Foundations of Materials Science and Engineering
6th Edition
ISBN: 9781259696558
Author: SMITH
Publisher: MCG
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Chapter 5.7, Problem 32AAP
To determine
Calculate the activation energy.
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Chapter 5 Solutions
Foundations of Materials Science and Engineering
Ch. 5.7 - Prob. 1KCPCh. 5.7 - Write an equation for the number of vacancies...Ch. 5.7 - Prob. 3KCPCh. 5.7 - Prob. 4KCPCh. 5.7 - Describe the substitutional and interstitial...Ch. 5.7 - Prob. 6KCPCh. 5.7 - What factors affect the diffusion rate in solid...Ch. 5.7 - Write the equation for Ficks second law of...Ch. 5.7 - Prob. 9KCPCh. 5.7 - Prob. 10KCP
Ch. 5.7 - (a) Calculate the equilibrium concentration of...Ch. 5.7 - Prob. 12AAPCh. 5.7 - Determine the diffusion flux of zinc atoms in a...Ch. 5.7 - The diffusion flux of copper solute atoms in...Ch. 5.7 - Prob. 15AAPCh. 5.7 - Prob. 16AAPCh. 5.7 - Prob. 17AAPCh. 5.7 - A gear made of 1020 steel (0.20 wt% C) is to be...Ch. 5.7 - Prob. 19AAPCh. 5.7 - The surface of a steel gear made of 1020 steel...Ch. 5.7 - Prob. 21AAPCh. 5.7 - If boron is diffused into a thick slice of silicon...Ch. 5.7 - Prob. 23AAPCh. 5.7 - Prob. 24AAPCh. 5.7 - Prob. 25AAPCh. 5.7 - Prob. 26AAPCh. 5.7 - Prob. 27AAPCh. 5.7 - Prob. 28AAPCh. 5.7 - Prob. 29AAPCh. 5.7 - Prob. 30AAPCh. 5.7 - The diffusivity of copper atoms in the aluminum...Ch. 5.7 - Prob. 32AAPCh. 5.7 - Prob. 33SEPCh. 5.7 - Prob. 34SEPCh. 5.7 - Prob. 37SEPCh. 5.7 - Prob. 38SEPCh. 5.7 - The activation energy of nickel atoms in FCC iron...Ch. 5.7 - Prob. 40SEPCh. 5.7 - The self-diffusion of iron atoms in BCC iron is...Ch. 5.7 - Would you expect the diffusion rate of copper...Ch. 5.7 - Would you expect the diffusion rate of copper...Ch. 5.7 - Prob. 44SEPCh. 5.7 - Prob. 45SEPCh. 5.7 - Prob. 46SEPCh. 5.7 - Prob. 47SEPCh. 5.7 - Prob. 48SEPCh. 5.7 - Prob. 49SEPCh. 5.7 - Prob. 50SEP
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- Iron (Fe) undergoes an allotropic transformation at 912°C: upon heating from a BCC (α phase) to an FCC (γ phase). Accompanying this transformation is a change in the atomic radius of Fe—from RBCC = 0.12584 nm to RFCC = 0.12894 nm—and, in addition, a change in density (and volume). Compute the percentage volume change associated with this reaction. Indicate a decreasing volume by a negative number.arrow_forwardA 1020 steel contains 0.20% carbon is carburized by a source that maintains a surface carbon content 0f 2.0% C. It is desired to produce a 0.80 wt% C concentration 0.1 cm below the steel surface after a 4-hour treatment. At what temperature should the carburization be carried out? R = 8.314 J/mol•K; DO = 2.3x10-5 m2 /s; Qd=148,000 J/mol erf(z) erf(z) erf(z) 0.55 0.5633 1.3 0.9340 0.025 0.05 0.0282 0.60 0.6039 1.4 0.9523 0.0564 0.65 0.6420 1.5 0.9661 0.10 0.1125 0.70 0.6778 1.6 0.9763 0.15 0.1680 0.75 0.7112 1.7 0.9838 0.20 0.25 0.30 0.2227 0.80 0.7421 1.8 0.9891 0.2763 0.85 0.7707 1.9 0.9928 0.3286 0.90 0.7970 2.0 0.9953 0.35 0.3794 0.95 0.8209 2.2 0.9981 0.40 0.4284 1.0 0.8427 2.4 0.9993 0.45 0.4755 1.1 0.8802 2.6 0.9998 0.50 0.5205 1.2 0.9103 2.8 0.9999arrow_forward•You are case-hardening a tool made of BCC (α) iron in the presence of a carbonaceous material. A heat treatment at 600 oC for 100 minutes results in a carbon concentration of 0.75 wt% at a position 0.5mm below the surface. How long would it take to obtain the same concentration at the same position if the heat treatment were conducted at 900 oC? x12/D1t1= x22/D2t2 Arrhenius equation: D=D0e^(〖-Qd〗∕RT) Qd = Activation energy of diffusion D0 = Pre-exponential diffusion factor R = gas constant = 8.314 J/(mol*K) Use the Arrhenius equation to calculate D1 and D2. Calculate the time to satisfy the problem statement.arrow_forward
- Consider de-oxidation by the addition of ferromanganese (60 percent Mn) to molten steel at 1600°C.The initial oxygen content is 0.04 wt%. It has to be brought down to 0.02 wt%. Calculate the quantity of ferromanganese required per tonne of steel. The manganese content of steel before de- oxidation is 0.1 wt%. (MnO) + [Fe] = [Mn] + (FeO) Given: K Mn at 1873 K = 0.4 K Fe-Mn at 1873 K = 0.156 Assumptions: Fe and Mn form ideal solutionsarrow_forwardThe activation energy for the diffusion of atomic species A in metal B is 114 kJ/mol. Calculate the diffusion coefficient at 891°C, given that the value of D at 1170°C is 76.7 × 10^-12 m2/s.arrow_forwardIn a binary Fe-Fe3C system, what is a transformation that occurs when cooling an austenistic mixture of 2% C by weight from 1100°C to below the eutectoid temperature? What is the microstructure, and how is it formed? What are the total and partial phases? Given:Eutectoid temperature=723°C; Eutectoid concentration=0.76% C; Limit concentration of ferrite=0.022%; Limiting concentration of cementite: 6.7%.arrow_forward
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- 1. For some hypothetical metal the equilibrium number of vacancies at 750°C is 2.8×1024?−3. If the density and atomic weight of this metal are 5.60 ? ??3⁄ and 65.6 ?/???, respectively, calculate the fraction of vacancies for this metal at 750°C. 2. Calculate the number of vacancies per cubic meter in iron at 850°C. The energy for vacancy formation is 1.08 eV/atom. The density and atomic weight for Fe are 7.65 g/cm3 and 55.85 g/mol, respectively. Answer both pleasearrow_forwardThe force of attraction between a divalent cation and a monovalent anion is 8.02x10-9 N. If the ionic radius of the cation is 0.060 nm, (q=1.6x10-19 C, k0=9x109 V∙m/C). What is the anion radius?arrow_forwardDetermine the approximate density of a Ti-6Al-4V titanium alloy that has a composition of 90 wt% Ti, 6 wt% Al, and 4 wt% Varrow_forward
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