Principles of Modern Chemistry
Principles of Modern Chemistry
8th Edition
ISBN: 9781305079113
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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Chapter 7, Problem 41AP

(a)

Interpretation Introduction

Interpretation:The number of hydroxyl groups in X needs to be determined.

Concept Introduction: For a molecule, all the structural formulas have same molecular formula but the arrangement of atoms in the molecule is different.

(b)

Interpretation Introduction

Interpretation:If X is an aldehyde, the possible structure for X and Y needs to be determined.

Concept Introduction: For a molecule, all the structural formulas have same molecular formula but the arrangement of atoms in the molecule is different.

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Draw Lewis structures and condensed structural formulas for the four alcohols with the molecular formula C4H10O. Classify each alcohol as primary, secondary, or tertiary. (Hint: First consider the connectivity of the four carbon atoms; they can be bonded either four in a chain or three in a chain with the fourth carbon as a branch on the middle carbon. Then consider the points at which the iOH group can be bonded to each carbon chain.)
Which of the compounds, ethanol, C2H6O, or methanol, CH3OH, should have the higher boiling point? Why? How would the boiling point change if the atmospheric pressure increased or decreased? What is the effect of small amount of impurity on the boiling point of an organic compound? List five physical properties of organic compounds that are often measured by organic chemists.
In what way(s) is(are) the structure of H2O similar to that of CHCl3? In what way is the structure of water different from that of CHCl3?
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