Foundations of Materials Science and Engineering
6th Edition
ISBN: 9781259696558
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 5.7, Problem 42SEP
Would you expect the diffusion rate of copper (self-diffusion) to be lower or higher in copper with ASTM grain size 4 than in copper with ASTM grain size 8? Explain your answer.
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Chapter 5 Solutions
Foundations of Materials Science and Engineering
Ch. 5.7 - Prob. 1KCPCh. 5.7 - Write an equation for the number of vacancies...Ch. 5.7 - Prob. 3KCPCh. 5.7 - Prob. 4KCPCh. 5.7 - Describe the substitutional and interstitial...Ch. 5.7 - Prob. 6KCPCh. 5.7 - What factors affect the diffusion rate in solid...Ch. 5.7 - Write the equation for Ficks second law of...Ch. 5.7 - Prob. 9KCPCh. 5.7 - Prob. 10KCP
Ch. 5.7 - (a) Calculate the equilibrium concentration of...Ch. 5.7 - Prob. 12AAPCh. 5.7 - Determine the diffusion flux of zinc atoms in a...Ch. 5.7 - The diffusion flux of copper solute atoms in...Ch. 5.7 - Prob. 15AAPCh. 5.7 - Prob. 16AAPCh. 5.7 - Prob. 17AAPCh. 5.7 - A gear made of 1020 steel (0.20 wt% C) is to be...Ch. 5.7 - Prob. 19AAPCh. 5.7 - The surface of a steel gear made of 1020 steel...Ch. 5.7 - Prob. 21AAPCh. 5.7 - If boron is diffused into a thick slice of silicon...Ch. 5.7 - Prob. 23AAPCh. 5.7 - Prob. 24AAPCh. 5.7 - Prob. 25AAPCh. 5.7 - Prob. 26AAPCh. 5.7 - Prob. 27AAPCh. 5.7 - Prob. 28AAPCh. 5.7 - Prob. 29AAPCh. 5.7 - Prob. 30AAPCh. 5.7 - The diffusivity of copper atoms in the aluminum...Ch. 5.7 - Prob. 32AAPCh. 5.7 - Prob. 33SEPCh. 5.7 - Prob. 34SEPCh. 5.7 - Prob. 37SEPCh. 5.7 - Prob. 38SEPCh. 5.7 - The activation energy of nickel atoms in FCC iron...Ch. 5.7 - Prob. 40SEPCh. 5.7 - The self-diffusion of iron atoms in BCC iron is...Ch. 5.7 - Would you expect the diffusion rate of copper...Ch. 5.7 - Would you expect the diffusion rate of copper...Ch. 5.7 - Prob. 44SEPCh. 5.7 - Prob. 45SEPCh. 5.7 - Prob. 46SEPCh. 5.7 - Prob. 47SEPCh. 5.7 - Prob. 48SEPCh. 5.7 - Prob. 49SEPCh. 5.7 - Prob. 50SEP
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- Compare the diffusion coefficients of carbon in BCC and FCC iron at the allotropic transformation temperature of 912°C and explain the reason for the difference in their values.arrow_forwardCalculate the value of the diffusion coefficient D (in m2/s) at 750°C for the diffusion of some species in a metal; assume that the values of D0 and Qd are 5.6 × 10-5 m2/s and 177 kJ/mol, respectively.arrow_forwardAnswer in a brief and concise essay. 1. Why does diffusion in solids important?arrow_forward
- Consider a diffusion couple setup between pure tungsten and a tungsten alloy containing 1 at% thorium. After several minutes of exposure at 2000 C, a transition zone of 0.01 cm thickness is established. What is the flux of thorium atoms at this time if diffusion is due to (a) volume diffusion, (b) grain boundary diffusion, and (c) surface diffusion? TABLE 5-2 I The effect of the type of diffusion for thorium in tungsten and for self-diffusion in silver* Diffusion Coefficient (D) Diffusion Type Thorium in Tungsten Silver in Silver Do cm?/s Q cal/mole Do cm2/s Q cal/mole 66,400 90,000 120,000 0.47 0.068 8,900 22,750 45,700 Surface Grain boundary 0.74 0.24 Volume 1.00 0.99arrow_forwardRank the magnitudes of the diffusion coefficients from greatest to least for the following systems: N in Fe at 700°C Cr in Fe at 700°C N in Fe at 900°C Cr in Fe at 900°C Now justify this ranking. (Note: Both Fe and Cr have the BCC crystal structure, and the atomic radii for Fe, Cr, and N are 0.124, 0.125, and 0.065 nm, respectively. You may also want to refer to Section 5.4.)arrow_forwardIn copper, what percentage of the volume change which occurs as the specimen is heated from room temperature to its melting point is due to the increased vacancy concentration, assuming that the vacancy concentration is just below the melting point (1083 oC) is 10-4. Given: Assume that the linear thermal expansion coefficient of copper is 16.5×10-6 K-1 over the whole temperature range.arrow_forward
- During freezing of a Cu-Zn alloy, we find that the composition is non-uniform. By heating the alloy to 600°C for 3 hours, diffusion of zinc helps to make the composition more uniform. What temperature would be required if we wished to perform this homogenization treatment in 30 minutes?arrow_forwardCompare the diffusion coefficients (in cm²/s) of nitrogen in BCC and FCC iron at the allotropic transformation temperature of 912°C. Decc -153606 X Your response differs from the correct answer by more than 10%. Double check your calculations, cm²/s -1976-7 Dicc x Your response differs significantly from the correct answer. Rework your solution from the beginning and check each step carefully. cm2/sarrow_forwardFor a steel alloy it has been determined that a carburizing heat treatment of 18 h duration at 885°C will raise the carbon concentration to 0.46 wt% at a point 2.0 mm from the surface. Estimate the time necessary to achieve the same concentration at a 8.4 mm position for an identical steel and at a carburizing temperature of 1120°C. Assume that Do is 2.5 x 10-4 m2/s and Qa is 104 kJ/mol.arrow_forward
- I need help answering these two conduction and diffusion questions. Thank YOUarrow_forwardThe diffusion coefficient of nickel in an austenitic stainless steel is 10-22 m2/s at 500°C and 10^-15 m^2/s at 1000°C. Calculate the activation energy for the diffusion of nickel in this alloy over this temperature range.arrow_forward(c) Consider an alloy that is undergoing carburizing process, initially has a uniform carbon concentration of 0.27 wt% and is to be treated at 950oC (1750oF). If the concentration of carbon at the surface is suddenly brought to and maintained at 1.32 wt%, how long will it take to achieve a carbon content of 0.85% at a position 0.7 mm below the surface? The diffusion coefficient for carbon in iron at this temperature is 1.6 x 10-11 m2/s; assume that the steel piece is semi-finite.arrow_forward
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Introduction to Diffusion in Solids; Author: Engineering and Design Solutions;https://www.youtube.com/watch?v=K_1QmKJvNjc;License: Standard youtube license