Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
expand_more
expand_more
format_list_bulleted
Question
Chapter 3, Problem 3.47P
Interpretation Introduction
Interpretation:
Does cyclooctene have two distinct configurations about its C=C bond is to be explained.
Concept introduction:
Double bonds in cycloalkenes of seven or fewer carbons are exclusively cis as the trans isomers are too strained at ordinary condition. Cycloalkene ring with more than seven carbons is large enough to have both configurations.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
5a) Construct a model of butene, C4H8, using two carbon atoms with planar geometry and two carbon atoms
with tetrahedral geometry. How many other isomers of C₂H, can you construct? Draw a dash structural
representation of each structure.
5b) How many bonds in butene enjoy free rotation?
Is there much flexibility in the structure of benzene or can you assign a definite shape to the entire molecule? Compare the shape to that of cyclohexane.
1. Although there is only one alkene with the
formula C2H4 (ethene) and only one with the
formula C3H6 (propene), there are several
alkenes with the formula C4H8. Draw all of the
possible bond line structures for alkenes with
the formula C4H3 including all possible
structural and stereoisomers.
Chapter 3 Solutions
Organic Chemistry: Principles and Mechanisms (Second Edition)
Ch. 3 - Prob. 3.1PCh. 3 - Prob. 3.2PCh. 3 - Prob. 3.3PCh. 3 - Prob. 3.4PCh. 3 - Prob. 3.5PCh. 3 - Prob. 3.6PCh. 3 - Prob. 3.7PCh. 3 - Prob. 3.8PCh. 3 - Prob. 3.9PCh. 3 - Prob. 3.10P
Ch. 3 - Prob. 3.11PCh. 3 - Prob. 3.12PCh. 3 - Prob. 3.13PCh. 3 - Prob. 3.14PCh. 3 - Prob. 3.15PCh. 3 - Prob. 3.16PCh. 3 - Prob. 3.17PCh. 3 - Prob. 3.18PCh. 3 - Prob. 3.19PCh. 3 - Prob. 3.20PCh. 3 - Prob. 3.21PCh. 3 - Prob. 3.22PCh. 3 - Prob. 3.23PCh. 3 - Prob. 3.24PCh. 3 - Prob. 3.25PCh. 3 - Prob. 3.26PCh. 3 - Prob. 3.27PCh. 3 - Prob. 3.28PCh. 3 - Prob. 3.29PCh. 3 - Prob. 3.30PCh. 3 - Prob. 3.31PCh. 3 - Prob. 3.32PCh. 3 - Prob. 3.33PCh. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Prob. 3.36PCh. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Prob. 3.39PCh. 3 - Prob. 3.40PCh. 3 - Prob. 3.41PCh. 3 - Prob. 3.42PCh. 3 - Prob. 3.43PCh. 3 - Prob. 3.44PCh. 3 - Prob. 3.45PCh. 3 - Prob. 3.46PCh. 3 - Prob. 3.47PCh. 3 - Prob. 3.48PCh. 3 - Prob. 3.49PCh. 3 - Prob. 3.50PCh. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - Prob. 3.53PCh. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - Prob. 3.56PCh. 3 - Prob. 3.1YTCh. 3 - Prob. 3.2YTCh. 3 - Prob. 3.3YTCh. 3 - Prob. 3.4YTCh. 3 - Prob. 3.5YTCh. 3 - Prob. 3.6YTCh. 3 - Prob. 3.7YTCh. 3 - Prob. 3.8YTCh. 3 - Prob. 3.9YTCh. 3 - Prob. 3.10YTCh. 3 - Prob. 3.11YTCh. 3 - Prob. 3.12YTCh. 3 - Prob. 3.13YT
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- b) Rank by number of C-C bonds that can freely rotate. Use a "1" for the highest number of freely rotatable bonds, followed by a "2", then a "3" for the lowest number.arrow_forwardDraw the bond-line formula for each of the following condensed structural formulas.These may go beyond the simple explanations above but you can imply the connectivity based on the atoms’ desired valence. a)(CH3)3CCH2CH3 b)(CH3)2CHOH c)(CH3)2CHOHarrow_forwardDraw a skeletal structure for the following molecule. (CH3)2C═CH(CH2)4CH3arrow_forward
- Which is more stable, cis–1,4-dimethylcyclohexane or the trans isomer? Draw the structure of the more stable isomer. Your structure should clearly distinguish between all axial and equatorial positions.arrow_forward5) Provide your own list of alkanes. They can not be the same structure but should all have the same number of carbons. (see the problem solving video for an example) Rank them in order of increasing melting point. You can not have the same example as someone else.arrow_forward1. Does chlorophyll a or chlorophyll b have a greater number of “conjugated” double bonds, or do they have the same number? Draw the structure of chlorophyll b and using a colored highlighter, indicate which of the double bonds are “conjugated”. 2. What is the main functional group in THF (tetrahydrofuran)? Is THF more polar or less polar than IPA (also called: isopropyl alcohol, isopropanol, or 2-propanol)? 3.If you mistakenly used hexanes-THF (2:1) for eluting the carotene pigments from your chromatography column, will they elute faster or slower than if you had correctly used hexanes-THF (10:1)? Explainarrow_forward
- Draw the cis isomer of the structure shown below. D • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • In cases where there is more than one answer, just draw one. If the structure does not have cis/trans isomers, simply redraw the molecule without stereobonds.arrow_forwardFatty acids are molecules with a carboxylic acid on one end and long hydrocarbon chain on the other. The sodium salts of fatty acids (such as sodium strearate, shown below) are commonly used in soaps to trap nonpolar dirt and grease particles. Soap does not work well in "hard water, which is water with high concentration of magensium and calcium ions (often found in water obtained from wells) Explain this observation at a molecular level.arrow_forwardSketch a plausible Molecular Orbital diagram for trimethylenemethane. H₂ċ H₂C C=CH2arrow_forward
- Choose the condensed structure for the following line structure. CH3C(CH3)2CH₂O(CH2)4CH3 CH3CH₂C(CH3)2CHO(CH₂)4CH3 CH3CH₂C(CH3)2CH₂O(CH₂)4CH3 CH,CH CH(CH,)CH,O(CH,),CH; CH3CH₂C(CH3)2CH₂OCH(CH2)3CH3arrow_forwardWhich is most stable, cis-1,4-dimethylhexane, or the trans isomoer? Draw the structure of the more stable isomer (your structure should clearly distinguish between all axial and equatorial positions.)arrow_forwardLine-bond structures appear to imply that there are two different isomers of 1,2-dibromobenzene, one with the bromine-bearing carbon atoms joined by a double bond and one with the bromine-bearing carbons joined by a single bond. In fact, though, there is only one 1,2-dibromobenzene. Explain. H H. C. Br H. .C. Br || || .C and 1,2-Dibromobenzene Br Brarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Linear Combination of Atomic Orbitals LCAO; Author: Edmerls;https://www.youtube.com/watch?v=nq1zwrAIr4c;License: Standard YouTube License, CC-BY
Quantum Molecular Orbital Theory (PChem Lecture: LCAO and gerade ungerade orbitals); Author: Prof Melko;https://www.youtube.com/watch?v=l59CGEstSGU;License: Standard YouTube License, CC-BY