Principles of Modern Chemistry
Principles of Modern Chemistry
8th Edition
ISBN: 9781305079113
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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Chapter 7, Problem 38AP
Interpretation Introduction

Interpretation: All the structural formulas of compound with molecular formula C4H11N needs to be determined if no H atom is directly attached to the N atom.

Concept Introduction: For a molecule, all the structural formulas have same molecular formula but the arrangement of atoms in the molecule is different.

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Two or more of your answers are incorrect. Use this condensed chemical structure to complete the table below. O || CH,=CH–C-H The condensed chemical structure of acrolein Some facts about the acrolein molecule: number of carbon-carbon single (CC) bonds: number of carbon-hydrogen single (CH) bonds: number of lone pairs: X S 2 1 4
Draw a skeletal ("line") structure of this molecule: O CH3 HỌ—C—CH NH2
These two different C2H6O compounds are called structural (or constitutional) isomers - compounds with the same molecular formula but with different connections among their constituent atoms. If you must break and make new bonds in order to convert one structure into the other (not simply rotate the model around), then they are structural isomers. The concept of isomers is very important in organic chemistry and biochemistry. This is also another instance where condensed formulas can be very useful because they can help you distinguish two isomers apart even when you don't have models. Exercise 8) Can your models be interconverted by rotating bonds, or must the bonds be broken first? What does that mean about these two structures?
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