Principles of Modern Chemistry
Principles of Modern Chemistry
8th Edition
ISBN: 9781305079113
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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Chapter 7, Problem 16P

(a)

Interpretation Introduction

Interpretation:

The logic should be explained for the suggestion of similar structure of C60 and C12B24N24 by comparing their number of valence electrons.

Concept Introduction:

The electrons present in the outermost energy level or shell is known as valence electrons. These electrons are available for bonding and outermost shell is known as valence shell.

(b)

Interpretation Introduction

Interpretation:

The most symmetric pattern of carbon, boron and nitrogen atoms in C12B24N24 should be determined to occupy the 60 atom sites in fullerenes structure along with the location where double bond could be present in the structure.

Concept Introduction:

Fullerene molecular formula: C60

Fullerene has 60 carbon atoms and its structure is arranged in a closed net having 12 pentagonal and 12 hexagonal faces to form cage like structure.

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Use the following set of assumptions to estimate the CN bond length in fulminic acid: 1) only the two best structures contribute to the true structure 2) the best structure contributes 75%, 3) the CN single bond is 1.47 pm, the double is 1.32 pm and the triple is L.16 pm. Enter your answer with 2 significant figures as a number with no units. Structure I Structure II Structure III H-C=N=0 H-C=N-0 ŌI H-C-N=01 VFullsc 10:41 PM
For the following descriptions of molecules, draw the Lewis structure (showing all atoms, lone pairs, formal charges) of the molecule and show all bond angles (assuming ideal VSEPR angles). An organic compound with the molecular formula H3CNO2. C is sp2 hybridized, N is sp3 hybridized, one O is sp² hybridized, while the second O is sp3 hybridized. An organic compound with the molecular formula H2CNO*. Both C and O are sp hybridized while N is sp³ hybridized.
The carbon–carbon bond length in C2H2 is 1.20 Å, that in C2H4 is 1.34 Å, and that in C2H6 is 1.53 Å. Near which of these values would you predict the bond length of C2 to lie? Is the experimentally observed value, 1.31 Å, consistent with your prediction?
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