Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 3, Problem 3.11YT
Interpretation Introduction
Interpretation:
A molecular modeling kit is to be constructed for the given two molecules, and it is to be tried to line one up with the other. Further, it is to be explained whether the two given molecules are the same or different.
Concept introduction:
A double bond will not have two distinct configurations if one carbon of the double bond possesses two identical atoms or groups. Therefore, for cis-trans configuration, the molecule must possess two different groups or atoms on the same carbon of the double bond.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Check the box next to each molecule on the right that has the shape of the model molecule on the left:
molecules
model
(check all that apply)
O HNO
O H,0
O H,S
O HOCI
You can drag the slide
None of the above
Note for advanced students: the length of bonds and size of atoms in the model is not necessarily realistic. The model is only
geometry and 3D shape of the molecule.
Check the box next to each molecule on the right that has the shape of the model molecule on the left:
molecules
model
(check all that apply)
O H,0
O H,S
You can drag the slider to rotate the model molecule.
O HNO
О НОСІ
O None of the above
Note for advanced students: the length of bonds and size of atoms in the model is not necessarily realistic. The model is only meant to show you the general
geometry and 3D shape of the molecule.
Focus on the C atom on the left as the central atom. How many other atoms are directly bonded to this C atom?
How many bonding domains are there on the C atom on the left?
How many lone pairs of electrons are there on the C atom on the left?
How many nonbonding domains are there on the C atom on the left?
Chapter 3 Solutions
Organic Chemistry: Principles and Mechanisms (Second Edition)
Ch. 3 - Prob. 3.1PCh. 3 - Prob. 3.2PCh. 3 - Prob. 3.3PCh. 3 - Prob. 3.4PCh. 3 - Prob. 3.5PCh. 3 - Prob. 3.6PCh. 3 - Prob. 3.7PCh. 3 - Prob. 3.8PCh. 3 - Prob. 3.9PCh. 3 - Prob. 3.10P
Ch. 3 - Prob. 3.11PCh. 3 - Prob. 3.12PCh. 3 - Prob. 3.13PCh. 3 - Prob. 3.14PCh. 3 - Prob. 3.15PCh. 3 - Prob. 3.16PCh. 3 - Prob. 3.17PCh. 3 - Prob. 3.18PCh. 3 - Prob. 3.19PCh. 3 - Prob. 3.20PCh. 3 - Prob. 3.21PCh. 3 - Prob. 3.22PCh. 3 - Prob. 3.23PCh. 3 - Prob. 3.24PCh. 3 - Prob. 3.25PCh. 3 - Prob. 3.26PCh. 3 - Prob. 3.27PCh. 3 - Prob. 3.28PCh. 3 - Prob. 3.29PCh. 3 - Prob. 3.30PCh. 3 - Prob. 3.31PCh. 3 - Prob. 3.32PCh. 3 - Prob. 3.33PCh. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Prob. 3.36PCh. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Prob. 3.39PCh. 3 - Prob. 3.40PCh. 3 - Prob. 3.41PCh. 3 - Prob. 3.42PCh. 3 - Prob. 3.43PCh. 3 - Prob. 3.44PCh. 3 - Prob. 3.45PCh. 3 - Prob. 3.46PCh. 3 - Prob. 3.47PCh. 3 - Prob. 3.48PCh. 3 - Prob. 3.49PCh. 3 - Prob. 3.50PCh. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - Prob. 3.53PCh. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - Prob. 3.56PCh. 3 - Prob. 3.1YTCh. 3 - Prob. 3.2YTCh. 3 - Prob. 3.3YTCh. 3 - Prob. 3.4YTCh. 3 - Prob. 3.5YTCh. 3 - Prob. 3.6YTCh. 3 - Prob. 3.7YTCh. 3 - Prob. 3.8YTCh. 3 - Prob. 3.9YTCh. 3 - Prob. 3.10YTCh. 3 - Prob. 3.11YTCh. 3 - Prob. 3.12YTCh. 3 - Prob. 3.13YT
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- A student draws the picture of ammonia (NH3) in the box below, left, and predicts it will be a flatmolecule with HNH bond angles of exactly 120°. Unfortunately, the student left something out. a. What did the student omit from his drawing? b. What is the actual HNH bond angle of ammonia (based on the draw g above, right)? c. Explain why water, ammonia, and methane (shown below) all have about the same bondangles (close to 109.5°) even though they have different numbers of bonds.arrow_forwardCheck the box next to each molecule on the right that has the shape of the model molecule on the left: molecules model (check all that apply) olo O C,H, О НОСІ You can drag the slider to rotate the model molecule. O CO, O N,H, O None of the above Note for advanced students: the length of bonds and size of atoms in the model is not necessarily realistic. The model is only meant to show you the general geometry and 3D shape of the molecule.arrow_forwardButane is an unbranched alkane with the molecular formula C4H10C4H10. a) Draw the complete structure of butane. (Show all hydrogen atoms.) b) Draw the structure of butane in line-bond or skeleton mode. (Do not show the hydrogen atoms.)arrow_forward
- Select ALL of the following that can be used to explain the polarities of NO2 and SeCl42- (these molecules are mentioned in earlier questions). NO2 has a permanent dipole moment or a net dipole moment greater than zero whereas SeCl42- has no net or zero dipole moment. Both molecules are symmetrical and hence nonpolar Due to their respective shapes, in NO2 the bond dipole moments reinforce each other whereas in SeCl42- they cancel out each other. NO2 has no net dipole moment and SeCl42- has a net dipole moment greater than zero. NO2 is an unsymmetrical molecule whereas SeCl42- is a symmetrical ion.arrow_forwardCheck the box next to each molecule on the right that has the shape of the model molecule on the left: molecules model (check all that apply) O CH,Cl, O CH,CI O CF4 You can drag the O BrF4 O None of the above Note for advanced students: the length of bonds and size of atoms in the model is not necessarily realistic. The model geometry and 3D shape of the molecule. toarrow_forwardCheck the box next to each molecule on the right that has the shape of the model molecule on the left: molecules model (check all that apply) OH,0° O So3 O Bro3 O CH,0 You can drag the slider O None of the above Note for advanced students: the length of bonds and size of atoms in the model is not necessarily realistic. The model is only geometry and 3D shape of the molecule.arrow_forward
- 1) For each condensed or skeletal structure below: A. Draw a complete Lewis structure. Note: show all non-bonding electron pairs. B. Indicate the hybridization of all C, O, and N atoms in each of the molecules. C. Label each of the indicated bonds (marked by an arrow) as either a sigma or pi bond. (Note: Remember, e.g. that a double bond is made up of both a o and a π bond). Also indicate which orbitals overlap to form the bond (e.g., Ols-2sp3). D. For atoms having lone pairs in the molecules below, indicate in which orbitals the lone pairs are located. E. Which of the bonds indicated by arrows is shorter? a) c) H CH3 C=CHC=C-CH g) (CH3)3CCN CH3 CH₂CH=CHCECH b) d) CH3 Lo LOH f) CH₂CH(CH3)SH h) (CH3)2CH(CH₂)3Brarrow_forwardCheck the box next to each molecule on the right that has the shape of the model molecule on the left: molecules model (check all that apply) ? alo to O BrF O NH, You can drag the slider to rotate the model molecule. O CH,O O CF4 O None of the above Note for advanced students: the length of bonds and size of atoms in the model is not necessarily realistic. The model is only meant to show you the general geometry and 3D shape of the molecule.arrow_forwardI need help drawing the VSEPR geometry of ( CH2O), the electronic, molecular geometry, and if it’s polar. All of these get me confuse. Please helparrow_forward
- A model for NO, is shown in the chem3D window. NO, has bent geometry. This geometry is sometimes called angular or V-shaped geometry. [ball & stick + labels Rotate the molecule until you have a feeling for its three-dimensional shape. How many atoms are bonded to the central atom? Consider the bond angle at the central atom. What is the approximate numerical value of this angle? v degrees. You could view this geometry as being derived from a trigonal planar molecule by removing one atom, or as being derived from a tetrahedral molecule by removing two atoms. Which does the bond angle suggest?| For practice, type in the name of the geometry of the molecule:arrow_forwardAlso, highlight each bond in this structure that is cis but which could be trans in a different cis/trans isomer. If there are no such bonds, check the No bonds to highlight box under the drawing area. Note: be careful not to highlight a bond just because it's cis in this drawing! It also needs to be a bond that would create a different cis/trans isomer if it were changed to trans. This molecule has cis/trans isomers in all. G Carrow_forwardI dont understand. Select the bonds in the 3D representation of thymine below that are multiple bonds. (Hint: Consider the number of bonds attached to an atom in the image compared to the normal valence of that atom. In a valid structure, the number of bonds to an atom will equal the valence of that atom.)arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning