construct a mental "model" of a container full gas to describe how, exactly, is temperature related to energy? Use the Macroscopic Model of an Ideal Gas. Precisely, you want to know how the temperature of a gas is related to the kinetic energy of the molecules it contains.arrow_forwardStatical Mechanics (Thermal and Statical Physics) Instruction: Write ALL the solutions of this (necessary or and not direct answer). Write also the equations that are needed to solve for a certain problem. Thank you. Problem: Now, we have the number of microstates and in between E and E + ∆E in isolated system of N particles in the volume V is given by: (Please see the image attached) Where a,b, c are constants. Note: Answer also letter A-Darrow_forward
- 1.1 A quantity of ideal monatomic gas consists of n molecules initially at temperature Ta. The pressure and volume are then slowly doubled in such a manner as to trace out a straight line on a p-V diagram. (a) In terms of n, R, and Ta, calculate: The work W (i) The internal energy AU (b) What would be the value of the molar specific heat for this process?arrow_forwardHi, could I get some help with this macro-connection physics problem involving the Ideal Gas Law? The set up is: What is the average volume in nm3 (cubic nanometers) taken up by molecules of an ideal gas at room temperature (taken as 300 K), and 1 atm of pressure or 101325 N/m2 to 4 digits of precision if kB = 1.38e-23 J/K and 1 nm = 10-9 m? Thank you.arrow_forwardProblem 1.24. Calculate the total thermal energy in a gram of lead at room temperature, assuming that none of the degrees of freedom are "frozen out" (this happens to be a good assumption in this case).arrow_forward
- Problem 1.33. An ideal gas is made to undergo the cyclic process shown in Figure 1.10(a). For each of the steps A, B, and C, determine whether each of the following is positive, nogative, or zero: (a) the work done on the gas; (b) the change in the energy content of the gas: (c) the heat added to the gas. Then determine the sign of each of these three quantities for the whole cycle. What does this process accomplish? (a) A (b) B Pa B A A D Volume V1 V Volume Figure 1.10. PV diagrams for Problems 1.33 and 1.34. steps; for example, during step A, heat is added to the gas (from an external flame or something) while the piston is held fixed. (c) Compute the net work done on the gas, the net heat added to the gas, and the net change in the energy of the gas during the entire cycle. Are the results as you expected? Explain briefly. Show that knowing the initial condition of a compressed system consisting of a gas you can derive its final temperature. Pressure Pressurearrow_forwardProve that the Cv of an ideal gas does not depend upon specific volume by showing that: ( SCv/ SV )=T( S2P/ ST2)V. (show the mathematical derivation)NOTE: The S btw is delta S (see picture attach) I can't copy the symbol.arrow_forward1 cal = 4.184 J, specific heat of iron = 0.45 J/g°C 1. If 2087.5 kcal of chemical energy is converted to mechanical energy and then electrical energy, how many kcal and joules of electrical energy is available? Explain. 2. a) Define the term, state function. ( one of the wo assmptions made for this model, (6 (amiog o) sbam od anoizulonoo ntw bas bovoado o Jominoqo brohadut eom3 sdinoesC b) Give THREE examples of state functions. (arrow_forward
- Using MATLAB editor, make a script m-file which includes a header block and comments: Utilizing the ideal gas law: Vmol= RT/P Calculate the molecular volume where: R = 0.08206 L-atm/(mol-K) P = 1.015 atm. and T = 270 - 315 K in 5 degree increments Make a display matrix which has the values of T in the first column and Vmol in the second column Save the script and publish function to create a pdf file from the script in a file named "ECE105_Wk2_L1_Prep_1"arrow_forwardPROBLEMS 1.1. In the table below, a number in the top row represents the pressure of a gas in the bulb of a constant-volume gas thermometer (corrected for dead space, thermal expansion of bulb, etc.) when the bulb is immersed in a water triple-point cell. The bottom row represents the corresponding readings of pressure when the bulb is surrounded by a material at a constant unknown temperature. Calculate the ideal- gas temperature T of this material. (Use five significant figures.) PTP, kPa P, kPa 133.32 99.992 33.331 66.661 102.37 204.69 153.54 51.190arrow_forwarde. Consider one unit cell and assume the length of the side of the cube is “a”. Remember that “a” is the distance between the centers of two adjacent atoms. How long is “a”, the edge of a unit cell, in terms of radius, r, of an atom? Write also your answer in the summary table.Answer: __________f. Based on the earlier questions, a simple cubic cell has the equivalent of only 1 atom. Recall the volume of sphere with radius, r, is expressed as V = 4/3 πr3. With this information, find the total volume of all the spheres in this unit cell, expressed in terms of r. (Hint: To do this, take the total number of atoms and multiply it by the volume of one atom, with radius, r)Answer: __________arrow_forward
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