General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 16, Problem 60P
Label the
a.
b.
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Glycerol contains:
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a. oxygens which are each bonded to two alkyl groups
b. oxygens single-bonded to primary and secondary carbons
c. Oxygens double-bonded to carbon, with alkyls on both sides
d. Oxygens double-bonded to carbon, with alkyls on one side only
e. Oxygens double-bonded to carbon, with an alkyl on one side and an --OH on the other side
1. Differentiate Ethyl alcohol from methyl alcohol.
2. Compare aldehydes and ketones as to (Use acetaldehyde and acetone as examples).
A. Reaction with cone. NaOH, heated
B. Reaction with Tollen’s reagent
Name each compound depicted in the ball-and-stick models.
a.
C.
Chapter 16 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 16.1 - Prob. 16.1PCh. 16.1 - Draw the structure of the three constitutional...Ch. 16.2 - Give the IUPAC name for each aldehyde. a. (...Ch. 16.2 - Give the structure corresponding to each TUPAC...Ch. 16.2 - Prob. 16.4PCh. 16.2 - Prob. 16.2PPCh. 16.2 - Give the structure corresponding to each name. a....Ch. 16.3 - Which compound in each pair has the higher boiling...Ch. 16.3 - Acetone and progesterone are two ketones that...Ch. 16.4 - Prob. 16.8P
Ch. 16.5 - What product is formed when each carbonyl compound...Ch. 16.5 - Prob. 16.4PPCh. 16.5 - Prob. 16.9PCh. 16.6 - Prob. 16.5PPCh. 16.6 - Prob. 16.10PCh. 16.6 - Prob. 16.11PCh. 16.7 - Prob. 16.12PCh. 16.8 - Prob. 16.6PPCh. 16.8 - Prob. 16.7PPCh. 16.8 - Prob. 16.13PCh. 16.8 - Prob. 16.8PPCh. 16.8 - Label the three acetalsin solanine, the toxic...Ch. 16.8 - Prob. 16.14PCh. 16.8 - Prob. 16.10PPCh. 16 - Prob. 15PCh. 16 - Prob. 16PCh. 16 - Prob. 17PCh. 16 - Prob. 18PCh. 16 - Prob. 19PCh. 16 - Prob. 20PCh. 16 - Prob. 21PCh. 16 - Prob. 22PCh. 16 - Prob. 23PCh. 16 - Prob. 24PCh. 16 - Give an acceptable name for each ketone. a. b. c....Ch. 16 - Prob. 26PCh. 16 - Prob. 27PCh. 16 - Draw the structure corresponding to each name. a....Ch. 16 - Prob. 29PCh. 16 - Prob. 30PCh. 16 - Prob. 31PCh. 16 - Prob. 32PCh. 16 - Draw out the structure of benzaldehyde, including...Ch. 16 - Prob. 34PCh. 16 - Which compound in each pair has the higher boiling...Ch. 16 - Prob. 36PCh. 16 - Prob. 37PCh. 16 - Prob. 38PCh. 16 - Prob. 39PCh. 16 - Prob. 40PCh. 16 - Prob. 41PCh. 16 - Prob. 42PCh. 16 - Prob. 43PCh. 16 - Prob. 44PCh. 16 - Prob. 45PCh. 16 - Consider the following ball-and-stick model....Ch. 16 - Prob. 47PCh. 16 - Prob. 48PCh. 16 - Prob. 49PCh. 16 - Prob. 50PCh. 16 - Prob. 51PCh. 16 - Prob. 52PCh. 16 - Prob. 53PCh. 16 - Prob. 54PCh. 16 - Prob. 55PCh. 16 - Prob. 56PCh. 16 - Prob. 57PCh. 16 - Prob. 58PCh. 16 - Prob. 59PCh. 16 - Label the functional group(s) in each compound as...Ch. 16 - Prob. 61PCh. 16 - Prob. 62PCh. 16 - What acetal is formed when each aldehyde or ketone...Ch. 16 - What acetal is formed when each aldehyde or ketone...Ch. 16 - Prob. 65PCh. 16 - Prob. 66PCh. 16 - Prob. 67PCh. 16 - Prob. 68PCh. 16 - Prob. 69PCh. 16 - Prob. 70PCh. 16 - Prob. 71PCh. 16 - Prob. 72PCh. 16 - Prob. 73PCh. 16 - Answer each question about phenylacetaldehyde,...Ch. 16 - Prob. 75PCh. 16 - Prob. 76PCh. 16 - Prob. 77PCh. 16 - Prob. 78PCh. 16 - Three constitutional isomers of molecular formula...Ch. 16 - Identify A—C in the following reaction sequenceCh. 16 - Androsterone is a male sex hormone that controls...Ch. 16 - Prob. 82PCh. 16 - Prob. 83PCh. 16 - Prob. 84PCh. 16 - Prob. 85PCh. 16 - Paraldehyde, a hypnotic and sedative once commonly...Ch. 16 - Prob. 87PCh. 16 - Prob. 88PCh. 16 - Prob. 89CPCh. 16 - Prob. 90CP
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- An acid catalyst in nucleophilic addition of aldehydes and ketones is used for: Select one: a. Protonation of carbonyl carbon b. Making the aldehyde and ketone more susceptible to nucleophiles c. Increasing the nucleophilicity of the nucleophile d. To provide a medium for the reaction.arrow_forwardLabel the functional group(s) in each compound as an alcohol, ether, acetal, or hemiacetal.arrow_forwardLabel the functional group(s) in each compound as ethers or acetals.arrow_forward
- 17. Which functional groups are in the following molecule of aspirin? HO, a benzene ring, an ester, a ketone, and an alcohol b. a benzene ring, two ketones, an ether, and an alcohol a benzene ring, a carboxylic acid, an ether, and a ketone d. a benzene ring, a carboxylic acid, and an ester a. c.arrow_forwardGive the IUPAC name for each ketone. C-CHCH,CH3 b. a.arrow_forwardV. Give the IUPAC name of the structurearrow_forward
- Explain why the ether with formula C2H6O is very slightly soluble in water, whereas the alcohol with the same formula is infinitely soluble in water.arrow_forwardAssign the IUPAC name to each of the following ethers. Name the smaller alkyl group as the alkoxy group. a. CH3CH2OCH2CH2CH3 b. c. d.arrow_forwardGive the structure of an alcohol that could be used to prepare each of the following compounds: a. b. c.arrow_forward
- The correct IUPAC name for this compound is: O a. 4-oxa-1-cyclohexanol O b. 4-hydroxyoxacyclohexene O c. 4-oxa-1-cyclohexenol O d. 4-oxacyclohexane-1-ol OHarrow_forwardWhat is produced when methanal undergoes Grignard reaction? O A. primary alcohol B. secondary alcohol O C. tertiary alcohol O D. no reactionarrow_forward1. WRITE THE IUPAC NAME OF THIS ETHER CH3CH2-O-CH2CH2CH2CH2CH3 2. HOW DO PHENOLS DIFFER FROM ALCOHOLS IN TERMS OF STRUCTURE AND PROPERTIES? 3. HOW DO PHENOLS DEIFFER IN PROPERTIES FROM AROMATIC HYDROCARBONS?arrow_forward
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