(a) Interpretation: The bonding and antibonding MOs that would result from the end-on overlap of chlorine AOs in the Cl 2 molecule are to be drawn. Concept introduction: Overlap of orbitals will result in a bonding MO if their phases in the overlapping parts are the same. In this case, the electron density increases between the nuclei of the two atoms. The overlap will result in an antibonding MO if their phases are opposite in the overlapping parts. In this case, the electron density between the nuclei of the atoms reduces.

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Answer 1

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Chapter 3, Problem 3.31P

Interpretation Introduction

(a)

Interpretation:

The bonding and antibonding MOs that would result from the end-on overlap of chlorine AOs in the Cl2 molecule are to be drawn.

Concept introduction:

Overlap of orbitals will result in a bonding MO if their phases in the overlapping parts are the same. In this case, the electron density increases between the nuclei of the two atoms.

The overlap will result in an antibonding MO if their phases are opposite in the overlapping parts. In this case, the electron density between the nuclei of the atoms reduces.

Interpretation Introduction

(b)

Interpretation:

The symmetry of the MOs resulting from the overlap of AOs in the Cl2 molecule is to be determined.

Concept introduction:

Symmetry of an MO depends on whether the overlap is end-on- or sideways. End-on overlap is called σ (sigma) symmetry, and sideways overlap is called π (pi) symmetry.

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The bond in Cl2 can be explained by the end-on overlap between two p AOs, as shown inthis diagram. (a) Draw the bonding and antibonding MOs that would result from such an interaction. (b) What is the symmetry of each of these MOs?

The following are three T MOs of octa-1,3,5,7-tetraene. Repeat Problem 14.26 for these orbitals. E F

3. (a) Based on the compound, deca-1,3,5,7,9-pentaene: (1) Give the total number of TT molecular orbitals (MOS) present. (ii) Give the total number of bonding MOs present. (ii) Give the total number of antibonding MOs present. (iv) Give the number of node(s) present in u. (v) Give the number of node(s) present in yto".

Answer 2

Question

Chapter 3, Problem 3.31P

Interpretation Introduction

(a)

Interpretation:

The bonding and antibonding MOs that would result from the end-on overlap of chlorine AOs in the Cl2 molecule are to be drawn.

Concept introduction:

Overlap of orbitals will result in a bonding MO if their phases in the overlapping parts are the same. In this case, the electron density increases between the nuclei of the two atoms.

The overlap will result in an antibonding MO if their phases are opposite in the overlapping parts. In this case, the electron density between the nuclei of the atoms reduces.

Interpretation Introduction

(b)

Interpretation:

The symmetry of the MOs resulting from the overlap of AOs in the Cl2 molecule is to be determined.

Concept introduction:

Symmetry of an MO depends on whether the overlap is end-on- or sideways. End-on overlap is called σ (sigma) symmetry, and sideways overlap is called π (pi) symmetry.

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Answer 3

Question

Chapter 3, Problem 3.31P

Interpretation Introduction

(a)

Interpretation:

The bonding and antibonding MOs that would result from the end-on overlap of chlorine AOs in the Cl2 molecule are to be drawn.

Concept introduction:

Overlap of orbitals will result in a bonding MO if their phases in the overlapping parts are the same. In this case, the electron density increases between the nuclei of the two atoms.

The overlap will result in an antibonding MO if their phases are opposite in the overlapping parts. In this case, the electron density between the nuclei of the atoms reduces.

Interpretation Introduction

(b)

Interpretation:

The symmetry of the MOs resulting from the overlap of AOs in the Cl2 molecule is to be determined.

Concept introduction:

Symmetry of an MO depends on whether the overlap is end-on- or sideways. End-on overlap is called σ (sigma) symmetry, and sideways overlap is called π (pi) symmetry.

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Answer 4

Question

Chapter 3, Problem 3.31P

Interpretation Introduction

(a)

Interpretation:

The bonding and antibonding MOs that would result from the end-on overlap of chlorine AOs in the Cl2 molecule are to be drawn.

Concept introduction:

Overlap of orbitals will result in a bonding MO if their phases in the overlapping parts are the same. In this case, the electron density increases between the nuclei of the two atoms.

The overlap will result in an antibonding MO if their phases are opposite in the overlapping parts. In this case, the electron density between the nuclei of the atoms reduces.

Interpretation Introduction

(b)

Interpretation:

The symmetry of the MOs resulting from the overlap of AOs in the Cl2 molecule is to be determined.

Concept introduction:

Symmetry of an MO depends on whether the overlap is end-on- or sideways. End-on overlap is called σ (sigma) symmetry, and sideways overlap is called π (pi) symmetry.

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Answer 5

Chapter 3, Problem 3.31P

Interpretation Introduction

(a)

Interpretation:

The bonding and antibonding MOs that would result from the end-on overlap of chlorine AOs in the Cl2 molecule are to be drawn.

Concept introduction:

Overlap of orbitals will result in a bonding MO if their phases in the overlapping parts are the same. In this case, the electron density increases between the nuclei of the two atoms.

The overlap will result in an antibonding MO if their phases are opposite in the overlapping parts. In this case, the electron density between the nuclei of the atoms reduces.

Interpretation Introduction

(b)

Interpretation:

The symmetry of the MOs resulting from the overlap of AOs in the Cl2 molecule is to be determined.

Concept introduction:

Symmetry of an MO depends on whether the overlap is end-on- or sideways. End-on overlap is called σ (sigma) symmetry, and sideways overlap is called π (pi) symmetry.

Answer 6

Chapter 3, Problem 3.31P

Interpretation Introduction

(a)

Interpretation:

The bonding and antibonding MOs that would result from the end-on overlap of chlorine AOs in the Cl2 molecule are to be drawn.

Concept introduction:

Overlap of orbitals will result in a bonding MO if their phases in the overlapping parts are the same. In this case, the electron density increases between the nuclei of the two atoms.

The overlap will result in an antibonding MO if their phases are opposite in the overlapping parts. In this case, the electron density between the nuclei of the atoms reduces.

Answer 7

Chapter 3, Problem 3.31P

Interpretation Introduction

(a)

Interpretation:

The bonding and antibonding MOs that would result from the end-on overlap of chlorine AOs in the Cl2 molecule are to be drawn.

Concept introduction:

Overlap of orbitals will result in a bonding MO if their phases in the overlapping parts are the same. In this case, the electron density increases between the nuclei of the two atoms.

The overlap will result in an antibonding MO if their phases are opposite in the overlapping parts. In this case, the electron density between the nuclei of the atoms reduces.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The symmetry of the MOs resulting from the overlap of AOs in the Cl2 molecule is to be determined.

Concept introduction:

Symmetry of an MO depends on whether the overlap is end-on- or sideways. End-on overlap is called σ (sigma) symmetry, and sideways overlap is called π (pi) symmetry.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The symmetry of the MOs resulting from the overlap of AOs in the Cl2 molecule is to be determined.

Concept introduction:

Symmetry of an MO depends on whether the overlap is end-on- or sideways. End-on overlap is called σ (sigma) symmetry, and sideways overlap is called π (pi) symmetry.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 3 - Prob. 3.1P Ch. 3 - Prob. 3.2P Ch. 3 - Prob. 3.3P Ch. 3 - Prob. 3.4P Ch. 3 - Prob. 3.5P Ch. 3 - Prob. 3.6P Ch. 3 - Prob. 3.7P Ch. 3 - Prob. 3.8P Ch. 3 - Prob. 3.9P Ch. 3 - Prob. 3.10P

Solution Summary: The author explains that the symmetry of an MO depends on whether the overlap is end-on- or sideways.

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