Principles of Modern Chemistry
8th Edition
ISBN: 9781305079113
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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Chapter 7, Problem 38AP
Interpretation Introduction
Interpretation: All the structural formulas of compound with molecular formula
Concept Introduction: For a molecule, all the structural formulas have same molecular formula but the arrangement of atoms in the molecule is different.
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Two or more of your answers are incorrect.
Use this condensed chemical structure to complete the table below.
O
||
CH,=CH–C-H
The condensed chemical structure of acrolein
Some facts about the acrolein molecule:
number of carbon-carbon single (CC) bonds:
number of carbon-hydrogen single (CH) bonds:
number of lone pairs:
X
S
2
1
4
Draw a skeletal ("line") structure of this molecule:
O
CH3
HỌ—C—CH NH2
These two different C2H6O compounds are called structural (or constitutional) isomers -
compounds with the same molecular formula but with different connections among their
constituent atoms. If you must break and make new bonds in order to convert one structure into
the other (not simply rotate the model around), then they are structural isomers. The concept of
isomers is very important in organic chemistry and biochemistry.
This is also another instance where condensed formulas can be very useful because they can
help you distinguish two isomers apart even when you don't have models.
Exercise 8) Can your models be interconverted by rotating bonds, or must the bonds be
broken first? What does that mean about these two structures?
Chapter 7 Solutions
Principles of Modern Chemistry
Ch. 7 - Prob. 1PCh. 7 - Is it possible for a motor fuel to have a negative...Ch. 7 - A gaseous alkane is burned completely in oxygen....Ch. 7 - A gaseous alkyne is burned completely in oxygen....Ch. 7 - Write a chemical equation involving structural...Ch. 7 - Prob. 6PCh. 7 - Prob. 7PCh. 7 - Prob. 8PCh. 7 - Prob. 9PCh. 7 - Prob. 10P
Ch. 7 - Prob. 11PCh. 7 - Prob. 12PCh. 7 - Prob. 13PCh. 7 - State the hybridization of each of the carbon...Ch. 7 - Prob. 15PCh. 7 - Prob. 16PCh. 7 - Prob. 17PCh. 7 - In a recent year, the United States produced...Ch. 7 - Prob. 19PCh. 7 - Prob. 20PCh. 7 - Prob. 21PCh. 7 - Prob. 22PCh. 7 - Prob. 23PCh. 7 - Prob. 24PCh. 7 - Prob. 25PCh. 7 - Prob. 26PCh. 7 - Acetic acid can be made by the oxidation of...Ch. 7 - Acrylic fibers are polymers made from a starting...Ch. 7 - Compare the bonding in formic acid (HCOOH) with...Ch. 7 - Prob. 30PCh. 7 - Prob. 31PCh. 7 - Prob. 32PCh. 7 - Prob. 33PCh. 7 - Prob. 34PCh. 7 - Prob. 35PCh. 7 - Describe the changes in hydrocarbon structure and...Ch. 7 - trans-Cyclodecene boils at 193C, but...Ch. 7 - Prob. 38APCh. 7 - Prob. 39APCh. 7 - Consider the following proposed structures for...Ch. 7 - Prob. 41APCh. 7 - Prob. 42APCh. 7 - Prob. 43APCh. 7 - Prob. 44APCh. 7 - Prob. 45APCh. 7 - The steroid stanolone is an androgenic steroid (a...Ch. 7 - The structure of the molecule cyclohexene is Does...Ch. 7 - Prob. 48CP
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- The carbon–carbon bond length in C2H2 is 1.20 Å, that in C2H4 is 1.34 Å, and that in C2H6 is 1.53 Å. Near which of these values would you predict the bond length of C2 to lie? Is the experimentally observed value, 1.31 Å, consistent with your prediction?arrow_forward6. Give the structural formulas of three compounds of the composition С5Н10О2 belonging to different classes of organic compounds.arrow_forwardWhat is the relationship between structure of molecule (A) and each of the other molecular structures shown below? Are they: • Identical molecules • Geometric isomers • Structural isomers • Different molecules (A) (B) (C) (D) (E) Molecules (A) & (B)? Molecules (A) & (C)? Molecules (A) & (D)? |arrow_forward
- Consider the compound C₂H₃N. Which one of the structures in Figure 4 is the best representation of this compound based on your current knowledge? * A B C D All these structures are good representations of the compound.arrow_forwardStructural Isomers: Alkanes One of the reasons for the complexity of carbon compounds is that it can bond (catenate) with itself. Oils are mostly made up of hydrocarbons, for 'saturated' compounds, these obey the formula CnH2n+2. The empirical formula (unlike benzene) will vary with n. Now we have established C is tetrahedral, how many structural (skeletal) isomers can we find for n=6, hexane C6H14 ? 1) Sketch all the isomers. What procedure did you use to make sure you didn’t miss any ? Do you think you could you do this now for heptane C7H16 ?! (Hint: 9 different ‘skeletal’ topologies) Note the number of possible isomers increases in highly exponential way. C10 – 75 isomers C15 – 4,347 isomers C20 - 366,319 isomers !! Note:- • Do not provide handwritten solution. Maintain accuracy and quality in your answer. Take care of plagiarism. • Answer completely. • You will get up vote for sure.arrow_forwardDraw at least four compounds of formula C4H6NOCl.arrow_forward
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