Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 10, Problem 10.45AP
(a)
Interpretation Introduction
Interpretation:
The
Concept Introduction:
Functional group:
Functional group contains particular atom or group of atoms bonded in a molecule which has specific chemical and physical properties. The functional group contains heteroatoms and a multiple bond in a compound.
(b)
Interpretation Introduction
Interpretation:
The solubility of spermaceti wax has to be predicted.
Concept Introduction:
Solubility:
The solubility is defined as the solid or liquid or gaseous substance which dissolves in suitable solvent. The solubility also depends upon the molecule is polar or nonpolar molecule. The nonpolar molecule has no separate positive and negative charge. Polar molecules have separate positive and negative charges.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Many naturally occurring compounds contain more than one functional group. Identify the functional groups in the following compounds:(a) Penicillin G is a naturally occurring antibiotic.(b) Dopamine is the neurotransmitter that is deficient in Parkinson’s disease.(c) Capsaicin gives the fiery taste to chili peppers.(d) Thyroxine is the principal thyroid hormone.(e) Testosterone is a male sex hormone.
Glucose, C6H12O6, contains an aldehyde group but exist predominantly in the form of the cyclic hemiacetal show below.
A cyclic hemiacetal is formed when the —OH group of one carbon bonds to the carbonyl group of another carbon. Identify which carbon provides the —OH group and which provides the —CHO? Give a functional isomer of glucose and draw its structure.
Give the structural formulae and name the functional groups of the following compounds.
(a) 3-chlorobut-1-ene
Name the functional group:
(b) butanedioic acid
Name the functional group:
(c) propanamide
Name the functional group:
(d) 3-methylbutanal
Name the functional group:
Chapter 10 Solutions
Principles of General, Organic, Biological Chemistry
Ch. 10.1 - Prob. 10.1PCh. 10.2 - Fill in all Hs and lone pairs in each compound. a....Ch. 10.3 - Convert each compound to a condensed formula.Ch. 10.3 - Convert each condensed formula to a complete...Ch. 10.3 - Convert each skeletal structure to a complete...Ch. 10.3 - How many Hs are bonded to each indicated carbon...Ch. 10.4 - Identify the functional groups in each compound....Ch. 10.4 - For each compound: [1] Identify the functional...Ch. 10.4 - Prob. 10.9PCh. 10.4 - Prob. 10.10P
Ch. 10.4 - Convert the ball-and-stick model of the local...Ch. 10.5 - How many hydrogen atoms are present in each...Ch. 10.5 - Prob. 10.13PCh. 10.5 - Prob. 10.14PCh. 10.5 - Prob. 10.15PCh. 10.5 - Prob. 10.16PCh. 10.6 - Give the IUPAC name for each compound.Ch. 10.6 - Prob. 10.18PCh. 10.6 - Prob. 10.19PCh. 10.6 - Prob. 10.20PCh. 10.7 - Prob. 10.21PCh. 10.7 - Prob. 10.22PCh. 10.9 - Answer the following questions about pentane...Ch. 10.9 - Prob. 10.24PCh. 10.9 - Prob. 10.25PCh. 10.10 - Prob. 10.26PCh. 10 - Prob. 10.27UKCCh. 10 - Prob. 10.28UKCCh. 10 - Prob. 10.29UKCCh. 10 - Prob. 10.30UKCCh. 10 - Prob. 10.31UKCCh. 10 - The largest known cycloalkane with a single ring...Ch. 10 - Draw three constitutional isomers having molecular...Ch. 10 - Draw four constitutional isomers having molecular...Ch. 10 - Answer the following questions about the alkane...Ch. 10 - Answer the questions in Problem 10.35 for the...Ch. 10 - Prob. 10.37UKCCh. 10 - Procaine (trade name Novocain) is a local...Ch. 10 - Prob. 10.39APCh. 10 - Prob. 10.40APCh. 10 - Complete each structure by filling in all Hs and...Ch. 10 - Prob. 10.42APCh. 10 - Prob. 10.43APCh. 10 - Prob. 10.44APCh. 10 - Prob. 10.45APCh. 10 - Prob. 10.46APCh. 10 - Convert each compound to a condensed structure.Ch. 10 - Prob. 10.48APCh. 10 - Prob. 10.49APCh. 10 - Prob. 10.50APCh. 10 - Prob. 10.51APCh. 10 - Prob. 10.52APCh. 10 - Albuterol (trade names: Proventil and Ventolin) is...Ch. 10 - Prob. 10.54APCh. 10 - Prob. 10.55APCh. 10 - Prob. 10.56APCh. 10 - Prob. 10.57APCh. 10 - Prob. 10.58APCh. 10 - Prob. 10.59APCh. 10 - Prob. 10.60APCh. 10 - Prob. 10.61APCh. 10 - Prob. 10.62APCh. 10 - Prob. 10.63APCh. 10 - Prob. 10.64APCh. 10 - Prob. 10.65APCh. 10 - Prob. 10.66APCh. 10 - Prob. 10.67APCh. 10 - Prob. 10.68APCh. 10 - Prob. 10.69APCh. 10 - Prob. 10.70APCh. 10 - Give the IUPAC name for each compound.Ch. 10 - Prob. 10.72APCh. 10 - Prob. 10.73APCh. 10 - Prob. 10.74APCh. 10 - Prob. 10.75APCh. 10 - Prob. 10.76APCh. 10 - Give the structure corresponding to each IUPAC...Ch. 10 - Prob. 10.78APCh. 10 - Prob. 10.79APCh. 10 - Each of the following IUPAC names is incorrect....Ch. 10 - Prob. 10.81APCh. 10 - Prob. 10.82APCh. 10 - Prob. 10.83APCh. 10 - Prob. 10.84APCh. 10 - Prob. 10.85APCh. 10 - Prob. 10.86APCh. 10 - Write a balanced equation for the incomplete...Ch. 10 - Prob. 10.88APCh. 10 - Prob. 10.89APCh. 10 - Prob. 10.90APCh. 10 - Prob. 10.91APCh. 10 - Prob. 10.92APCh. 10 - Answer the following questions for the cycloalkane...Ch. 10 - Prob. 10.94APCh. 10 - Prob. 10.95CPCh. 10 - Prob. 10.96CP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 5. Give the structural formulae and name the functional groups of the following compounds. (a) 3-chlorobut-1-ene (b) butanedioic acid Name the functional group: (c) propanamide Name the functional group: (d) 3-methylbutanal Name the functional group: Name the functional group:arrow_forwardTRUE OR FALSE (a) A functional group is a group of atoms in an organic molecule that undergoes a predictable set of chemical reactions. (b) The functional group of an alcohol, an aldehyde, and a ketone have in common the fact that each contains a single oxygen atom. (c) A primary alcohol has one —OH group, a secondary alcohol has two —OH groups, and a tertiary alcohol has three —OH groups. (d) There are two alcohols with the molecular formula C3H8O. (e) There are three amines with the molecular formula C3H9N. (f) Aldehydes, ketones, carboxylic acids, and esters all contain a carbonyl group. (g) A compound with the molecular formula of C3H6O may be either an aldehyde, a ketone, or a carboxylic acid. (h) Bond angles about the carbonyl carbon of an aldehyde, a ketone, a carboxylic acid, and an ester are all approximately 109.5°. (i) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O. (j) The molecular formula of the smallest carboxylic…arrow_forward1. The structure of compound A is shown below. OH NH2 (a) Redraw the above structure in the form of expanded and condensed structures. (b) Determine the number of primary, secondary, tertiary and quaternary carbon atom that can be found in the compound. (c) Redraw, circle and name the functional groups present in the compound. (d) State the possible type of stereoisomerism of the compound and draw the appropriate structures to describe the isomerism.arrow_forward
- 1. (a) Draw the structures of the eight isomeric pentyl alcohols, C3H11OH. (b) Name each by the IUPAC system and by the carbinol system. (c) Label each as primary, secondary, or tertiary, (d) Which one is isopentyl alcohol? tert-Pentyl alcohol? (e) Give the structure of a primary, a secondary, and a tertiary alcohol of the formula C,H13OH.arrow_forwardAn alcohol is oxidized to a carboxylic acid, and 0.2003 g of the acid is titrated with 45.25 mL of 0.03811 M NaOH.(a) What is the molar mass of the acid? (b) What are the molarmass and molecular formula of the alcohol?arrow_forwardIdentify which of the following statement(s) is/are true. (f) Aldehydes, ketones, carboxylic acids, and esters all contain a carbonyl group. (g) A compound with the molecular formula of C3H6O may be either an aldehyde, a ketone, or a carboxylic acid. (h) Bond angles about the carbonyl carbon of an aldehyde, a ketone, a carboxylic acid, and an ester are all approximately 109.5°. (i) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O. (j) The molecular formula of the smallest carboxylic acid is C2H4O2.arrow_forward
- The foul odor of rancid butter is caused by butyric acid, CH3CH2CH2CO2H.(a) Draw the Lewis structure and determine the oxidation number and hybridization for each carbon atom in the molecule.(b) The esters formed from butyric acid are pleasant-smelling compounds found in fruits and used in perfumes. Draw the Lewis structure for the ester formed from the reaction of butyric acid with 2-propanol.arrow_forward5.Write the structural formula of the ester that, when hydrolyzed, would yield the following:(a) methanol and propanoic acid(b) 1-octanol and acetic acid (c) ethanol and butanoic acidarrow_forwardDraw the structure and name the product formed if the following alcohols are oxidized. Assume an excess of the oxidizing agent is used. If the alcohol is not expected to react with a chemical oxidizing agent, write NR (no reaction).(a) CH3CH2CH2CH2OH(b) 2-butanol(c) 2-methyl-2-propanol(d) 2-methyl-1-propanolarrow_forward
- (a) Draw a skeletal structure of the anabolic steroid 4-androstene-3,17-dione, also called "andro," from the following description. Andro contains the tetracyclic steroid skeieton with carbonyl groups at C3 and C17, a double bond between C4 and C5, and methyl groups bonded to C10 and C13. (b) Add wedges and dashes for all stereogenic centers with the following information: the configuration at C10 is R, the configuration at C13 is S, and all substituents at ring fusions are trans to each other.arrow_forwardIn an advanced analytical chemistry lab, a team analyzing a compound 'Q' known to be a structural isomer of octane (C8H18). To determine the specific structure of 'Q', a series of spectroscopic analyses are performed. The sequence of the analysis involves: Infrared (IR) spectroscopy, which indicates the absence of functional groups like alcohols, ketones, and carboxylic acids. Nuclear Magnetic Resonance (NMR) spectroscopy, showing signals indicative of only methyl and methylene groups, with no evidence of methine (CH) or quaternary carbon environments. Mass spectrometry (MS), revealing a fragmentation pattern consistent with branched alkane structures. Based on this sequence of analyses, what is the most likely structure of compound 'Q'? Options: A. 2,2,4- Trimethylpentane B. n-Octane C. 2-Methylheptane D. 3-Ethylhexane Don't use chatgpt please provide valuable answerarrow_forward5) Provide complete and balanced chemical reactions for the following. Write the formula and the name of the alcohol that when dehydrated, gives rise to the following alkenes. Give complete reactions. (а) СH-CH,CH-CH-CHCH-CHa (b) • 3-ethyl-1-hexanol is a primary alcohol. Give the two complete oxidation reactions using potassium permanganate.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY