Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
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Question
Chapter 3, Problem 3.9P
Interpretation Introduction
Interpretation:
The hybridization of the N atom in the given molecule is to be determined.
Concept introduction:
Atomic orbitals mix and form an equal number of hybrid orbitals. The number of hybrid orbitals required by an atom in a molecule or an ion is equal to the number of electron groups in its valence shell. In case of atoms from the second row, like carbon, these are formed by mixing of one s AO and the necessary number of p AO(s).
An electron group is a lone pair or a bond. The bond, whether single, double, or triple, counts as just one electron group.
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Chapter 3 Solutions
Organic Chemistry: Principles and Mechanisms (Second Edition)
Ch. 3 - Prob. 3.1PCh. 3 - Prob. 3.2PCh. 3 - Prob. 3.3PCh. 3 - Prob. 3.4PCh. 3 - Prob. 3.5PCh. 3 - Prob. 3.6PCh. 3 - Prob. 3.7PCh. 3 - Prob. 3.8PCh. 3 - Prob. 3.9PCh. 3 - Prob. 3.10P
Ch. 3 - Prob. 3.11PCh. 3 - Prob. 3.12PCh. 3 - Prob. 3.13PCh. 3 - Prob. 3.14PCh. 3 - Prob. 3.15PCh. 3 - Prob. 3.16PCh. 3 - Prob. 3.17PCh. 3 - Prob. 3.18PCh. 3 - Prob. 3.19PCh. 3 - Prob. 3.20PCh. 3 - Prob. 3.21PCh. 3 - Prob. 3.22PCh. 3 - Prob. 3.23PCh. 3 - Prob. 3.24PCh. 3 - Prob. 3.25PCh. 3 - Prob. 3.26PCh. 3 - Prob. 3.27PCh. 3 - Prob. 3.28PCh. 3 - Prob. 3.29PCh. 3 - Prob. 3.30PCh. 3 - Prob. 3.31PCh. 3 - Prob. 3.32PCh. 3 - Prob. 3.33PCh. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Prob. 3.36PCh. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Prob. 3.39PCh. 3 - Prob. 3.40PCh. 3 - Prob. 3.41PCh. 3 - Prob. 3.42PCh. 3 - Prob. 3.43PCh. 3 - Prob. 3.44PCh. 3 - Prob. 3.45PCh. 3 - Prob. 3.46PCh. 3 - Prob. 3.47PCh. 3 - Prob. 3.48PCh. 3 - Prob. 3.49PCh. 3 - Prob. 3.50PCh. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - Prob. 3.53PCh. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - Prob. 3.56PCh. 3 - Prob. 3.1YTCh. 3 - Prob. 3.2YTCh. 3 - Prob. 3.3YTCh. 3 - Prob. 3.4YTCh. 3 - Prob. 3.5YTCh. 3 - Prob. 3.6YTCh. 3 - Prob. 3.7YTCh. 3 - Prob. 3.8YTCh. 3 - Prob. 3.9YTCh. 3 - Prob. 3.10YTCh. 3 - Prob. 3.11YTCh. 3 - Prob. 3.12YTCh. 3 - Prob. 3.13YT
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- Orbital representation of the molecule in the image.arrow_forwardMatch the given molecular formula with the expected hybridization about the central atom.arrow_forwardProblem Which of the following substances exhibits H bonding? For any that do, show the H bonds between two of its molecules. (a) C̟H, (b) CH;OH (c) CH3C–NH,arrow_forward
- In each of the following equations, what hybridization change, if any, occurs for the underlined atom?arrow_forward4. ,A: Briefly describe why the p orbital can contain a positive charge and hybridized orbital cannot. Use pictures in your answer. B: Briefly explain why a hybridized orbital can contain a negative charge, and P-orbital cannot. Use pictures in your answer.arrow_forwardDetermining Hybridization in a Conjugated System Determine the hybridization around the labeled carbon atom in the following anion.arrow_forward
- To preview the image Click Here t A) For the indicated Carbon atom, give its hybridization and a list of all hybridized and unhybridized atomic orbitals and how each orbital is used for this atom. B) REDRAW the structure on your paper. Directly ON TOP of the structure, draw pictorial representation of the T for the localized bonding molecular orbitals for the bond that is indicated in the following structure. State the atomic orbitals that are used to build the molecular orbitals. Part B CEC-H Part A pointing to this carbonarrow_forwardDetermine the geometry of each molecule using your chart above. Recall that electron domains are determined as follows:arrow_forwardThe instructions are to draw the resonance hybrid structure of the molecule on the left. My answer is circled , which is wrong. Can someone explain why?arrow_forward
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