Organic Chemistry: Principles and Mechanisms (Second Edition)
Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
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Chapter 3, Problem 3.6YT
Interpretation Introduction

Interpretation:

To label each orbital in figure 3-11c as sp2, px, py, or pz.

Concept introduction:

The sp2 hybridized orbitals are formed by mixing of one S and two p orbitals and resemble the p orbitals more. Constructive and destructive interferences form three sp2 orbitals, which are identical in shape but differ in their orientation.

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For each of the statements below, indicate whether it is true or false and explain your reasoning. (1 sentence ) 1/ It takes more energy to ionize an electron from the 2s orbital than an electron from the 2p orbital in the Li2+ ion. 2/ The electron affinity of the Ne atom is larger than the electron affinity of the F atom. 3/ K* has a larger radius than Ar. 4/ For a diatomic molecule, in which the internuclear axis is the z-axis, the 3dz? orbital cannot mix with the 2px orbital. 5/ The internuclear distance of O2 increases as it takes an additional electron to become O2".
Rank the effective nuclear charge Z experienced by a valence electron in each of these atoms: atom Z* experienced by a valence electron. An atom of beryllium. |(pick one) ♥ An atom of lithium. (pick one) ♥ An atom of carbon. (pick one) v An atom of boron. (pick one)
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