Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 10.5, Problem 10.15P
a.
Interpretation Introduction
Interpretation:
The compounds butane or isobutane has to be represented.
Concept Introduction:
Butane and Isobutane:
In butane structure there will be four carbon atoms present in the straight chain. The carbon present in one continuous chain.
In isobutane there will be three carbon atoms present in a row and one carbon bond is bonded to middle carbon. This
b.
Interpretation Introduction
Interpretation
The compounds whether butane or isobutane has to be identified.
Concept Introduction:
Refer part: a.
c.
Interpretation Introduction
Interpretation:
The compounds either butane or isobutane has to be represented.
Concept Introduction:
Refer part: a.
d.
Interpretation Introduction
Interpretation:
The compounds butane or isobutane has to be represented.
Concept-Introduction:
Refer part: a.
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Part II - Isomerism
1. Octane, C8H18, has 18 different constitutional or chain isomers. One of them,
isooctane, is used as a standard in determining the octane rating of gasoline
a. Draw the structural formulas for at least ten chain isomers of octane.
b. Give the IUPAC name of each.
c. Which of the isomers that you have drawn has the highest boiling point?
Which has the lowest boiling point? Rationalize.
Part II - Isomerism
1. Octane, C8H18, has 18 different constitutional or chain isomers. One of them,
isooctane, is used as a standard in determining the octane rating of gasoline
a. Draw the structural formulas for at least ten chain isomers of octane.
b. Give the IUPAC name of each.
c. Which of the isomers that you have drawn has the highest boiling point?
Which has the lowest boiling point? Rationalize.
2. Which of the following structural formulas represent identical compounds
and which represent constitutional/structural isomers?
Identical compounds:
Constitutional isomers:
CH3
i). CH3-C-CI
ČH3
a). CH3CH2CHCH3
e). CH2CH2CHCH3
CI
CI
CI
CH,CI
b). CH3-C-CH3
f). CH3CH2CH2CH,CI
j). CICH2
CI
CH3
g). CICH,CHCH3
CH2CI
k). CH3-CH-CH3
CI
c). CH3CHCHCH3
CH2CH3
1). CH3CHCI
h). CH3CHCH2CH2CI
CI
d).
-CI
Name each alkyne.
CH,-C=C-CH,
CH3
b. CH;-C=C-C-CH,-CH,
CH3
c. CH=C-CH-CH2-CH2-CH,
CH-CH,
ČH,
Chapter 10 Solutions
Principles of General, Organic, Biological Chemistry
Ch. 10.1 - Prob. 10.1PCh. 10.2 - Fill in all Hs and lone pairs in each compound. a....Ch. 10.3 - Convert each compound to a condensed formula.Ch. 10.3 - Convert each condensed formula to a complete...Ch. 10.3 - Convert each skeletal structure to a complete...Ch. 10.3 - How many Hs are bonded to each indicated carbon...Ch. 10.4 - Identify the functional groups in each compound....Ch. 10.4 - For each compound: [1] Identify the functional...Ch. 10.4 - Prob. 10.9PCh. 10.4 - Prob. 10.10P
Ch. 10.4 - Convert the ball-and-stick model of the local...Ch. 10.5 - How many hydrogen atoms are present in each...Ch. 10.5 - Prob. 10.13PCh. 10.5 - Prob. 10.14PCh. 10.5 - Prob. 10.15PCh. 10.5 - Prob. 10.16PCh. 10.6 - Give the IUPAC name for each compound.Ch. 10.6 - Prob. 10.18PCh. 10.6 - Prob. 10.19PCh. 10.6 - Prob. 10.20PCh. 10.7 - Prob. 10.21PCh. 10.7 - Prob. 10.22PCh. 10.9 - Answer the following questions about pentane...Ch. 10.9 - Prob. 10.24PCh. 10.9 - Prob. 10.25PCh. 10.10 - Prob. 10.26PCh. 10 - Prob. 10.27UKCCh. 10 - Prob. 10.28UKCCh. 10 - Prob. 10.29UKCCh. 10 - Prob. 10.30UKCCh. 10 - Prob. 10.31UKCCh. 10 - The largest known cycloalkane with a single ring...Ch. 10 - Draw three constitutional isomers having molecular...Ch. 10 - Draw four constitutional isomers having molecular...Ch. 10 - Answer the following questions about the alkane...Ch. 10 - Answer the questions in Problem 10.35 for the...Ch. 10 - Prob. 10.37UKCCh. 10 - Procaine (trade name Novocain) is a local...Ch. 10 - Prob. 10.39APCh. 10 - Prob. 10.40APCh. 10 - Complete each structure by filling in all Hs and...Ch. 10 - Prob. 10.42APCh. 10 - Prob. 10.43APCh. 10 - Prob. 10.44APCh. 10 - Prob. 10.45APCh. 10 - Prob. 10.46APCh. 10 - Convert each compound to a condensed structure.Ch. 10 - Prob. 10.48APCh. 10 - Prob. 10.49APCh. 10 - Prob. 10.50APCh. 10 - Prob. 10.51APCh. 10 - Prob. 10.52APCh. 10 - Albuterol (trade names: Proventil and Ventolin) is...Ch. 10 - Prob. 10.54APCh. 10 - Prob. 10.55APCh. 10 - Prob. 10.56APCh. 10 - Prob. 10.57APCh. 10 - Prob. 10.58APCh. 10 - Prob. 10.59APCh. 10 - Prob. 10.60APCh. 10 - Prob. 10.61APCh. 10 - Prob. 10.62APCh. 10 - Prob. 10.63APCh. 10 - Prob. 10.64APCh. 10 - Prob. 10.65APCh. 10 - Prob. 10.66APCh. 10 - Prob. 10.67APCh. 10 - Prob. 10.68APCh. 10 - Prob. 10.69APCh. 10 - Prob. 10.70APCh. 10 - Give the IUPAC name for each compound.Ch. 10 - Prob. 10.72APCh. 10 - Prob. 10.73APCh. 10 - Prob. 10.74APCh. 10 - Prob. 10.75APCh. 10 - Prob. 10.76APCh. 10 - Give the structure corresponding to each IUPAC...Ch. 10 - Prob. 10.78APCh. 10 - Prob. 10.79APCh. 10 - Each of the following IUPAC names is incorrect....Ch. 10 - Prob. 10.81APCh. 10 - Prob. 10.82APCh. 10 - Prob. 10.83APCh. 10 - Prob. 10.84APCh. 10 - Prob. 10.85APCh. 10 - Prob. 10.86APCh. 10 - Write a balanced equation for the incomplete...Ch. 10 - Prob. 10.88APCh. 10 - Prob. 10.89APCh. 10 - Prob. 10.90APCh. 10 - Prob. 10.91APCh. 10 - Prob. 10.92APCh. 10 - Answer the following questions for the cycloalkane...Ch. 10 - Prob. 10.94APCh. 10 - Prob. 10.95CPCh. 10 - Prob. 10.96CP
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- The octane rating for gasoline is a measurement of how readily a fuelcombusts compared to 2,2,4-trimethylpentane, an isomer of octane.a. Draw 2,2,4-trimethylpentane and verify that it is an isomer ofoctane.b. Draw four other isomers of octane.c. Select one of the isomers and draw it such that it looksdifferent on the page but is still the exact same compound.d. Name this isomer.e. Define isomer using a complete sentence.arrow_forwardName each alkane. b. CH3-CH2-CH-CH, CH, CH3 CH3 CH-CH, c. CH;-CH-CH2-CH-CH;-CH,-CH,arrow_forward3. Name the following alkenes and alkynes. HC-CH-C=C-CH-CH--CH3 CH-CH H H H H. H C= C C C-H H. H.arrow_forward
- What is the preferred IUPAC name of the alkene shown in Figure below? CH3 CH3 CH3 `CH-CH3 A. 1-ethyl-2,4,5-trimethylcyclohexene B. 2-ethyl-1,4,5-trimethylcyclohexene C. 2-ethyl-1,4,5-trimethylcyclohex-1-ene D. 4-ethyl-1,2,5-trimethylcyclohexenearrow_forwardWhat is the IUPAC name of the branched alkane below? CH3 H3C. CH3 H3C ČH3 O a. 2,3-methylpropane O b. 2-ethyl-3-methylbutane Oc. trimethylpropane O d., 2, 2-dimethyl-3-methylbutane O e. 2,2,3-trimethylbutane ge Jump to..arrow_forwardP. CH3-CH2-CH3 Q. CH3-CH2-CH=CH-CH3 R. CH3-CH2-CH2-CH2-CH3 S. CH3-CH=CH-CH2-CH3 Which compounds belong to the same homologous series? P and Q Q and R R and S P and R Which structures show unsaturated hydrocarbons? P and Q P and R Q and S R and Sarrow_forward
- 2. Give the IUPAC name for the following compound. Draw the Lewis structure starting from left most carbon and make sure each carbon forms 4 single bonds. Usually alkyl groups as substituents are in the parentheses except one methyl group at the end of carbon chain ( CH3C(CH3)2CH(CH₂CH3)CH₂CH₂CH(CH3)CH3arrow_forward2. Classify each compound as an alcohol, aldehyde, sugar, ketone, methyl ketone, or hydrocarbon (there should only be one of each type of compound). Hexane Ethanol Benzaldehyde Cyclohexanone Acetone (Propanone) Glucose emplearrow_forward5. Give the IUPAC NAME of the following compound: H2C=CH(CH2)2CH=CH2 б. 6. Give the COMMON NAME of the following compound CH3 CH3-C-CH2-CH3 CH3arrow_forward
- • Question 1: Give IUPAC name for each compound. CH3 CH3-C-CH3 a. CH3CH₂CH₂-C-CH₂CH₂CH₂CH3 CH3 CH₂CH3 b. H-C-CH₂-CHCH₂ CH33 CH3 H CH₂-C-CH₂ CH₂CH3 C. CH₂CH₂CH₂-C-CH₂CH₂-C-CH3 H d. CH3 CHCH₂-C-CH3 H I CH3 • Question 2: Give IUPAC name for each compound. H CH₂CH₂CH3 રકમ જમarrow_forwardA a) Identify the functional group in each molecule by structure and by name b) Give the group of compounds to which the molecule belongs c) Explain how you name these compounds and write the IUPAC name below each compound. E. CH-OR CH CH CH₂-CH-CH₂-CH-CH B. Br -- CH: -- CH:- C = C - CH CH₂ - CH3 C. CH3- CH - C - CH: - CH3 11 CH₁ D, CH3- C - CH - CH - C OH CH₂ CH₂ S F. Br Cl CIarrow_forwardName each disubstituted benzene. Br b. CH;-CH3 a. с. CI `CH;-CH3 Brarrow_forward
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